(2,2,3,3,4,4,5,5-Octafluoro-6-hydroxyhexyl) 2-methylprop-2-enoate | 66818-53-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (2,2,3,3,4,4,5,5-Octafluoro-6-hydroxyhexyl) 2-methylprop-2-enoate
• CAS: 66818-53-9
• 化学式: C₁₀H₁₀F₈O₃
• 分子量: 330.175
• InChiKey: OEUBBKMUWISWNA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  (2,2,3,3,4,4,5,5-Octafluoro-6-hydroxyhexyl) 2-methylprop-2-enoate 、 1H,1H,2H,2H-全氟辛基三氯硅烷 反应 7.0h， 以90%的产率得到
  参考文献：
  名称：

  EP2532669

  摘要：

  公开号：

文献信息

• NOVEL FLUORINATED COMPOUND, A COMPOSITION COMPRISING THE SAME, AND A PRODUCTION METHOD FOR A FILM USING THE SAME
  申请人：Jung Soon-Hwa

  公开号：US20120308802A1

  公开（公告）日：2012-12-06

  The present invention relates to a novel fluorinated compound, a composition comprising the same, and a method for manufacturing a film by using the same, and more particularly a novel compound having a structure in which one or more fluorine and acrylate-based functional groups are substituted in a silane core, a composition comprising the compound and photoinitiator, and a method for manufacturing a film by using the same. If the composition comprising the compound according to the present invention is used, it is possible to manufacture a film in which a refractive index is low, reflectivity is reduced, and transmissivity is increased.

  本发明涉及一种新型氟化合物、包含该化合物的组合物以及使用该化合物制造薄膜的方法，更具体地说，涉及一种新型化合物，其结构中的硅烷核心被一个或多个氟和丙烯酸酯基团取代，以及包含该化合物和光引发剂的组合物，以及使用该组合物制造薄膜的方法。如果使用本发明中所述的化合物组成的组合物，则可以制造出折射率低、反射率降低、透射率增加的薄膜。
• FLUORINE-CONTAINING ADAMANTANE DERIVATIVE, FLUORINE-CONTAINING ADAMANTANE DERIVATIVE HAVING POLYMERIZABLE GROUP, RESIN COMPOSITION CONTAINING THE SAME, AND ANTIREFLECTION FILM
  申请人：Okada Yasunari

  公开号：US20090099326A1

  公开（公告）日：2009-04-16

  To provide a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as mar resistance and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative. Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formula, R 1 and R 2 are each a hydrogen atom, for example, n is an integer of 0 or more, X 1 is a polymerizable group represented by the formula (III-a), for example, Y is a hydrogen atom, for example, s and t are each an integer of 1 to 15, and u is an integer of 0 to 14, with the proviso that s+t+u=16.

  提供一种含有聚合物化基团和含氟的金刚烷衍生物，能够产生具有良好耐热性、抗划伤等良好机械性能和低折射率的固化产品，以及含有这种聚合物化基团金刚烷衍生物的树脂组合物和用于生产聚合物化基团和含氟金刚烷衍生物的反应中间体的含氟金刚烷衍生物。具体提供了以下通式（I）所代表的含氟金刚烷衍生物、以下通式（II）所代表的聚合物化基团和含氟金刚烷衍生物，以及含有这种聚合物化基团和含氟金刚烷衍生物的树脂组合物。在公式中，R1和R2分别是氢原子，例如，n是0或更多的整数，X1是由公式（III-a）表示的聚合物化基团，例如，Y是氢原子，例如，s和t分别是1到15的整数，u是0到14的整数，并且有条件s+t+u=16。
• OBJECT WITH COMPOSITE HARD COATING LAYER AND METHOD OF FORMING COMPOSITE HARD COATING LAYER
  申请人：TDK Corporation

  公开号：EP1520688A1

  公开（公告）日：2005-04-06

  The present invention provides inexpensively an article with a hard coat excellent in anti-staining property, lubricity, scratch resistance and abrasion resistance. The present invention also provides a method for forming the hard coat. A hard coat agent composition comprising an active energy ray-curable compound is applied onto a surface of an article (1) to be hard-coat-treated, thereby forming a hard coat agent composition layer, a surface material layer is formed by film-forming with a surface material comprising a fluorine-containing polyfunctional (meth)acrylate compound and a fluorine-containing monofunctional (meth)acrylate compound on the surface of the hard coat agent composition layer, and active energy rays are irradiated onto the formed hard coat agent composition layer and surface material layer so as to cure the both layers simultaneously, thereby forming a hard coat layer (2) contacting the surface of the article (1) and an anti-staining surface layer (3) contacting the surface of the hard coat layer (2).

