Bis(1-propylbutyl)amine | 50424-19-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Bis(1-propylbutyl)amine
• 英文别名: di(heptan-4-yl)amine；Bis-(α-propyl-butyl)-amin；N-heptan-4-ylheptan-4-amine
• CAS: 50424-19-6
• 化学式: C₁₄H₃₁N
• 分子量: 213.407
• InChiKey: BSJIJKAGKDMENJ-UHFFFAOYSA-N

物化性质

• 沸点：
  248.3±8.0 °C(Predicted)
• 密度：
  0.792±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Bis(1-propylbutyl)amine 在 三乙胺 、 N,N-二甲基甲酰胺 作用下， 以 四氢呋喃 、 乙醚 、 环己烷 为溶剂， 反应 3.5h， 生成 N,N-Bis(1-propylbutyl)-2-(1-methylpropyl)-1,2-dihydronaphthalene-1-carboxamide
  参考文献：
  名称：

  Atroposelectivity in the reactions of ortholithiated aromatic tertiary amides with aldehydes

  摘要：

  将N,N-二烷基萘酰胺与醛加成得到的产品是一对稳定的、在轴向位置具有非对映异构性的对映异构体，其选择性高达90∶10，倾向于生成syn-对映异构体。

  DOI：

  10.1039/a701671i
• 作为产物：
  描述：

  N-庚烷-4-亚基羟胺 在 氢气 、 镍 作用下， 生成 Bis(1-propylbutyl)amine
  参考文献：
  名称：

  Mailhe, Bulletin de la Societe Chimique de France, 1914, vol. <4>15, p. 328

  摘要：

  DOI：

文献信息

• Selective Palladium(II)-Catalyzed Carbonylation of Methylene β-C−H Bonds in Aliphatic Amines
  作者：Jaime R. Cabrera-Pardo、Aaron Trowbridge、Manuel Nappi、Kyohei Ozaki、Matthew J. Gaunt

  DOI：10.1002/anie.201706303

  日期：2017.9.18

  The ligand is key: Palladium(II)-catalyzed C−H carbonylation reactions of methylene C−H bonds in secondary aliphatic amines lead to the formation of trans-disubstituted β-lactams in excellent yields and selectivities. The generality of the C−H carbonylation process is aided by the action of xantphos-based ligands.

  配体是关键：钯（II）催化的脂肪族仲胺中亚甲基CH键的CH羰基化反应导致反式二取代的β-内酰胺的形成，具有极高的收率和选择性。基于Xantphos的配体的作用有助于CH羰基化过程的普遍性。
• Alexander; Misegades, Journal of the American Chemical Society, 1948, vol. 70, p. 1316
  作者：Alexander、Misegades

  DOI：——

  日期：——
• Rohrmann; Shonle, Journal of the American Chemical Society, 1944, vol. 66, p. 1517,1519
  作者：Rohrmann、Shonle

  DOI：——

  日期：——
• Rewritable optical information recording medium, recording and reproducing methods, as well as recording and reproducing apparatus
  申请人：Tamada Sakuya

  公开号：US20060088786A1

  公开（公告）日：2006-04-27

  A rewritable optical information recording medium including a recording layer composed of an organic dye film is provided, in which recording and erasing information can be performed reversibly by laser light irradiation. A rewritable optical information recording medium including at least one organic dye film which is substantially made of only at least one kind of organic dye compounds as a recording film is provided. The recording and erasure of information are performed by a reversible physical change of the organic dye film substance caused by laser light irradiation. Specifically, data recording is performed by a physical change locally caused by the irradiation of recording laser light, data reproduction is performed by detecting change in intensity of returned light of reproducing laser light having less power than the recording laser light, and data erasure is performed by applying at least once continuous light or pulse light having laser power more than the reproducing laser light and less than the recording laser light. The physical change is a change in shape.
• ADHESIVE COMPOSITIONS
  申请人：Henkel Corporation

  公开号：US20130189532A1

  公开（公告）日：2013-07-25

  Moisture curable poly(acrylate) compositions having more environmentally acceptable catalysts and/or faster skin over time. The compositions demonstrate resistance to hydrocarbon fluids, such as transmission fluids, oils and fuels and are useful as gasketing materials.