3,4,5,6-tetrahydrophthalamic acid monomethyl ester | 184643-93-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3,4,5,6-tetrahydrophthalamic acid monomethyl ester
• 英文别名: Methyl 2-carbamoylcyclohex-1-ene-1-carboxylate；methyl 2-carbamoylcyclohexene-1-carboxylate
• CAS: 184643-93-4
• 化学式: C₉H₁₃NO₃
• 分子量: 183.207
• InChiKey: BSNDQEDOQJYKHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  69.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-(4-chloro-2-fluoro-5-methoxycarbonylmethylthiophenyl)-acetoimidoylchloride 、 3,4,5,6-tetrahydrophthalamic acid monomethyl ester 在 三甲胺 作用下， 以 苯 为溶剂， 生成 N-acetyl-N-(4-chloro-2-fluoro-5-methoxycarbonylmethylthiophenyl)-3,4,5,6-tetrahydrophthalamic acid methyl ester
  参考文献：
  名称：

  N-phenyltetrahydrophthalamic acid derivatives, methods of producing

  摘要：

  该发明提供了通式\x9bI!所代表的N-苯基四氢邻苯二甲酸衍生物，以及生产该衍生物的方法，包含该衍生物作为有效成分的除草剂，以及作为中间产物的亚咪基氯化物衍生物和生产该亚咪基氯化物的方法，其中X和Y分别表示氢原子或卤原子，R.sup.1表示低碳酰基烷基硫基，R.sup.2表示低烷基，卤代低烷基或取代或未取代的苯基，R.sup.3表示低烷氧基，低烯氧基，低炔氧基或低烷氧烷氧基。本发明的除草剂非常有用，可以广泛应用于旱地、稻田、果园、草坪、森林、非作物土地等，对作物无害。

  公开号：

  US05801122A1

文献信息

• N-acyl-n-phenyltetrahydrophthalamic acid derivatives, methods of
  申请人：Central Glass Company, Limited

  公开号：US05468719A1

  公开（公告）日：1995-11-21

  The invention provides N-acyl-N-phenyltetrahydrophthalamic acid derivatives represented by the general formula [I], methods of producing the same, herbicides containing the same as the effective components, imidoylchloride derivatives as the intermediate products and methods of producing the same, ##STR1## wherein R.sup.1 represents an alkyl group, an alkenyl group, an alkynyl group, an alkoxyalkyl group, a haloalkyl group, a haloalkenyl group, a haloalkynyl group or a cyanoalkyl group, R.sup.2 represents a lower alkyl group or a halogenated lower alkyl group, and R.sup.3 represents a lower alkoxy group, a lower alkenyloxy group, a lower alkynyloxy group, a lower alkoxyalkoxy group, a substituted or unsubstituted benzyloxy group, a lower haloalkyloxy group or a lower alkoxycarbonylalkoxy group. The herbicides of the present invention, which are very useful, can be widely applied to upland, paddy field, orchard, turf, forest, non-crop land, etc., and are not harmful to crops.

  本发明提供了由通式[I]表示的N-酰基-N-苯基四氢萘酸衍生物，其制备方法，含有其作为有效成分的除草剂，咪唑氯化物衍生物作为中间产物及其制备方法，其中，R1表示烷基，烯基，炔基，烷氧基烷基，卤代烷基，卤代烯基，卤代炔基或氰基烷基；R2表示低碳基或卤代低碳基；R3表示低碳氧基，低碳烯氧基，低碳炔氧基，低碳氧基烷氧基，取代或未取代苄氧基，低卤代烷氧基或低碳氧羰基烷氧基。本发明的除草剂非常有用，可以广泛应用于旱地、稻田、果园、草坪、森林、非农作地等，对作物无害。
• N-acyl-N-phenyltetrahydrophthalamic acid derivatives, methods of
  申请人：Central Glass Company, Limited

  公开号：US05292922A1

  公开（公告）日：1994-03-08

  The invention provides N-acyl-N-phenyltetrahydrophthalamic acid derivatives represented by the general formula [I], methods of producing the same, and herbicides containing the same as the effective components, ##STR1## wherein X and Y each individually represent hydrogen atoms or halogen atoms, R.sup.1 represents a hydrogen atom, a halogen atom, a lower alkoxy group, a lower alkenyloxy group, a lower alkynyloxy group, a lower alkoxyalkoxy group or a lower alkoxycarbonylalkoxy group, R.sup.2 represents a lower alkyl group, a halogenated lower alkyl group, or a substituted or unsubstituted phenyl group, and R.sup.3 represents a lower alkoxy group, a lower alkenyloxy group, a lower alkynyloxy group, a lower alkoxyalkoxy group, a benzyloxy group or a lower alkoxycarbonylalkoxy group. The herbicides which are very useful can be widely applied to upland, paddy field, orchard, turf, forest, non-crop land, etc, and are not harmful to crops.

