ethoxymethyl formate | 32665-20-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: ethoxymethyl formate
• 英文别名: formic acid ethoxymethyl ester；Ameisensaeure-aethoxymethylester
• CAS: 32665-20-6
• 化学式: C₄H₈O₃
• 分子量: 104.106
• InChiKey: PSMNQBXDJUFDBY-UHFFFAOYSA-N

物化性质

• 沸点：
  114-116 °C
• 密度：
  1.0537 g/cm3(Temp: 0 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  7
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  氯甲基乙醚 、 alkaline earth salt of/the/ methylsulfuric acid 生成 ethoxymethyl formate
  参考文献：
  名称：

  Wedekind, Chemische Berichte, 1903, vol. 36, p. 1384

  摘要：

  DOI：

文献信息

• Farren et al., Journal of the American Chemical Society, 1925, vol. 47, p. 2422
  作者：Farren et al.

  DOI：——

  日期：——
• Kinetic Studies on the Reactions of Hydroxyl Radicals with a Series of Alkoxy Esters
  作者：S. M. O'Donnel、H. W. Sidebottom、J. C. Wenger、A. Mellouki、G. Le Bras

  DOI：10.1021/jp048782w

  日期：2004.9.1

  Rate coefficients for the gas-phase reactions of hydroxyl radicals with a series of alkoxy esters of structure RC(O)O(CH2)(n)OR', where R = H, CH3, R' = CH3, C2H5, and n = 1-2, have been determined with use of relative and absolute rate methods. Relative rate measurements were performed in a Teflon reaction chamber at 298 +/- 2 K and atmospheric pressure. Absolute rate measurements were made with pulsed laser photolysislaser induced fluorescence over the temperature range 263-372 K at pressures of similar to100 Torr. The kinetic data are used to derive Arrhenius expressions for the reactions and tropospheric lifetimes for the alkoxy esters. The reactivity of the alkoxy esters is discussed in light of the current understanding of the atmospheric chemistry of oxygenated organic compounds.
• Pihlaja, Kalevi; Lampi, Aija, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1986, vol. 40, # 3, p. 196 - 199
  作者：Pihlaja, Kalevi、Lampi, Aija

  DOI：——

  日期：——
• Palomaa; Herna, Chemische Berichte, 1933, vol. 66, p. 309
  作者：Palomaa、Herna

  DOI：——

  日期：——
• Wedekind, Chemische Berichte, 1903, vol. 36, p. 1384
  作者：Wedekind

  DOI：——

  日期：——