1-methyl-4-[(Z)-2-phenyltellanylethenyl]sulfinylbenzene | 690638-62-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-methyl-4-[(Z)-2-phenyltellanylethenyl]sulfinylbenzene
• CAS: 690638-62-1
• 化学式: C₁₅H₁₄OSTe
• 分子量: 369.942
• InChiKey: BEDYUUDVFKZTIN-QXMHVHEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲基炔丙基醚 、 1-methyl-4-[(Z)-2-phenyltellanylethenyl]sulfinylbenzene 在 palladium dichloride copper(l) iodide 、 三乙胺 作用下， 以 甲醇 为溶剂， 以63%的产率得到1-((Z)-5-Methoxy-pent-1-en-3-yne-1-sulfinyl)-4-methyl-benzene
  参考文献：
  名称：

  Hydrotelluration and carbotelluration of acetylenic sulfoxides: regio- and stereoselective preparation of α- and β-organotellurovinyl sulfoxides

  摘要：

  (Z)-beta-Organotellurovinyl sulfoxides were synthesized via a highly regio- and stereoselective anti-hydrotelluration of acetylenic sulfoxides. alpha-Organotellurovinyl sulfoxides were obtained from a three component syn-carbotelluration reaction of acetylenic sulfoxides, that is, syn-addition of monoorganocopper reagents to acetylenic sulfoxides followed by the electrophilic reaction of the vinyl copper intermediates with benzenetellurenyl iodide at low temperature. Synthetic applications of the organotellurovinyl sulfoxides have been investigated. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.02.064
• 作为产物：
  描述：

  联苯二碲 、 1-(ethynylsulfinyl)-4-methylbenzene 在 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 0.5h， 以85%的产率得到1-methyl-4-[(Z)-2-phenyltellanylethenyl]sulfinylbenzene
  参考文献：
  名称：

  Hydrotelluration and carbotelluration of acetylenic sulfoxides: regio- and stereoselective preparation of α- and β-organotellurovinyl sulfoxides

  摘要：

  (Z)-beta-Organotellurovinyl sulfoxides were synthesized via a highly regio- and stereoselective anti-hydrotelluration of acetylenic sulfoxides. alpha-Organotellurovinyl sulfoxides were obtained from a three component syn-carbotelluration reaction of acetylenic sulfoxides, that is, syn-addition of monoorganocopper reagents to acetylenic sulfoxides followed by the electrophilic reaction of the vinyl copper intermediates with benzenetellurenyl iodide at low temperature. Synthetic applications of the organotellurovinyl sulfoxides have been investigated. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.02.064

文献信息

• Hydrotelluration and carbotelluration of acetylenic sulfoxides: regio- and stereoselective preparation of α- and β-organotellurovinyl sulfoxides
  作者：Qing Xu、Xian Huang、Jun Ni

  DOI：10.1016/j.tetlet.2004.02.064

  日期：2004.3

  (Z)-beta-Organotellurovinyl sulfoxides were synthesized via a highly regio- and stereoselective anti-hydrotelluration of acetylenic sulfoxides. alpha-Organotellurovinyl sulfoxides were obtained from a three component syn-carbotelluration reaction of acetylenic sulfoxides, that is, syn-addition of monoorganocopper reagents to acetylenic sulfoxides followed by the electrophilic reaction of the vinyl copper intermediates with benzenetellurenyl iodide at low temperature. Synthetic applications of the organotellurovinyl sulfoxides have been investigated. (C) 2004 Elsevier Ltd. All rights reserved.