  本发明提供了由一般式[I]表示的N-酰基-N-苯基四氢萘酸衍生物，以及制备这些衍生物的方法和含有这些衍生物作为有效成分的除草剂，其中X和Y分别独立表示氢原子或卤素原子，R1表示氢原子、卤素原子、低烷氧基、低烯氧基、低炔氧基、低烷氧烷氧基或低烷氧羰基烷氧基，R2表示低烷基、卤代低烷基或取代或未取代的苯基，R3表示低烷氧基、低烯氧基、低炔氧基、低烷氧烷氧基、苄氧基或低烷氧羰基烷氧基。这些非常有用的除草剂可以广泛应用于旱地、水稻田、果园、草坪、森林、非农作物土地等地，并且对作物无害。
• N-ACYL-N-PHENYLTETRAHYDROPHTHALAMIC ACID DERIVATIVE, PRODUCTION THEREOF, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP0496900A1

  公开（公告）日：1992-08-05

  An N-acyl-N-phenyltetrahydrophthalamic acid derivative represented by general formula (I), a process for producing the same, and a herbicide containing the same as the active ingredient: wherein X and Y represent each independently hydrogen or halogen; R¹ represents hydrogen, halogen, lower alkoxy, lower alkenyloxy, lower alkynyloxy, lower alkoxyalkoxy or lower alkoxycarbonylalkoxy; R² represents lower alkyl, halogenated lower alkyl, or (un)substituted phenyl; and R³ represents lower alkoxy, lower alkenyloxy, lower alkynyloxy, lower alkoxyalkoxy, benzyloxy, or lower alkoxycarbonylalkoxy. The herbicide is widely applicable to upland fields, paddy fields, orchards, pastures, turfs, forests, non-crop lands and so forth, and is highly safe to crops, thus proving very useful.

  一种由通式(I)代表的N-酰基-N-苯基四氢酞胺酸衍生物、一种生产该衍生物的工艺以及一种含有该衍生物作为活性成分的除草剂：其中X和Y各自独立地代表氢或卤素；R¹代表氢、卤素、低级烷氧基、低级烯氧基、低级炔氧基、低级烷氧基烷氧基或低级烷氧基羰基烷氧基；R²代表低级烷基、卤代低级烷基或（未）取代苯基；R³代表低级烷氧基、低级烯氧基、低级炔氧基、低级烷氧基烷氧基、苄氧基或低级烷氧基羰基烷氧基。该除草剂广泛适用于高地、水田、果园、牧场、草皮、森林、非农作物地等，对农作物非常安全，因此证明非常有用。
• N-ARYLOXYACYL-N-PHENYLTETRAHYDROPHTHALAMIC ACID DERIVATIVE, PROCESS FOR PRODUCING THE SAME, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP0627409A1

  公开（公告）日：1994-12-07

  An N-aryloxyacyl-N-phenyltetrahydrophthalamic acid derivative represented by general formula (I), a process for producing the same, and a herbicide containing the same as the active ingredient, which is very useful as a herbicide because it can be widely applied to upland field, lowland, orchard, pasture, turf, forest and non-crop land, and is highly safe for crop. In formula (I), X and Y represent each independently hydrogen or halogen; R¹ represents hydrogen, halogen, lower alkyl, lower alkoxy, lower alkenyloxy, lower alkynyloxy, lower alkoxyalkoxy or lower alkoxycarbonylalkoxy; R² represents hydrogen or lower alkyl; R³ represents hydroxy, lower alkoxy, lower alkenyloxy, lower alkynyloxy, lower alkoxy-alkoxy, benzyloxy or lower alkoxycarbonylalkoxy; and m represents an integer of 0 to 5.

  一种由通式(I)表示的N-芳氧基酰基-N-苯基四氢酞胺酸衍生物、一种生产该衍生物的工艺以及一种以该衍生物为有效成分的除草剂，该除草剂可广泛应用于高地、低地、果园、牧场、草皮、林地和非作物地，作为除草剂非常有用，并且对作物高度安全。在式 (I) 中，X 和 Y 各自独立地代表氢或卤素；R¹ 代表氢、卤素、低级烷基、低级烷氧基、低级烯氧基、低级炔氧基、低级烷氧基烷氧基或低级烷氧基羰基烷氧基；R² 代表氢或低级烷基；R³ 代表羟基、低级烷氧基、低级烯氧基、低级炔氧基、低级烷氧基烷氧基、苄氧基或低级烷氧基羰基烷氧基；m 代表 0 至 5 的整数。
• N-PHENYLTETRAHYDROPHTHALAMIC ACID DERIVATIVE, PROCESS FOR PRODUCING THE SAME, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP0741131A1

  公开（公告）日：1996-11-06

  The invention provides N-phenyltetrahydrophthalamic acid derivatives represented by the general formula [I], methods of producing the same, herbicides containing the same as the effective components, imidoylchloride derivatives as the intermediate products and methods of producing the same, wherein X and Y each individually represent hydrogen atoms or halogen atoms, R1 represents a lower alkoxycarbonylalkylthio group, R2 represents a lower alkyl group, a halogenated lower alkyl group or a substituted or unsubstituted phenyl group, and R3 represents a lower alkoxy group, a lower alkenyloxy group, a lower alkynyloxy group, or a lower alkoxyalkoxy group. The herbicides of the present invention, which are very useful, can be widely applied to upland, paddy field, orchard, turf, forest, non-crop land, etc., and are not harmful to crops.

  本发明提供由通式[I]代表的N-苯基四氢酞胺酸衍生物、生产方法、含有作为有效成分的N-苯基四氢酞胺酸衍生物的除草剂、作为中间产物的亚胺酰氯衍生物以及生产方法、 其中 X 和 Y 各自代表氢原子或卤素原子，R1 代表低级烷氧基羰基烷硫基，R2 代表低级烷基、卤代低级烷基或取代或未取代的苯基，R3 代表低级烷氧基、低级烯氧基、低级炔氧基或低级烷氧基烷氧基。本发明的除草剂非常有用，可广泛应用于高地、水田、果园、草皮、森林、非作物地等，对作物无害。