2-Hydroxy-3-(4-dimethoxymethylphenoxy)propyl methacrylate | 135053-26-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Hydroxy-3-(4-dimethoxymethylphenoxy)propyl methacrylate
• 英文别名: [3-[4-(dimethoxymethyl)phenoxy]-2-hydroxypropyl] 2-methylprop-2-enoate
• CAS: 135053-26-8
• 化学式: C₁₆H₂₂O₆
• 分子量: 310.34
• InChiKey: LNPBSKRKCPJKBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  74.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-(dimethoxymethyl)phenol 、 甲基丙烯酸缩水甘油酯 在 苄基三丁基氯化铵 氮气 、 二氯甲烷 、 sodium hydroxide 、 magnesium sulfate 作用下， 反应 5.58h， 生成 2-Hydroxy-3-(4-dimethoxymethylphenoxy)propyl methacrylate
  参考文献：
  名称：

  Derivatized and/or crosslinked products from acetal- and

  摘要：

  制备了一种多糖衍生物接枝聚合物、一种多糖交联接枝聚合物和一种多糖衍生物交联接枝聚合物。衍生物聚合物的结构为Sacch-g-[(M--CH.dbd.N--Y).sub.x -g-[(M).sub.q]；交联聚合物的结构为Sacch-g-[(M--CH.dbd.N).sub.z -P].sub.w -g-[(M).sub.q]或Sacch-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q]；衍生和交联聚合物的结构为Sacch-g-[(M--CH.dbd.N--Y).sub.x]-g-[(M--CH.dbd.N)-P]-g-[(M).sub.q]或Sacch-g-[(M--CH.dbd.N--Y).sub.x]-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q]。Sacch代表淀粉、胶或纤维素等多糖；g代表接枝；M代表一个或多个具有乙烯或烯丙基不饱和单体，其中至少一个含有缩醛或醛基；P代表来自含有多个主要胺基或酮基的试剂的多价残基；--N.dbd.代表当P的一个主要胺基与单体重复单元M的缩醛或醛基反应时形成的基团；13 CH.dbd.代表当P的一个酮基与单体重复单元M的缩醛或醛基反应时形成的基团；x至少为1；z至少为2；w至少为1；q为0或更大。

  公开号：

  US05049634A1

文献信息

• Monomers and polymers containing acetal and aldehyde groups
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0418917A2

  公开（公告）日：1991-03-27

  Various novel acetal- and aldehyde-containing monomers are prepared. They can be polymerized and copolymerized by conventional polymerization techniques. The polymers contain repeating units derived from one or more ethylenically or allylically unsaturated monomers containing an acetal group or aldehyde group and optionally one or more repeating units derived from ethylenically or allylically unsaturated monomers other than the acetal-containing or aldehyde-containing monomer such as ethylene, vinyl acetate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, methyl methacrylate or acrylic acid. Aqueous emulsions of polymers containing the acetal-containing monomers and a hydroxy-containing monomer are useful as binders for nonwoven fabrics.

  制备了各种新型含醛单体。它们可以通过传统聚合技术进行聚合和共聚。乙烯、乙酸乙烯酯、丙烯酸乙酯、丙烯酸丁酯、丙烯酸 2-乙基己酯、丙烯酸羟乙酯、丙烯酸羟丙酯、甲基丙烯酸甲酯或丙烯酸。含缩醛单体和含羟基单体的聚合物水乳液可用作无纺布的粘合剂。
• US5049634A
  申请人：——

  公开号：US5049634A

  公开（公告）日：1991-09-17
• US5258477A
  申请人：——

  公开号：US5258477A

  公开（公告）日：1993-11-02
• Derivatized and/or crosslinked products from acetal- and
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：US05049634A1

  公开（公告）日：1991-09-17

  A derivatized graft polymer of a polysaccharide, a crosslinked graft polymer of a polysaccharide, and a derivatized and crosslinked graft polymer of a polysaccharide are prepared. The derivatized polymer has the structure Sacch-g-[(M--CH.dbd.N--Y).sub.x -g-[(M).sub.q ]; the crosslinked polymer has the structure Sacch-g-[(M--CH.dbd.N).sub.z -P].sub.w -g-[(M).sub.q ] or Sacch-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q ]; the derivatized and crosslinked polymer has the structure Sacch-g-[(M--CH.dbd.N--Y).sub.x ]-g-[(M--CH.dbd.N)-P]-g-[(M).sub.q ] or Sacch-g-[(M--CH.dbd.N--Y).sub.x ]-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q ]. Sacch represents a polysaccharide such as starch, gum, or cellulose; g-represents a graft; M represents one or more ethylenically or allylically unsaturated monomers, at least one of which contains an acetal or aldehyde; P represents a multivalen residue from a reagent containing more than one primary amine group or ketone group; --N.dbd. represents the group formed when one primary amine group of P reacts with the acetal or aldehyde group of the monomer repecting unit M; 13 CH.dbd. represents the group formed when one of the ketone groups of P reacts with the acetal or aldehyde group of the monomer repeating unit M; x is at least 1; z is at least 2; w is at least 1; and q is 0 or greater.

  制备了一种多糖衍生物接枝聚合物、一种多糖交联接枝聚合物和一种多糖衍生物交联接枝聚合物。衍生物聚合物的结构为Sacch-g-[(M--CH.dbd.N--Y).sub.x -g-[(M).sub.q]；交联聚合物的结构为Sacch-g-[(M--CH.dbd.N).sub.z -P].sub.w -g-[(M).sub.q]或Sacch-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q]；衍生和交联聚合物的结构为Sacch-g-[(M--CH.dbd.N--Y).sub.x]-g-[(M--CH.dbd.N)-P]-g-[(M).sub.q]或Sacch-g-[(M--CH.dbd.N--Y).sub.x]-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q]。Sacch代表淀粉、胶或纤维素等多糖；g代表接枝；M代表一个或多个具有乙烯或烯丙基不饱和单体，其中至少一个含有缩醛或醛基；P代表来自含有多个主要胺基或酮基的试剂的多价残基；--N.dbd.代表当P的一个主要胺基与单体重复单元M的缩醛或醛基反应时形成的基团；13 CH.dbd.代表当P的一个酮基与单体重复单元M的缩醛或醛基反应时形成的基团；x至少为1；z至少为2；w至少为1；q为0或更大。