N-(2-metnyl-1-propenyl)-2-hexahydroazepinone | 13265-63-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酰胺类
• 英文名称: N-(2-metnyl-1-propenyl)-2-hexahydroazepinone
• 英文别名: N-(1-isobutenyl)-hexahydroazepin-2-one；N-β,β-Dimethylvinyl-caprolactam；1-(2-Methylprop-1-enyl)azepan-2-one
• CAS: 13265-63-9
• 化学式: C₁₀H₁₇NO
• 分子量: 167.251
• InChiKey: GFFYMDHYRONCRJ-UHFFFAOYSA-N

物化性质

• 沸点：
  135-137 °C(Press: 12 Torr)
• 密度：
  1.020±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(2-metnyl-1-propenyl)-2-hexahydroazepinone 、 triethyloxonium fluoroborate 以 二氯甲烷 为溶剂， 以100%的产率得到C₁₂H₂₂NO⁽¹⁺⁾*BF₄^(1-)
  参考文献：
  名称：

  Zezza, Charles A.; Kwon, Tae Woo; Sheu, JennLine, Heterocycles, 1992, vol. 34, # 7, p. 1325 - 1342

  摘要：

  DOI：
• 作为产物：
  描述：

  己内酰胺 、 异丁醛 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 以63%的产率得到N-(2-metnyl-1-propenyl)-2-hexahydroazepinone
  参考文献：
  名称：

  Zezza, Charles A.; Smith, Michael B., Synthetic Communications, 1987, vol. 17, # 6, p. 729 - 740

  摘要：

  DOI：

文献信息

• Polymers polymerized from at least four monomers, and compositions and uses thereof
  申请人：ISP INVESTMENTS LLC

  公开号：US10494466B2

  公开（公告）日：2019-12-03

  Family of non-homopolymers synthesized from N-vinyl lactam, (meth)acrylic acid, hydrophobic (meth)acrylic ester of a straightchain or branched-chain alkyl alcohol and monomer selected from the group consisting of functionalized and unfunctionalized: dialkyl maleates, dialkyl fumarates, and combinations thereof. The non-homopolymers may exhibit solubility in one or more lower molecular weight alcohols and/or a glass transition temperature greater than 80° C.

  由 N-乙烯内酰胺、（甲基）丙烯酸、直链或支链烷基醇的疏水性（甲基）丙烯酸酯和选自官能化和非官能化单体（马来酸二烷基酯、富马酸二烷基酯及其组合）合成的非均聚物系列。非均聚物在一种或多种低分子量醇中的溶解度和/或玻璃化温度高于 80 摄氏度。
• ZEZZA CH. A.; SMITH M. B., SYNTH. COMMUN., 17,(1987) N 6, 729-740
  作者：ZEZZA CH. A.、 SMITH M. B.

  DOI：——

  日期：——
• POLYMERS POLYMERIZED FROM AT LEAST FOUR MONOMERS, AND COMPOSITIONS AND USES THEREOF
  申请人：ISP Investments Inc.

  公开号：US20150353666A1

  公开（公告）日：2015-12-10

  Family of non-homopolymers synthesized from N-vinyl lactam, (meth)acrylic acid, hydrophobic (meth)acrylic ester of a straightchain or branched-chain alkyl alcohol and monomer selected from the group consisting of functionalized and unfunctionalized: dialkyl maleates, dialkyl fumarates, and combinations thereof. The non-homopolymers may exhibit solubility in one or more lower molecular weight alcohols and/or a glass transition temperature greater than 80° C.
• [EN] POLYMERS POLYMERIZED FROM AT LEAST FOUR MONOMERS, AND COMPOSITIONS AND USES THEREOF<br/>[FR] POLYMÈRES POLYMÉRISÉS À PARTIR D'AU MOINS QUATRE MONOMÈRES, ET LEURS COMPOSITIONS ET UTILISATIONS
  申请人：ISP INVESTMENTS INC

  公开号：WO2014149486A1

  公开（公告）日：2014-09-25

  family of non-homopolymers synthesized from N-vinyl lactam, (meth)acrylic acid, hydrophobic (meth)acrylic ester of a straightchain or branched-chain alkyl alcohol and monomer selected from the group consisting of functionalized and unfunctionalized: dialkyi maleates, dialkyi fumarates, and combinations thereof. The non-homopolymers may exhibit solubility in one or more lowermolecular weight alcohols and/or a glass transition temperature greater than 80?C.