(Z)-prop-1-ene-1,2,3-tricarbohydrazide | 6635-36-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (Z)-prop-1-ene-1,2,3-tricarbohydrazide
• CAS: 6635-36-5
• 化学式: C₆H₁₂N₆O₃
• 分子量: 216.2
• InChiKey: CATDCCZZTIKDOE-IWQZZHSRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  165
• 氢给体数：
  6
• 氢受体数：
  6

文献信息

• LAYERED RUBBER PRODUCT
  申请人：ZEON CORPORATION

  公开号：EP1795341A1

  公开（公告）日：2007-06-13

  A rubber laminate comprised of a cross-linked rubber layer containing a carboxyl-group containing nitrile copolymer rubber (A), a carboxyl-group containing acryl-based polymer (B), and a specific phosphonium salt and a fluorine-based polymer layer. Preferably, the carboxyl-group content per 100 grams of the (A) ingredient is 2×10-3 to 1×10-1 equivalents and the carboxyl-group content per 100 grams of the (B) ingredient is 4×10-4 to 1×10-1 equivalents, the (A) ingredient and (B) ingredient are in a weight ratio of 40:60 to 90:10, and the phosphonium salt content in the cross-linked rubber layer is 0.5 to 10 parts by weight per 100 parts by weight of the total of the (A) ingredient and (B) ingredient. According to the present invention, there is provided a rubber laminate excellent in oil resistance and gasoline permeation resistance plus tensile strength, low compression set, and other mechanical characteristics, ozone resistance, and interlayer adhesion.

  一种橡胶层压板，由含有含羧基的丁腈共聚物橡胶（A）、含羧基的丙烯基聚合物（B）、特定的鏻盐和氟基聚合物层的交联橡胶层组成。优选地，每 100 克（A）成分中的羧基含量为 2×10-3 至 1×10-1 当量，每 100 克（B）成分中的羧基含量为 4×10-4 至 1×10-1 当量，（A）成分和（B）成分的重量比为 40:60 至 90:10，交联橡胶层中的鏻盐含量为 0.5 至 10 份（按重量计），每 100 份（按重量计）(A)成分和(B)成分的总和。根据本发明，提供了一种耐油性和耐汽油渗透性优异的橡胶层压板，同时还具有拉伸强度、低压缩永久变形和其他机械特性、耐臭氧性和层间粘合性。
• Removable Water-Dispersible Acrylic Pressure-Sensitive Adhesive Composition and Pressure-Sensitive Adhesive Sheet
  申请人：Nitto Denko Corporation

  公开号：EP2492330A2

  公开（公告）日：2012-08-29

  A removable water-dispersible acrylic pressure-sensitive adhesive composition according to the present invention includes an acrylic emulsion polymer (A), a water-insoluble crosslinking agent (B), and a carboxylic-acid-containing acrylic polymer (C). The polymer (A) includes a (meth)acrylic alkyl ester and a carboxyl-containing unsaturated monomer as essential constitutive monomers and has a content of the (meth)acrylic alkyl ester of 70 to 99.5 percent by weight and a content of the carboxyl-containing unsaturated monomer of 0.5 to 10 percent by weight, each based on the total amount of constitutive monomers. The polymer (C) includes (meth)acrylic acid as an essential constitutive monomer and has a total content of acrylic acid and methacrylic acid of 11 percent by weight or more based on the total amount of constitutive monomers.

  根据本发明的可移除水分散丙烯酸压敏胶组合物包括丙烯酸乳液聚合物（A）、不溶于水的交联剂（B）和含羧酸的丙烯酸聚合物（C）。聚合物（A）包括作为基本组成单体的（甲基）丙烯酸烷基酯和含羧基不饱和单体，根据组成单体的总量，（甲基）丙烯酸烷基酯的含量为 70%至 99.5%（重量百分比），含羧基不饱和单体的含量为 0.5%至 10%（重量百分比）。聚合物(C)包括(甲基)丙烯酸作为基本组成单体，其丙烯酸和甲基丙烯酸的总含量为组成单体总量的 11%（重量）或以上。
• Removable water-dispersible acrylic pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet
  申请人：Nitto Denko Corporation

  公开号：EP2511357A1

  公开（公告）日：2012-10-17

  A removable water-dispersible acrylic pressure-sensitive adhesive composition according to the present invention includes an acrylic emulsion polymer (A) including, as essential constitutive monomers, a (meth)acrylic alkyl ester in a content of 70 to 99.5 percent by weight, and a carboxyl-containing unsaturated monomer in a content of 0.5 to 10 percent by weight, each based on the total amount of constitutive monomers; a waterw-insoluble crosslinking agent (B); an acetylenic diol compound (C); and a compound (D) represented by chemical formula CRaO-(PO)l-(EO)m-(PO)n-Rb]. The acetylenic diol compound (C) has a HLB value of less than 13.

