trans-1,2,3,3-tetrachloropropene | 34495-84-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: trans-1,2,3,3-tetrachloropropene
• 英文别名: (E)-1,2,3,3-tetrachloro-propene；1c,2,3,3-tetrachloro-propene；1c,2,3,3-Tetrachlor-propen；1,2,3,3-tetrachloropropene；trans-1,2,3,3-Tetrachlor-1-propen；trans-1,2,3,3-Tetrachlor-propen；trans-1,1,2,3-Tetrachloro-2-propene；(E)-1,2,3,3-tetrachloroprop-1-ene
• CAS: 34495-84-6
• 化学式: C₃H₂Cl₄
• 分子量: 179.861
• InChiKey: JUGQRTGGLWOBPG-OWOJBTEDSA-N

物化性质

• 沸点：
  165.0±0.0 °C(Predicted)
• 密度：
  1.532±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  7
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trans-1,2,3,3-tetrachloropropene 在 硫酸 作用下， 以 水 为溶剂， 生成 2-chloromalondialdehyde
  参考文献：
  名称：

  Process for making diaryl pyridines useful as cox-2 inhibitors

  摘要：

  这项发明涵盖了一种制备公式I化合物的过程，用于治疗环氧合酶-2介导的疾病。

  公开号：

  US06369275B1
• 作为产物：
  描述：

  1,1,2,3,3-五氯丙烷 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成 trans-1,2,3,3-tetrachloropropene
  参考文献：
  名称：

  Preparation of 1,2,3,3-tetrachloropropene

  摘要：

  1,1,2,3,3-五氯丙烷的脱氢氯化反应，以水溶性碱金属氢氧化物为催化剂，在几乎不加乙醇的情况下进行。1,2,3,3-四氯丙烯是从反应混合物中在几乎不加醚的情况下回收的。首选的回收方法是蒸汽蒸馏和闪蒸。

  公开号：

  US05811605A1

文献信息

• Process For Producing Chlorinated Hydrocarbons
  申请人：Axiall Ohio, Inc.

  公开号：US20140206911A1

  公开（公告）日：2014-07-24

  The preparation of chlorinated hydrocarbons, such as pentachloropropanes, such as 1,1,1,2,3-pentachloropropane, from tetrachloropropanes, such as 1,1,1,3-tetrachloropropane, in the presence of a polyvalent antimony compound that includes a pentavalent antimony compound, such as antimony pentachloride, is described. Also described are methods for preparing optionally chlorinated alkenes, such as, tetrachloropropenes, from chlorinated alkanes, such as pentachloropropanes, in the presence of ferric chloride and a polyvalent antimony compound that includes a pentavalent antimony compound.

  氯代烃的制备，例如五氯丙烷，如1,1,1,2,3-五氯丙烷，从四氯丙烷，如1,1,1,3-四氯丙烷，在存在包括五价锑化合物的多价锑化合物的情况下进行，例如五氯化锑。还描述了在存在三氯化铁和包括五价锑化合物的多价锑化合物的情况下，从氯代烷烃，如五氯丙烷，制备可选氯代烯烃，如四氯丙烯的方法。
• METHOD FOR PRODUCING 1,2-DICHLORO-3,3-DIFLUORO-1-PROPENE AND SOLVENT COMPOSITION
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：US20200369584A1

  公开（公告）日：2020-11-26

  By fluorinating 1,2,3,3-tetrachloro-1-propene (1230xd) using hydrogen fluoride as a fluorinating agent, an efficient method for producing 1,2-dichloro-3,3-difluoro-1-propene (1232xd) is provided. Through this composition including 1232xd, there are also provided an environmentally friendly composition having excellent ability to dissolve various organic matters, a method for cleaning an article using the composition, a method for producing a lubricant solution using the composition, and a method for producing a component provided with a lubricant coating film.

  通过使用氢氟酸作为氟化剂对1,2,3,3-四氯-1-丙烯（1230xd）进行氟化，提供了一种生产1,2-二氯-3,3-二氟-1-丙烯（1232xd）的高效方法。通过包括1232xd的这种组合物，还提供了一种具有优异溶解各种有机物能力的环保组合物、使用该组合物清洁物品的方法、使用该组合物生产润滑剂溶液的方法，以及生产具有润滑涂层膜的零件的方法。
• PROCESS FOR THE PRODUCTION OF CHLORINATED AND/OR FLUORINATED PROPENES
  申请人：Tirtowidjojo Max M.

  公开号：US20110083955A1

  公开（公告）日：2011-04-14

  The present invention provides one-step processes for the production of chlorinated and/or fluorinated propenes. The processes provide good product yield with low, e.g., less than about 20%, or even less than 10%, concentrations of residues/by-products. Advantageously, the processes may be conducted at low temperatures than 500° C. so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts or initiators may provide additional enhancements to conversion rates and selectivity, as may adjustments to the molar ratio of the reactants.

  本发明提供了用于生产氯化和/或氟化丙烯的一步法工艺。这些工艺提供了良好的产品产量，残留物/副产品的浓度低，例如低于约20%，甚至低于10%。优点是，这些工艺可以在低于500°C的低温下进行，从而提供节能，并且可以在较高的压力下进行，以实现较高的产量。使用催化剂或引发剂可能会提供对转化率和选择性的额外增强，调整反应物的摩尔比也可能有所帮助。
• Method of combatting plants which infest maize cultivations without
  申请人：Montedison S.p.A.

  公开号：US04311516A1

  公开（公告）日：1982-01-19

  Plants which infest maize cultivations are successfully combatted without damage to the maize by treating the infested maize with herbicidal esters of N,N-disubstituted glycines and an antidote having the general formula ##STR1## in which X is H or halogen; and R is H, C.sub.1 -C.sub.5 alkyl, poly (haloalkyl), alkenyl, poly (haloalkenyl), alkinyl, (poly) haloalkinyl all containing carbon atoms in a number ranging from 2 to 5, or phenyl.

  玉米种植园中的植物，通过使用具有一般公式##STR1##的N,N-二取代甘氨酸酯类除草剂和具有抗毒性的解毒剂处理受感染的玉米，成功地被消灭，而不会对玉米造成损害。其中X为H或卤素；R为H、C.sub.1-C.sub.5烷基、聚（卤代烷基）、烯烃基、聚（卤代烯烃基）、炔烃基、（聚）卤代炔烃基，全部含有2至5个碳原子，或苯基。
• Dichloroacetamides which are antidotes for protecting maize against the
  申请人：Montedison S.p.A.

  公开号：US04195036A1

  公开（公告）日：1980-03-25

  There are disclosed dichloroacetamides which are antidotes that are particularly and specifically active against the toxic action exerted on maize cultivations by herbicidal esters of N,N-disubstituted glycines; methods for preparing the antidotes, and compositions comprising them, in particular compositions comprising both the antidotes and the herbicidal esters of N,N-disubstituted glycines.

  披露了二氯乙酰胺类抗毒剂，这些抗毒剂特别有效地针对除草酯类对玉米种植的毒性作用；制备抗毒剂的方法，以及包括它们的组合物，特别是包括抗毒剂和N，N-二取代甘氨酸酯类除草剂的组合物。