iodyl chloride | 135659-29-9

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 英文名称: iodyl chloride
• CAS: 135659-29-9
• 化学式: ClIO₂
• 分子量: 194.356
• InChiKey: FJGATDISEXKPPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  iodine monoxide 、 chlorine monoxide 以 gaseous matrix 为溶剂， 生成 iodyl chloride
  参考文献：
  名称：

  Kinetics of the IO Radical. 1. Reaction of IO with ClO

  摘要：

  The rate coefficient for the IO + ClO --> products (5) reaction was measured by coupling discharge flow and pulsed laser-induced fluorescence techniques. Rate coefficients were measured from 200 to 362 K by monitoring the temporal profile of IO in an excess of ClO The rate coefficient is described by the expression: k(5)(T) = (5.1 +/- 1.7) x 10-(12) exp[(280 +/- 80)/T] cm(3) molecule(-1) s(-1) where the quoted uncertainties include estimated systematic errors, Atomic iodine was identified as a major product of reaction 5. A branching ratio of Phi = 0.14 +/- 0.04 at 298 K was obtained for the sum of channels which do not produce I atoms.

  DOI：

  10.1021/jp970914g

文献信息

• Photochemistry of an ozone molecular complex with iodine monochloride in cryogenic matrixes. The infrared spectra of iodosyl chloride (OICl) and iodyl chloride (O2ICl)
  作者：Michael Hawkins、Lester Andrews、Anthony J. Downs、David J. Drury

  DOI：10.1021/ja00323a002

  日期：1984.5

  Formation de complexes moleculaires O 3 •ICl par codeposition de O 3 et ICl dans des matrices d'Ar, Kr et N 2 . Par irradiation a 470-750 nm photodissociation tres sensible de ces complexes en chlorure de iodosyle OICl, dont la decomposition prolongee conduit a des atomes O et au chlorure d'iodyle O 2 ICl. Decomposition de ces chlorures sous rayonnement UV a 240-320 nm

  Formation de complexes Moleculaires O 3 •ICl par coposition de O 3 et ICl dans des matrices d'Ar, Kr et N 2 。Par 辐照 470-750 nm 光解离 tres sensible de ces complexes en chlorure de iodosyle OICl，不要分解延长导管 a des atomes O et au chlorure d'iodle O 2 ICl。分解 氯化物 sous rayonnement UV a 240-320 nm
• Kinetics of the IO Radical. 1. Reaction of IO with ClO
  作者：Andrew A. Turnipseed、Mary K. Gilles、James B. Burkholder、A. R. Ravishankara

  DOI：10.1021/jp970914g

  日期：1997.7.1

  The rate coefficient for the IO + ClO --> products (5) reaction was measured by coupling discharge flow and pulsed laser-induced fluorescence techniques. Rate coefficients were measured from 200 to 362 K by monitoring the temporal profile of IO in an excess of ClO The rate coefficient is described by the expression: k(5)(T) = (5.1 +/- 1.7) x 10-(12) exp[(280 +/- 80)/T] cm(3) molecule(-1) s(-1) where the quoted uncertainties include estimated systematic errors, Atomic iodine was identified as a major product of reaction 5. A branching ratio of Phi = 0.14 +/- 0.04 at 298 K was obtained for the sum of channels which do not produce I atoms.