1-(1,1,2,3,3,3-hexafluoro-propyl)-pyrrole | 830-37-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 1-(1,1,2,3,3,3-hexafluoro-propyl)-pyrrole
• 英文别名: 1-(1,1,2,3,3,3-Hexafluor-propyl)-pyrrol；1-(1,1,2,3,3,3-hexafluoropropyl)pyrrole；N-hexafluoropropylazole
• CAS: 830-37-5
• 化学式: C₇H₅F₆N
• 分子量: 217.114
• InChiKey: MJYVASYHNINIGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  吡咯 在 氢化钾 作用下， 生成 1-(1,1,2,3,3,3-hexafluoro-propyl)-pyrrole
  参考文献：
  名称：

  Organic compounds

  摘要：

  公开号：

  US02861990A1

文献信息

• Synthesis and cycloaddition of N-substituted pyrroles with polyfluorinated substituents
  作者：S. V. Moiseev、N. V. Vasil'ev

  DOI：10.1007/s11172-006-0063-z

  日期：2005.8

  Reactions of N-pyrrolylpotassium with fluorinated electrophiles yielded N-substituted pyrroles containing polyfluoroalkyl, polyfluoroalkenyl, polyfluoroalkylsulfonyl, and polyfluoroaryl substituents. N-Polyfluoro-substituted pyrroles did not isomerize at ≥100 °C; they were found to be reactive in [4+2] cycloaddition reactions with perfluorobut-2-yne.

  N-吡咯基钾与氟化亲电试剂反应，生成了含有多氟烷基、多氟烯基、多氟烷基磺酰基和多氟芳基取代的N-取代吡咯。N-多氟取代的吡咯在≥100°C下不发生异构化；它们被发现能够参与与全氟丁-2-炔的[4+2]环加成反应。
• FLUORINE-CONTAINING POLYMER HAVING HETEROAROMATIC RING
  申请人：Komatsu Yuzo

  公开号：US20090105400A1

  公开（公告）日：2009-04-23

  There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.

  提供了一种含氟聚合物，其具有带有杂环芳香环的离子基，并且可用作由稳定的含氟杂环芳香环化合物组成的材料，还提供了一种具有杂环芳香环的含氟聚合物，可用作上述聚合物或固化剂的起始材料。此外，还提供了一种具有杂环芳香环（如咪唑）的含氟聚合物及其聚合物盐，以及包含该聚合物、聚合物盐和纳米填料的聚合物组合物。
• PROCESS FOR PREPARING HETEROAROMATIC RING COMPOUND HAVING N-Rf GROUP
  申请人：Komatsu Yuzo

  公开号：US20100222598A1

  公开（公告）日：2010-09-02

  There is provided a preparation process in which a N—H group of a heteroaromatic ring compound having a N—H group in its ring is converted directly to a N—Rf group at a high reaction efficiency without using a catalyst. The preparation process is a process for preparing a compound comprising a heteroaromatic ring structure having a N—Rf group (—Rf is a fluorine-containing organic group) in its ring and is characterized in that the heteroaromatic ring compound having a N—H group in its ring is allowed to react with fluoroalkene in the absence of an alkali metal.

  提供了一种制备过程，其中在不使用催化剂的情况下，将具有其环中的N-H基团的杂环芳香化合物的N-H基团直接转化为高反应效率的N-Rf基团。该制备过程是制备具有其环中的N-Rf基团（-Rf是含氟有机基团）的杂环芳香环结构化合物的过程，并且其特征在于，在没有碱金属的情况下，将具有其环中的N-H基团的杂环芳香化合物与氟代烯烃发生反应。
• METHOD FOR PRODUCTION OF HETEROAROMATIC RING COMPOUND HAVING N-Rf GROUP
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1975157A1

  公开（公告）日：2008-10-01

  There is provided a preparation process in which a N-H group of a heteroaromatic ring compound having a N-H group in its ring is converted directly to a N-Rf group at a high reaction efficiency without using a catalyst. The preparation process is a process for preparing a compound comprising a heteroaromatic ring structure having a N-Rf group (-Rf is a fluorine-containing organic group) in its ring and is characterized in that the heteroaromatic ring compound having a N-H group in its ring is allowed to react with fluoroalkene in the absence of an alkali metal.

  本发明提供了一种制备工艺，在该工艺中，环中具有 N-H 基团的杂芳香族环状化合物的 N-H 基团可直接转化为 N-Rf 基团，且反应效率高，无需使用催化剂。该制备工艺是一种制备包含杂芳香族环结构的化合物的工艺，该化合物的环中具有一个 N-Rf 基团（-Rf 是含氟有机基团），其特征在于让环中具有一个 N-H 基团的杂芳香族环化合物在没有碱金属的情况下与氟烯烃反应。
• FLUORINE-CONTAINING POLYMER CONTAINING HETEROAROMATIC RING
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1983008A1

  公开（公告）日：2008-10-22

  There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.

  本发明提供了一种具有离子基团的含氟聚合物，该聚合物具有杂芳香族环，可用作由具有稳定的含氟杂芳香族环的各种杂芳香族环化合物组成的材料，还提供了一种具有杂芳香族环的含氟聚合物，该聚合物可用作上述聚合物的起始材料或固化剂。此外，还提供了一种在侧链中具有咪唑等杂芳环的含氟聚合物、其聚合物盐，以及包含这种聚合物和聚合物盐以及纳米填料的聚合物组合物。