1,1-bis(p-anisyl)hydrazine | 92255-59-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-bis(p-anisyl)hydrazine
• 英文别名: N,N-bis-(4-methoxy-phenyl)-hydrazine；H2NN(p-CH3O-Ph)2；N,N-Bis-(4-methoxy-phenyl)-hydrazin；N,N-Di-(p-methoxyphenyl)-hydrazin = N,N-Dianisylhydrazin；1,1-Di-(p-anisyl)-hydrazin；1,1-Bis(4-methoxyphenyl)hydrazine
• CAS: 92255-59-9
• 化学式: C₁₄H₁₆N₂O₂
• 分子量: 244.293
• InChiKey: DATLWAQKOHHADP-UHFFFAOYSA-N

物化性质

• 熔点：
  111 °C
• 沸点：
  428.1±30.0 °C(Predicted)
• 密度：
  1.167±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  47.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,1-bis(p-anisyl)hydrazine 、 六氯化钨 、 乙腈 以 二氯甲烷 为溶剂， 生成 (MeCN)WCl4(NN(p-CH3O-Ph)2)
  参考文献：
  名称：

  Groups 5 and 6 Terminal Hydrazido(2−) Complexes: N_β Substituent Effects on Ligand-to-Metal Charge-Transfer Energies and Oxidation States

  摘要：

  Brightly colored terminal hydrazido(2-) (dme)MCl3(NNR2) (dme = 1,2-dimethoxyethane; M = Nb, Ta; R = alkyl, aryl) or (MeCN)WCl4(NNR2) complexes have been synthesized and characterized. Perturbing the electronic environment of the beta (NR2) nitrogen affects the energy of the lowest-energy charge-transfer (CT) transition in these complexes. For group 5 complexes, increasing the energy of the N-beta lone pair decreases the ligand-to-metal CT (LMCT) energy, except for electron-rich niobium diallcylhydrazides, which pyramidalize N-beta in order to reduce the overlap between the Nb=N-alpha pi bond and the N-beta lone pair. For W complexes, increasing the energy of N-beta eventually leads to reduction from formally [W-VI N-NR2] with a hydraziclo(2-) ligand to [W-IV=N=NR2] with a neutral 1,1-diazene ligand. The photophysical properties of these complexes highlight the potential redox noninnocence of hydrazido ligands, which could lead to ligand- and/or metal-based redox chemistry in early transition metal derivatives.

  DOI：

  10.1021/ja302275j
• 作为产物：
  描述：

  4'-甲氧基乙酰苯胺 在 盐酸 、 乙醇 、 水 、 碘 、 铜 、 potassium carbonate 、 溶剂黄146 、 硝基苯 、 锌 、 sodium nitrite 作用下， 生成 1,1-bis(p-anisyl)hydrazine
  参考文献：
  名称：

  Wieland, Chemische Berichte, 1908, vol. 41, p. 3486

  摘要：

  DOI：

文献信息

• An Easy Route to<i>N</i>,<i>N</i>-Diarylhydrazines by Cu-Catalyzed Arylation of Pyridine-2-carbaldehyde Hydrazones with Aryl Halides
  作者：Wei Wu、Xin-Le Li、Xin-Heng Fan、Lian-Ming Yang

  DOI：10.1002/ejoc.201201445

  日期：2013.2

  A copper-catalyzed C–N coupling reaction is described for the preparation of pyridine-2-carbaldehyde N,N-diarylhydrazones by the arylation of N-mono- or -non-substituted hydrazones with aryl bromides/iodides, and the subsequent conversion of the hydrazones into N,N-diarylhydrazines by a transimination process with an aqueous solution of H2NNH2. The reaction features the use of CuI as the catalyst without

  描述了一种铜催化的 C-N 偶联反应，用于通过 N-单或非取代腙与芳基溴化物/碘化物的芳基化制备吡啶-2-甲醛 N,N-二芳基腙，以及随后的转化通过使用 H2NNH2 水溶液的转亚胺化过程将腙转化为 N,N-二芳基肼。该反应的特点是使用 CuI 作为催化剂，无需外部配体。这种方法为从简单、易于获得的前体合成结构多样的 N,N-二芳基肼提供了一种方便的替代方法。
• CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Electronics Co., Ltd

  公开号：EP2977378A1

  公开（公告）日：2016-01-27

  Claimed are condensed cyclic compound of Formulae 1A to 1D and their use in organic electroluminescent light-emitting devices (OLED).

