1-methyl cyclopentyl (meth)acrylate | 102617-53-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-methyl cyclopentyl (meth)acrylate
• 英文别名: Methyl 2-(cyclopentylmethyl)prop-2-enoate；methyl 2-(cyclopentylmethyl)prop-2-enoate
• CAS: 102617-53-8
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: KCLDFXGVPKGXFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(溴甲基)丙烯酸甲酯 反应 26.0h， 生成 1-methyl cyclopentyl (meth)acrylate
  参考文献：
  名称：

  Use of allylic triflones for allylation of C-H bonds

  摘要：

  Allylic triflones react with THF and cyclohexane and related molecules to undergo a trifluoromethyl radical mediated C-H functionalization reaction. Due to polar effects, the reactions benefit from the presence of electron-withdrawing group at the 2-position of the allylic triflones. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)00775-8

文献信息

• Metzger, Juergen O.; Klenke, Kurt, Chemische Berichte, 1990, vol. 123, # 4, p. 875 - 879
  作者：Metzger, Juergen O.、Klenke, Kurt

  DOI：——

  日期：——
• Prostereogenic Face and Orientation Selective Oxidative Coupling Reaction between Methyl Methacrylate and 2,5-Dihydrofuran Catalyzed by a Ruthenium(0) Compound
  作者：Yuki Hiroi、Nobuyuki Komine、Masafumi Hirano、Sanshiro Komiya

  DOI：10.1021/om200091n

  日期：2011.3.28

  We disclose the first prostereogenic face and orientational control of coordinated olefins in an oxidative coupling reaction at a transition-metal center. Chemo-, regio-, and diastereoselective cross-dimerization between methyl methacrylate (MMA) and 2,5-dihydrofuran is catalyzed by Ru(eta(6)-naphthalene)(eta(4)-1,5-COD) (1; S mol %) at 0 degrees C in 24 h without use of solvent to give methyl rac-(2S)-3-[(3R)-2,3-dihydrofuran-3-yl]-2-methy1propionate (2a) in 81% yield.
• Hartmanns, Joerg; Klenke, Kurt; Metzger, Juergen O., Chemische Berichte, 1986, vol. 119, # 2, p. 488 - 499
  作者：Hartmanns, Joerg、Klenke, Kurt、Metzger, Juergen O.

  DOI：——

  日期：——
• Use of allylic triflones for allylation of C-H bonds
  作者：Jason Xiang、Jerry Evarts、Alexey Rivkin、Dennis P. Curran、P.L. Fuchs

  DOI：10.1016/s0040-4039(98)00775-8

  日期：1998.6

  Allylic triflones react with THF and cyclohexane and related molecules to undergo a trifluoromethyl radical mediated C-H functionalization reaction. Due to polar effects, the reactions benefit from the presence of electron-withdrawing group at the 2-position of the allylic triflones. (C) 1998 Elsevier Science Ltd. All rights reserved.