  根据本发明的一种可移除的水分散丙烯酸压敏胶组合物包括丙烯酸乳液聚合物（A），作为必要的组成单体，包括含量为70%至99.5%（按重量计）的(甲基)丙烯酸烷基酯和含羧基的不饱和单体（按重量计，各占组成单体总量的 0.5%至 10%）；不溶于水的交联剂 (B)；乙炔二元醇化合物 (C)；以及由化学式 CRaO-(PO)l-(EO)m-(PO)n-Rb] 表示的化合物 (D)。乙炔二元醇化合物（C）的 HLB 值小于 13。
• WATER-DISPERSIBLE ACRYLIC ADHESIVE AGENT COMPOSITION AND ADHESIVE SHEET
  申请人：Nitto Denko Corporation

  公开号：EP2562226A1

  公开（公告）日：2013-02-27

  Provided are a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer which has excellent resistance to increase in adhesive strength and a good appearance and less causes staining; and a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition. The water-dispersible acrylic pressure-sensitive adhesive composition includes an acrylic emulsion polymer (A) formed from constitutive monomers essentially containing 70 to 99.5 percent by weight of a (meth)acrylic alkyl ester and 0.5 to 10 percent by weight of a carboxyl-containing unsaturated monomer; and a compound (B) represented by following Formula (I):         R1O-(PO)a-(EO)b-(PO)c-R2     (I) wherein R1 and R2 each represent a linear or branched chain alkyl group or hydrogen atom; PO represents oxypropylene group; EO represents oxyethylene group; and "a," "b," and "c" are each a positive integer, where EO and POs are added in a block manner.

  本发明提供了一种可遇水分散的丙烯酸压敏胶组合物，该组合物能够形成压敏胶层，该压敏胶层具有极佳的抗粘合强度增加能力和良好的外观，并且不易沾污；还提供了一种压敏胶片，该压敏胶片具有由该压敏胶组合物形成的压敏胶层。水可分散丙烯酸压敏胶组合物包括丙烯酸乳液聚合物 (A)，该聚合物由基本上含有 70% 至 99.5% 重量百分比的 (甲基)丙烯酸烷基酯和 0.5% 至 10% 重量百分比的含羧基不饱和单体的组成单体形成；以及由下式 (I) 表示的化合物 (B)： R1O-(PO)a-(EO)b-(PO)c-R2 (I) 其中 R1 和 R2 分别代表直链或支链烷基或氢原子；PO 代表氧丙烯基团；EO 代表氧乙烯基团；"a"、"b "和 "c "均为正整数，其中 EO 和 PO 是以嵌段方式添加的。
• REMOVABLE WATER-DISPERSING ACRYLIC ADHESIVE COMPOSITION AND ADHESIVE SHEET
  申请人：Nitto Denko Corporation

  公开号：EP2562227A1

  公开（公告）日：2013-02-27

  Provided is a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a removable pressure-sensitive adhesive layer which has satisfactory resistance to increase in adhesive strength and a good appearance and less causes staining on an adherend. The removable water-dispersible acrylic pressure-sensitive adhesive composition includes an acrylic emulsion polymer (A) formed from constitutive monomers essentially including 70 to 99.5 percent by weight of a (meth)acrylic alkyl ester and 0.5 to 10 percent by weight of a carboxyl-containing unsaturated monomer based on the total amount of the constitutive monomers; a water-insoluble crosslinking agent (B); an acetylenic diol compound (C); and a specific polyether defoaming agent (D). The acetylenic diol compound (C) has an HLB of less than 13, and the polyether defoaming agent (D) has a PO in a content of from 70 to 100 percent by weight and a number-average molecular weight of from 1200 to 4000.

  本发明提供了一种可遇水分散的丙烯酸压敏胶组合物，该组合物能够形成可移除的压敏胶层，具有令人满意的抗粘合强度增加能力和良好的外观，并且不易在被粘物上造成污渍。可移除的水分散丙烯酸压敏胶组合物包括丙烯酸乳液聚合物（A），该聚合物由组成单体形成，以组成单体总量为基准，组成单体基本上包括 70%至 99.5%（重量百分比）的（甲基）丙烯酸烷基酯和 0.5%至 10%（重量百分比）的含羧基不饱和单体；水不溶性交联剂（B）；乙炔二元醇化合物（C）；以及特定聚醚消泡剂（D）。乙炔二元醇化合物（C）的 HLB 小于 13，聚醚消泡剂（D）的 PO 含量为 70%至 100%（重量百分比），数均分子量为 1200 至 4000。