  权利要求 1A 至 1D 的缩合环状化合物及其在有机电致发光器件（OLED）中的用途。
• INDANE DERIVATIVES AND THEIR USE IN ORGANIC ELECTRONICS
  申请人：DOTTIKON ES HOLDING AG

  公开号：US20200075862A1

  公开（公告）日：2020-03-05

  The present invention relates to indane derivatives of the formula (I) and mixtures thereof, wherein X is selected from groups of the formula -A-(NAr 2 ), wherein A is a chemical bond or phenylene which is unsubstituted or substituted by 1, 2 or 3 substituents selected from C 1 -C 6 -alkyl and C 1 -C 6 -alkoxy; Ar is unsubstituted or substituted aryl, wherein two groups Ar bound to the same nitrogen atom may together with the nitrogen atom also form a fused ring system having 3 or more than 3 unsubstituted or substituted rings; and the variables Y, n, m, k and l are as defined in the claims and the description. The invention further relates to methods for preparing such compounds and their use in organic electronics, in particular as hole transport material or electron blocking material.
• DI-, TRI- AND TETRAPHENYLINDANE DERIVATES AND THEIR USE IN ORGANIC ELECTRONICS
  申请人：Dottikon ES Holding AG

  公开号：US20220006020A1

  公开（公告）日：2022-01-06

  The present invention relates to indane derivatives of the formula (I) and mixtures thereof, wherein X is selected from groups of the formulae -A-NH2 or -A-(NAr 2 ), wherein A is a chemical bond or phenylene which is unsubstituted or substituted by 1, 2, 3 or 4 substituents selected from C 1 -C 6 alkyl and C 1 -C 6 -alkoxy; Ar is unsubstituted or substituted aryl, wherein two groups Ar bound to the same nitrogen atom may together with the nitrogen atom also form a fused ring system having 3 or more than 3 unsubstituted or substituted rings; and the variables R A , R B , Y, k, I, m, p, q and r are as defined in the claims and the description. The invention further relates to methods for preparing such compounds and their use in organic electronics, in particular as hole transport material or electron blocking material.
• Groups 5 and 6 Terminal Hydrazido(2−) Complexes: N_β Substituent Effects on Ligand-to-Metal Charge-Transfer Energies and Oxidation States
  作者：Ian A. Tonks、Alec C. Durrell、Harry B. Gray、John E. Bercaw

  DOI：10.1021/ja302275j

  日期：2012.5.2

  Brightly colored terminal hydrazido(2-) (dme)MCl3(NNR2) (dme = 1,2-dimethoxyethane; M = Nb, Ta; R = alkyl, aryl) or (MeCN)WCl4(NNR2) complexes have been synthesized and characterized. Perturbing the electronic environment of the beta (NR2) nitrogen affects the energy of the lowest-energy charge-transfer (CT) transition in these complexes. For group 5 complexes, increasing the energy of the N-beta lone pair decreases the ligand-to-metal CT (LMCT) energy, except for electron-rich niobium diallcylhydrazides, which pyramidalize N-beta in order to reduce the overlap between the Nb=N-alpha pi bond and the N-beta lone pair. For W complexes, increasing the energy of N-beta eventually leads to reduction from formally [W-VI N-NR2] with a hydraziclo(2-) ligand to [W-IV=N=NR2] with a neutral 1,1-diazene ligand. The photophysical properties of these complexes highlight the potential redox noninnocence of hydrazido ligands, which could lead to ligand- and/or metal-based redox chemistry in early transition metal derivatives.