3,4:3',4'-bi(benzo[b]thiophene) | 70160-67-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 3,4:3',4'-bi(benzo[b]thiophene)
• 英文别名: anthra[1,9-bc:5,10-b'c']dithiophene；3,4,3',4'-bibenzo[b]thiophene；4,12-dithiapentacyclo[8.6.1.12,5.013,17.09,18]octadeca-1(17),2,5,7,9(18),10,13,15-octaene
• CAS: 70160-67-7
• 化学式: C₁₆H₈S₂
• 分子量: 264.372
• InChiKey: JSHGFUHRFYURGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,4:3',4'-bi(benzo[b]thiophene) 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以100%的产率得到1,6-dibromoanthra[1,9-bc:5,10-b'c']dithiophene
  参考文献：
  名称：

  BIBENZOTHIOPHENE DERIVATIVES

  摘要：

  提供含有双苯硫、硒或碲结构的化合物，这些化合物具有平面性、刚性共轭结构和高电荷迁移率，因此可用作光学器件、电子器件和集成器件的有机半导体，例如用于薄膜晶体管液晶显示器（LCD）的有机场效应晶体管（OFET）、电子纸、用于平板显示器的有机发光二极管（OLED）、有机射频识别（ORFID）标签、有机光伏（OPV）、传感器器件以及模拟和数字电子学。

  公开号：

  US20090292130A1
• 作为产物：
  描述：

  1,5-二氯蒽醌 在 盐酸 、 manganese dioxide 、 sodium 、 乙酸酐 作用下， 以 乙醇 、 水 为溶剂， 生成 3,4:3',4'-bi(benzo[b]thiophene)
  参考文献：
  名称：

  HOLE TRANSPORT COMPOSITIONS AND RELATED DEVICES AND METHODS (I)

  摘要：

  一种组分，包括：至少一种包含传输空穴核的化合物，其中该核与第一芳胺基团和与第一芳胺基团不同的第二芳胺基团共价键合，且该化合物与至少一种难溶性基团共价键合，其中该难溶性基团与传输空穴核、第一芳胺基团、第二芳胺基团或其组合之一共价键合，且该化合物的分子量约为5,000克/摩尔或更低。芳胺化合物的混合物，包括芴核化合物，当涂覆到空穴注入层时，可以提供良好的膜形成和稳定性。 OLEDs的溶液处理是一个特别重要的应用。

  公开号：

  US20120001127A1

文献信息

• A ratiometric fluorescence sensor for caffeine
  作者：Nicolas Luisier、Albert Ruggi、Stephan N. Steinmann、Laurane Favre、Nicolas Gaeng、Clémence Corminboeuf、Kay Severin

  DOI：10.1039/c2ob26117k

  日期：——

  The dye disodium 3,4:3′,4′-bibenzo[b]thiophene-2,2′-disulfonate can be used as a molecular probe for the fluorimetric detection of caffeine in aqueous solution. The fluorescence response is attributed to non-covalent interactions of caffeine with the dye in the ground state and in the excited state. The bimodal interaction allows performing ratiometric measurements with very good selectivity over structurally related analytes. The dye was also used to develop a simple test strip for the visual differentiation of normal and decaffeinated coffee with a standard UV lamp.

  染料 3,4:3′,4′-联苯并[b]噻吩-2,2′-二磺酸钠可用作分子探针，对水溶液中的咖啡因进行荧光检测。这种荧光反应归因于咖啡因在基态和激发态下与染料的非共价相互作用。这种双模相互作用允许对结构相关的分析物进行选择性非常好的比率测量。该染料还被用于开发一种简单的测试条，以便用标准紫外灯目测区分正常咖啡和无咖啡因咖啡。
• ORGANIC ELECTRONIC DEVICES AND POLYMERS, INCLUDING PHOTOVOLTAIC CELLS AND DIKETONE-BASED POLYMERS
  申请人：Brown Christopher T.

  公开号：US20110204341A1

  公开（公告）日：2011-08-25

  Polymers which can be used in p-type materials for organic electronic devices and photovoltaic cells. Compounds, monomers, dimers, trimers, and polymers comprising: Good photovoltaic efficiency and lifetime can be achieved. The R group can provide solubility, environmental stability, and fine tuning of spectroscopic and/or electronic properties. Different polymer microstructures can be prepared which encourage multiple band gaps and broad and strong absorptions. The carbonyl can interact with adjacent thiophene rings to provide backbone with rigidity, induce planarity, and reduce and/or eliminate intramolecular chain twisting defects. Polymers comprising benzodithiophene and/or benzothiadiazole structures can show particularly high performance.

