1-nitro-2-p-chlorophenylsulfanyl-1-phenylethene | 85296-25-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-nitro-2-p-chlorophenylsulfanyl-1-phenylethene
• 英文别名: 1-nitro-1-phenyl-2-p-chlorophenylthioethene；1-chloro-4-[(E)-2-nitro-2-phenylethenyl]sulfanylbenzene
• CAS: 85296-25-9
• 化学式: C₁₄H₁₀ClNO₂S
• 分子量: 291.758
• InChiKey: VNGXCHFYDXWGMX-GXDHUFHOSA-N

物化性质

• 沸点：
  423.0±45.0 °C(Predicted)
• 密度：
  1.36±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-nitro-2-p-chlorophenylsulfanyl-1-phenylethene 、 N,N'-二苯基硫脲 反应 5.0h， 生成
  参考文献：
  名称：

  α-Nitro-β-iodo(sulfanyl)ethenes in reactions with N,S-binucleophiles

  摘要：

  alpha-Nitro-beta-iodo(sulfanyl)ethenes were brought into reactions with N,S-binucleophiles that completed with the replacement of the beta-functional group. Iodonitroethenes with thiourea and N,N'-diphenylthiourea provided products of S-substitution. The reaction of less reactive sulfanylnitrostyrene with N,N'-diphenylthiourea and also of iodonitrostyrene with 5-amino-benzothiazolyl-2-thiol required longer time and led to the formation of more stable products of N-substitution. The reactions with 5-aminobenzothiazolyl-2-thiolate in all events resulted in the products of S-substitution.

  DOI：

  10.1134/s1070428009020134
• 作为产物：
  描述：

  1,2-dinitro-1-phenylethene 、 4-氯苯硫酚 在 sodium methylate 作用下， 生成 1-nitro-2-p-chlorophenylsulfanyl-1-phenylethene 、 1-nitro-1-phenyl-2-p-chlorophenylthioethene
  参考文献：
  名称：

  Mukhina, E. S.; Berkova, G. A.; Pavlova, Z. F., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 7.1, p. 1249 - 1254

  摘要：

  DOI：

文献信息

• Specific Features of Reaction between 1,2-Dinitro- and 1-Nitro-2-Thioethenes and Hydrazine
  作者：T. Yu. Kretser、N. V. Kuz'mina、E. S. Lipina、G. A. Berkova、V. M. Berestovitskaya

  DOI：10.1023/b:rujo.0000010199.56110.ab

  日期：2003.8
• Mukhina, E. S.; Berkova, G. A.; Pavlova, Z. F., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 7.1, p. 1249 - 1254
  作者：Mukhina, E. S.、Berkova, G. A.、Pavlova, Z. F.、Lipina, E. S.、Perekalin, V. V.

  DOI：——

  日期：——
• α-Nitro-β-iodo(sulfanyl)ethenes in reactions with N,S-binucleophiles
  作者：A. V. Mikova、E. S. Lipina、T. Yu. Kretser、N. V. Kuzmina

  DOI：10.1134/s1070428009020134

  日期：2009.2

  alpha-Nitro-beta-iodo(sulfanyl)ethenes were brought into reactions with N,S-binucleophiles that completed with the replacement of the beta-functional group. Iodonitroethenes with thiourea and N,N'-diphenylthiourea provided products of S-substitution. The reaction of less reactive sulfanylnitrostyrene with N,N'-diphenylthiourea and also of iodonitrostyrene with 5-amino-benzothiazolyl-2-thiol required longer time and led to the formation of more stable products of N-substitution. The reactions with 5-aminobenzothiazolyl-2-thiolate in all events resulted in the products of S-substitution.