chlorine oxyfluoride | 22363-68-4

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 英文名称: chlorine oxyfluoride
• 英文别名: chlorosyl fluoride；Fluorochlorane oxide
• CAS: 22363-68-4
• 化学式: ClFO
• 分子量: 70.4508
• InChiKey: AXCBHWGTRNNXKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三氟化氯 、 水 以 neat (no solvent, gas phase) 为溶剂， 生成 chlorine oxyfluoride
  参考文献：
  名称：

  Infrared spectroscopy and molecular properties of chlorosyl fluoride, FClO

  摘要：

  The structure of the very reactive, yet fairly long-lived, FClO molecule has been determined experimentally for the first time. Analysis of the high-resolution infrared spectrum of its nu(1) band provided the spectroscopic constants needed. FClO was obtained as the main product of the reaction between CIF3 and H2O under slow-flow conditions. A preliminary analysis of the nu(2) band and a comparison of the FClO structural properties with those of related molecules are also presented. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(99)01197-5

文献信息

• Infrared spectroscopy and molecular properties of chlorosyl fluoride, FClO
  作者：Holger S.P Müller

  DOI：10.1016/s0009-2614(99)01197-5

  日期：1999.12

  The structure of the very reactive, yet fairly long-lived, FClO molecule has been determined experimentally for the first time. Analysis of the high-resolution infrared spectrum of its nu(1) band provided the spectroscopic constants needed. FClO was obtained as the main product of the reaction between CIF3 and H2O under slow-flow conditions. A preliminary analysis of the nu(2) band and a comparison of the FClO structural properties with those of related molecules are also presented. (C) 1999 Elsevier Science B.V. All rights reserved.