1,3-dichlorpropan-2-ol hexanoate | 88606-65-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1,3-dichlorpropan-2-ol hexanoate
• 英文别名: 1,3-dichloro-2-propyl hexanoate；hexanoic acid-(β,β'-dichloro-isopropyl ester)；Hexansaeure-(β,β'-dichlor-isopropylester)；Hexanoic acid, 2-chloro-1-(chloromethyl)ethyl ester；1,3-dichloropropan-2-yl hexanoate
• CAS: 88606-65-9
• 化学式: C₉H₁₆Cl₂O₂
• 分子量: 227.131
• InChiKey: JTZZRMIMWBAHQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-dichlorpropan-2-ol hexanoate 、 sodium myristoate 以 N,N-二甲基甲酰胺 为溶剂， 生成 2-caproyl-1,3-dimyristoyl-glycerol
  参考文献：
  名称：

  Epicuticular wax of Cirsium arvense

  摘要：

  DOI：

  10.1016/s0031-9422(82)85031-0
• 作为产物：
  描述：

  1,3-二氯丙醇 、 己酸酐 以 吡啶 为溶剂， 生成 1,3-dichlorpropan-2-ol hexanoate
  参考文献：
  名称：

  Epicuticular wax of Cirsium arvense

  摘要：

  DOI：

  10.1016/s0031-9422(82)85031-0

文献信息

• Process of stripping a liquid medium
  申请人：Solvay SA

  公开号：EP2708525A1

  公开（公告）日：2014-03-19

  Process of stripping a liquid medium containing at least one oligomer of glycerol, wherein a stripping agent comprising hydrogen chloride is used at a temperature higher than 120 °C.

  对含有至少一种甘油低聚物的液体介质进行汽提的工艺，其中使用的汽提剂包括氯化氢，温度高于 120 ℃。
• Synthesis of Allyl Esters of Fatty Acids and Their Ovicidal Effect on Cydia pomonella (L.)
  作者：Marc Escribà、Montserrat Barbut、Jordi Eras、Ramon Canela、Jesús Avilla、Mercè Balcells

  DOI：10.1021/jf900097j

  日期：2009.6.10

  Eight allyl esters of fatty acids were synthesized in moderate to high yields with a novel two-step procedure using glycerol as a starting material. The two-step methodology avoids the use of allyl alcohol. The first step consisted of heating at 80 degrees C for 48 h a 2:1:5 mmol mixture of glycerol, a fatty acid, and chlorotrimethylsilane in a solvent-free medium. The crude compound was then dissolved in butanone and heated at 115 degrees C in the presence of Nal. A tandem Finkelstein rearrangement-elimination reaction occurs, producing the corresponding allyl ester. The activity of these esters against Cydia pomonella (L.) (Lepidoptera: Tortricidae) eggs was tested in the laboratory by topical application of one 0.1 mu L drop. All of the compounds showed a concentration-mortality response and caused 100% mortality at the highest concentration tested (10 mg/mL). There was an inverse relationship between the alkyl chain length and the ovicidal activity of the allyl ester; the LC50 and the LC90 of the two compounds that have the longer alkyl chains were significantly higher than those of the rest of the compounds. The ovicidal and IGR activities of this kind of compound appear to be unprecedented.
• Humnicki, Bulletin de la Societe Chimique de France, 1929, vol. <4>45, p. 281
  作者：Humnicki

  DOI：——

  日期：——
• PROCESS OF STRIPPING A LIQUID MEDIUM
  申请人：Solvay SA

  公开号：EP2895449A1

  公开（公告）日：2015-07-22
• [EN] PROCESS OF STRIPPING A LIQUID MEDIUM<br/>[FR] PROCÉDÉ D'ÉPURATION D'UN MILIEU LIQUIDE
  申请人：SOLVAY

  公开号：WO2014040883A1

  公开（公告）日：2014-03-20

  Process of stripping a liquid medium containing at least one oligomer of glycerol, wherein a stripping agent comprising hydrogen chloride is used at a temperature higher than 120°C.