N,N′-bis(4-nitrobenzyl)urea | 93734-90-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N′-bis(4-nitrobenzyl)urea
• 英文别名: N,N'-bis(4-nitrobenzyl)urea；1,3-bis(4-nitrobenzyl)urea；N,N'-bis-(4-nitro-benzyl)-urea；N,N'-Bis-(4-nitro-benzyl)-harnstoff；1,3-Bis[(4-nitrophenyl)methyl]urea
• CAS: 93734-90-8
• 化学式: C₁₅H₁₄N₄O₅
• 分子量: 330.3
• InChiKey: UACMZCOHHAIJJM-UHFFFAOYSA-N

物化性质

• 沸点：
  632.7±50.0 °C(Predicted)
• 密度：
  1.388±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  133
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N,N′-bis(4-nitrobenzyl)urea 在 盐酸 作用下， 生成 4-硝基苄胺盐酸盐
  参考文献：
  名称：

  Curtius, Journal fur praktische Chemie (Leipzig 1954), 1914, vol. <2> 89, p. 500,512

  摘要：

  DOI：
• 作为产物：
  描述：

  (4-nitro-phenyl)-acetyl azide 在 水 作用下， 生成 N,N′-bis(4-nitrobenzyl)urea
  参考文献：
  名称：

  Curtius, Journal fur praktische Chemie (Leipzig 1954), 1914, vol. <2> 89, p. 500,512

  摘要：

  DOI：

文献信息

• 액정 배향 처리제
  申请人：Nissan Chemical Corporation 닛산 가가쿠 가부시키가이샤(519980958906)

  公开号：KR20150138410A

  公开（公告）日：2015-12-09

  러빙 처리시의 막 표면에 대한 스크레치나 깎임이 적고, 액정의 배향성이 양호하고, 또한 액정 셀의 전압 유지율이 높고, 이온 밀도도 낮은 액정 배향막이 얻어지는 액정 배향 처리제를 제공한다. 디아민 성분과 테트라카르복실산 유도체를 반응시켜 얻어지는 폴리이미드 전구체 또는 폴리이미드의 어느 하나를 함유하는 액정 배향 처리제로서, 상기 디아민 성분은 하기 식 (1) 로 나타내는 디아민을 함유하는 것을 특징으로 하는 액정 배향 처리제. (식 (1) 중, X 는 산소 원자 또는 황 원자이고, Y 및 Y 는 각각 독립적으로, 단결합, -O-, -S-, -OCO-, 또는 -COO- 이고, R 및 R 는 각각 독립적으로 탄소수 1 ∼ 3 의 알킬렌기이다)

  提供了一种液晶取向处理剂，其在液晶取向处理时对阻挡层表面的划痕或磨损较少，液晶的取向性良好，并且液晶单元格的电压保持率高，离子密度低。液晶取向处理剂包含由二胺成分和四羧酸衍生物反应得到的聚酰亚胺树脂或聚酰亚胺的任意一种。上述二胺成分特征在于包含如下式(1)所示的二胺。式(1)中，X是氧原子或硫原子，Y和Y'各自独立地为单键，-O-, -S-, -OCO-, 或-COO-，R和R'各自独立地为碳数为1至3的烷基。
• NaIO4-oxidized carbonylation of amines to ureas
  作者：Phillip A. Shelton、Yue Zhang、Thi Hoang Ha Nguyen、Lisa McElwee-White

  DOI：10.1039/b819891h

  日期：——

  Oxidative carbonylation of amines using NaIO4 as the oxidant and NaI as a promoter affords good to excellent yields of ureas from primary amines in the absence of transition metalcatalysts.

  使用 NaIO4 作为氧化剂和 NaI 作为促进剂的胺的氧化碳基化反应，可以在没有过渡金属催化剂的情况下，从初级胺中获得良好到优异的尿素产率。
• Bambusurils Bearing Nitro Groups and Their Further Modifications
  作者：Mirza Arfan Yawer、Kristina Sleziakova、Lukas Pavlovec、Vladimir Sindelar

  DOI：10.1002/ejoc.201701329

  日期：2018.1.10

  Bambusurils are recently developed neutral anion receptors that show a high affinity towards many inorganic anions, not only in organic solvents but also in water. However, the number of water-soluble bambusurils and also those bearing functional groups is very limited. In this paper we report the synthesis of four- and six-membered bambusurils containing eight and twelve nitro groups. All the nitro

  Bambusurils 是最近开发的中性阴离子受体，对许多无机阴离子表现出高亲和力，不仅在有机溶剂中，而且在水中。然而，水溶性竹笋的数量以及带有官能团的竹材数量非常有限。在本文中，我们报告了含有八个和十二个硝基的四元和六元竹荪的合成。bambusuril 门户上的所有硝基都可以转化为氨基官能团，这为大环提供了水溶性并允许它们进一步修饰。例如，我们已经证明了竹柳上的氨基转化为相应的脲官能化竹柳衍生物。我们还报告了第一个仅带有两个官能团的竹子的例子，
• W(CO)₆-Catalyzed Oxidative Carbonylation of Primary Amines to N,N‘-Disubstituted Ureas in Single or Biphasic Solvent Systems. Optimization and Functional Group Compatibility Studies
  作者：Jennifer E. McCusker、A. Denise Main、Kirsten S. Johnson、Cara A. Grasso、Lisa McElwee-White

  DOI：10.1021/jo000364+

  日期：2000.8.1

  Primary amines undergo carbonylation to N,N'-disubstituted ureas using W(CO)(6) as the catalyst, IZ as the oxidant, and CO as the carbonyl source. Preparation of various N,N'-disubstituted ureas from aliphatic primary amines, RNH2 (R = n-Pr, n-Bu, i-Pr, sec-Bu, or t-Bu), was achieved in good to excellent yields. Studies of functional group compatibility using a series of substituted benzylamines demonstrated broad tolerance of functionality during the carbonylation reaction. Preparation of various N,N'-disubstituted ureas from substituted benzylamines, R-C6H4CH2NH2 (R = H, p-OCH3, p-CO2H, p-CO2Et, p-CH2OH, p-SCH3, p-vinyl, p-Cl, p-Br, m-I, p-NH2, p-NO2, or p-CN), was achieved in good yields. For many substituted benzylamines, yields of ureas were higher when a two-phase CH2Cl2/H(2)o solvent system was used.
• Hafner, Chemische Berichte, 1890, vol. 23, p. 341
  作者：Hafner

  DOI：——

  日期：——