  本发明以低廉的成本提供了一种具有抗沾污性、润滑性、抗划伤性和耐磨性极佳的硬涂层的物品。本发明还提供了一种形成硬涂层的方法。将包含活性能量射线固化化合物的硬涂层剂组合物涂在要进行硬涂层处理的物品 (1) 的表面上，从而形成硬涂层剂组合物层，在硬涂层剂组合物层的表面用包含含氟多官能度（甲基）丙烯酸酯化合物和含氟单官能度（甲基）丙烯酸酯化合物的表面材料成膜形成表面材料层、在形成的硬涂层剂成分层和表面材料层上照射活性能量射线，使两层同时固化，从而形成与物品（1）表面接触的硬涂层层（2）和与硬涂层层（2）表面接触的防沾污表面层（3）。
• Dentale Beschichtungsmaterialien
  申请人：Firma Ivoclar Vivadent AG

  公开号：EP1510197A1

  公开（公告）日：2005-03-02

  Polymerisierbare Werkstoffe, die(1) 1 bis 80 Gew.-% mindestens eines Polysiloxans, (2) 0,1 bis 5 Gew.-% eines oder mehrerer Initiatoren für die radikalische Polymerisation, (3) 0 bis 60 Gew.-% radikalisch polymerisierbares Monomer und (4) 1 bis 50 Gew.-% eines oder mehrerer radikalisch polymerisierbarer Monomere, die mindestens eine Phosphonsäuregruppe, Sulfonsäuregruppe und/oder Mono- oder Dihydrogenphosphorsäureestergruppe tragen, enthalten, wobei das Polysiloxan (1), das Monomer (3) oder beide durch Fluor substituiert sind. Die Werkstoffe eignen sich insbesondere zur Beschichtung natürlicher oder künstlicher Zähne.

  可聚合材料，其中包括(1)1-80%（按重量计）至少一种聚硅氧烷，(2)0.1-5%（按重量计）一种或多种用于自由基聚合的引发剂，(3)0-60%（按重量计）可自由基聚合的单体，以及(4)1-50%（按重量计）一种或多种可自由基聚合的单体。(4) 1%至 50%（重量百分比）的一种或多种可自由基聚合的单体，这些单体至少带有一个膦酸基、磺酸基和/或一氢或二氢磷酸酯基，聚硅氧烷 (1)、单体 (3) 或两者均被氟取代。这些材料尤其适用于天然或人造牙齿的涂层。
• Curable composition for photo imprints, method for forming pattern, fine pattern, and method for manufacturing semiconductor device
  申请人：FUJIFILM Corporation

  公开号：US10175576B2

  公开（公告）日：2019-01-08

  Provided is a curable composition for photo imprints excellent in the mold releasability and the ink jettability. The curable composition for photo imprints, comprising: a polymerizable compound (A); a photo-polymerization initiator (B); and a mold releasing agent (C), the mold releasing agent (C) being represented by the formula (I) below. Rf represents a C1-8 fluorine-containing alkyl group having two or more fluorine atoms; m represents 1 or 2; L represents a single bond or divalent linking group; n represents 1 or 2; X represents a single bond, oxygen atom, sulfur atom, or nitrogen atom; R1 represents a C1-8 substituent being free from a polymerizable group; R2 represents a hydrogen atom, C1-8 substituent, or divalent linking group; p represents 1 or 2, q represents 0 or 1, and r represents 1 or 2; R1 and R2 may combine with each other to form a ring.

  本发明提供了一种用于照片印记的固化组合物，该组合物具有优异的脱模性和油墨润湿性。这种用于照片印记的可固化组合物包括：可聚合化合物（A）；光聚合引发剂（B）；和脱模剂（C），脱模剂（C）由下式（I）表示。Rf 代表具有两个或两个以上氟原子的 C1-8 含氟烷基；m 代表 1 或 2；L 代表单键或二价连接基团；n 代表 1 或 2；X 代表单键、氧原子、硫原子或氮原子；R1 代表不含可聚合基团的 C1-8 代基；R2 代表氢原子、C1-8 代基或二价连接基团；p 代表 1 或 2，q 代表 0 或 1，r 代表 1 或 2；R1 和 R2 可相互结合形成一个环。