  可以用于有机电子器件和光伏电池的p型材料的高分子。化合物，单体，二聚体，三聚体和聚合物包括：可以实现良好的光伏效率和寿命。R基团可以提供可溶性，环境稳定性和光谱和/或电子性质的微调。可以制备不同的高分子微结构，以鼓励多重带隙和广泛而强烈的吸收。羰基可以与相邻的噻吩环相互作用，提供具有刚性的骨架，诱导平面性，并减少和/或消除分子内链扭曲缺陷。包含苯并噻吩和/或苯并噻二唑结构的高分子可以显示出特别高的性能。
• HOLE TRANSPORT COMPOSITIONS AND RELATED DEVICES AMD METHODS (II)
  申请人：Brown Christopher T.

  公开号：US20120003790A1

  公开（公告）日：2012-01-05

  A composition comprising: at least one compound comprising a hole transporting core, wherein the core is covalently bonded to a first arylamine group and also covalently bonded to a second arylamine group different from the first, and wherein the compound is covalently bonded to at least one intractability group, wherein the intractability group is covalently bonded to the hole transporting core, the first arylamine group, the second arylamine group, or a combination thereof, and wherein the compound has a molecular weight of about 5,000 g/mole or less. Blended mixtures of arylamine compounds, including fluorene core compounds, can provide good film formation and stability when coated onto hole injection layers. Solution processing of OLEDs is a particularly important application.

  一种组合物，包括：至少一种包含空穴传输核的化合物，其中该核与第一芳胺基团共价键合，并且也与第二个与第一不同的芳胺基团共价键合，且该化合物与至少一个难处理性基团共价键合，其中该难处理性基团与空穴传输核、第一芳胺基团、第二芳胺基团或其中的组合物共价键合，且该化合物的分子量约为5,000 g/mol或更低。芳胺化合物的混合物，包括芴核化合物，可以在涂覆空穴注入层时提供良好的膜形成和稳定性。 OLED的溶液加工是一个特别重要的应用。
• HOLE TRANSPORT COMPOSITIONS AND RELATED DEVICES AND METHODS (II)
  申请人：Plextronics, Inc.

  公开号：US20130344648A1

  公开（公告）日：2013-12-26

  A composition comprising: at least one compound comprising a hole transporting core, wherein the core is covalently bonded to a first arylamine group and also covalently bonded to a second arylamine group different from the first, and wherein the compound is covalently bonded to at least one intractability group, wherein the intractability group is covalently bonded to the hole transporting core, the first arylamine group, the second arylamine group, or a combination thereof, and wherein the compound has a molecular weight of about 5,000 g/mole or less. Blended mixtures of arylamine compounds, including fluorene core compounds, can provide good film formation and stability when coated onto hole injection layers. Solution processing of OLEDs is a particularly important application.

  一种组合物，包括：至少一种包含空穴传输核的化合物，其中该核与第一芳胺基团共价键合，并且还与第二芳胺基团不同，其中该化合物与至少一个难处理性基团共价键合，其中该难处理性基团与空穴传输核、第一芳胺基团、第二芳胺基团或其组合物共价键合，该化合物的分子量约为5,000克/摩尔或更低。芳胺化合物的混合物，包括芴核化合物，可以在涂覆孔注入层时提供良好的膜形成和稳定性。 OLED的溶液处理是一个特别重要的应用。
• Hole transport compositions and related devices and methods (II)
  申请人：Plextronics, Inc.

  公开号：US08815639B2

  公开（公告）日：2014-08-26

  A composition comprising: at least one compound comprising a hole transporting core, wherein the core is covalently bonded to a first arylamine group and also covalently bonded to a second arylamine group different from the first, and wherein the compound is covalently bonded to at least one intractability group, wherein the intractability group is covalently bonded to the hole transporting core, the first arylamine group, the second arylamine group, or a combination thereof, and wherein the compound has a molecular weight of about 5,000 g/mole or less. Blended mixtures of arylamine compounds, including fluorene core compounds, can provide good film formation and stability when coated onto hole injection layers. Solution processing of OLEDs is a particularly important application.

  一种组合物，包括至少一种包含空穴传输核的化合物，其中该核与第一芳胺基团共价键合，同时也与第二个与第一不同的芳胺基团共价键合，该化合物与至少一个不易处理的基团共价键合，其中该不易处理的基团与空穴传输核、第一芳胺基团、第二芳胺基团或其组合共价键合，该化合物的分子量约为5,000克/摩尔或更低。芳胺化合物的混合物，包括芴核化合物，可以在涂覆空穴注入层时提供良好的薄膜形成和稳定性。 OLED的溶液处理是一个特别重要的应用。