Bis-(4-acetamidocyclohexyl)methan | 54081-45-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Bis-(4-acetamidocyclohexyl)methan
• 英文别名: Acetamide, N,Na(2)-(methylenedi-4,1-cyclohexanediyl)bis-；N-[4-[(4-acetamidocyclohexyl)methyl]cyclohexyl]acetamide
• CAS: 54081-45-7
• 化学式: C₁₇H₃₀N₂O₂
• 分子量: 294.437
• InChiKey: GARRJFMMGMBXKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4,4'-二氨基二环己基甲烷 、 乙腈 在 水 、 copper(II) oxide 作用下， 反应 8.0h， 生成 Bis-(4-acetamidocyclohexyl)methan
  参考文献：
  名称：

  酰胺交换反应：用于二乙酰胺合成的简单高效的CuO催化剂†

  摘要：

  开发了一种高度铜催化的六亚甲基二胺（HDA）与CH 3 CN和H 2 O的酰胺交换反应，无需有机溶剂或气体保护即可合成六亚甲基双乙酰胺（HMBA）。获得了100％的HDA转化率和> 99％的HMBA选择性。X射线衍射，扫描电子显微镜和程序升温还原氢气被用来表征催化剂的结构特性。还研究了反应机理。

  DOI：

  10.1039/c6ra05563j

文献信息

• METHOD FOR PRODUCING CARBAMATE COMPOUND
  申请人：Ube Industries, Ltd.

  公开号：EP2325167A1

  公开（公告）日：2011-05-25

  A task of the present invention is to provide a process for preparation a carbamate compound using a carbonic acid ester and an amide compound in the presence of a basic compound(s), wherein the process is a novel industrial method which is advantageous in that the reaction rate is faster than conventional and the by-produced ester compound can be recovered, and the present invention is directed to a method comprising reacting an amide compound represented by the formula (1) with a carbonic acid ester represented by the formula (2) in the presence of a basic compound(s) to obtain a carbamate compound represented by the formula (3).

  本发明的任务是提供一种在碱性化合物存在下使用碳酸酯和酰胺化合物制备氨基甲酸 酯化合物的工艺，其中该工艺是一种新颖的工业方法，其优点是反应速率比传统方法快， 且副生成的酯化合物可以回收、本发明涉及一种方法，包括在碱性化合物存在下，使式（1）代表的酰胺化合物与式（2）代表的碳酸酯反应，得到式（3）代表的氨基甲酸酯化合物。
• DENTAL MATERIAL, DENTAL MATERIAL COMPOSITION, DENTAL REPAIR MATERIAL, AND CURED PRODUCT
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2710994A1

  公开（公告）日：2014-03-26

  The present invention provides a dental material, a dental material composition and a dental restorative material that exhibit small polymerization shrinkage particularly during curing and are producible at low cost on the industrial scale. The dental material of the present invention includes a specific urethane (meth)acrylic compound represented by Formula (1) described below.

  本发明提供了一种牙科材料、一种牙科材料组合物和一种牙科修复材料，它们在固化过程中尤其表现出较小的聚合收缩，并且可以在工业规模上以低成本生产。本发明的牙科材料包括由下述式（1）表示的特定聚氨酯（甲基）丙烯酸化合物。
• NOVEL COMPOUND, COMPOSITION CONTAINING SAID COMPOUND, AND CURED PRODUCT
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2711381A1

  公开（公告）日：2014-03-26

  The present invention provides a novel compound and a composition including the compound that exhibit small polymerization shrinkage particularly during curing and are producible at low cost on the industrial scale. The compound of the present invention is represented by Formula (1):

  本发明提供了一种新型化合物和一种包括该化合物的组合物，其聚合收缩率小，尤其是在固化过程中，并且可在工业规模上以低成本生产。本发明的化合物由式（1）表示：
• ARTIFICIAL NAIL COMPOSITION, ARTIFICIAL NAIL, METHOD FOR FORMING ARTIFICIAL NAIL, AND NAIL ART KIT
  申请人：FUJIFILM Corporation

  公开号：EP2979687A1

  公开（公告）日：2016-02-03

  To provide an artificial nail composition that has excellent stability over time and that can give an artificial nail having excellent surface gloss, removability, and adhesion, and to provide an artificial nail, a method for forming an artificial nail, and a nail art kit that employ the artificial nail composition. An artificial nail composition comprises (Component A) an amino group-containing polymer.

  目的提供一种人造指甲组合物，该组合物具有优异的长期稳定性，能使人造指甲具有优异的表面光泽度、可移除性和附着力，并提供一种人造指甲、一种人造指甲的形成方法和一种美甲工具包，该美甲工具包采用了该人造指甲组合物。 人造指甲组合物包括（成分 A）含氨基的聚合物。
• PIGMENT DISPERSION COMPOSITION, INKJET RECORDING METHOD, AND METHOD FOR PRODUCING COMPOUND
  申请人：FUJIFILM Corporation

  公开号：EP3053974A1

  公开（公告）日：2016-08-10

  A pigment dispersion composition contains a pigment, a polymerizable compound, and a compound having a structural unit represented by Formula (A), a structural unit represented by Formula (B), a structural unit represented by Formula (C) derived from polyalkylene oxide having a number average molecular weight of equal to or greater than 300 and less than 5,000, and a structural unit represented by Formula (D), in which a mass ratio [(B)/(C)] is 20/80 to 60/40.

  一种颜料分散体组合物含有颜料、可聚合化合物和具有式 (A) 所代表的结构单元、式 (B) 所代表的结构单元、由聚环氧烷衍生的式 (C) 所代表的结构单元（其平均分子量等于或大于 300 但小于 5000）以及式 (D) 所代表的结构单元的化合物，其中质量比[(B)/(C)]为 20/80 至 60/40。