2-(2-Methoxy-1-methylethoxy)acetic acid | 16024-63-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(2-Methoxy-1-methylethoxy)acetic acid
• 英文别名: 2-(1-methoxypropan-2-yloxy)acetic acid
• CAS: 16024-63-8
• 化学式: C₆H₁₂O₄
• 分子量: 148.16
• InChiKey: YFFWONKYNSJNQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• Catalysts and methods for catalytic oxidation
  申请人：Busch Hadley Daryle

  公开号：US20060116281A1

  公开（公告）日：2006-06-01

  Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.

  本发明涉及催化系统和方法，其中金属催化剂（优选含锰催化剂）与选定的大环刚性配体（优选交桥大环配体）形成配合物，用于氧化物质。这些金属催化剂可用于合成有机氧化反应，如氧化有机官能团、烃和杂原子，包括烯烃、炔烃、硫化物转化为磺酮等的对映体环氧化；氧化表面上可氧化化合物（例如污渍），如织物、餐具、台面、假牙等；溶液中可氧化化合物的氧化，如在织物洗涤中的染料转移抑制；以及在漂白制浆造纸产品中的进一步应用。
• BLEACHING COMPOSITION
  申请人：Kao Corporation

  公开号：EP0447553A1

  公开（公告）日：1991-09-25

  A bleaching composition comprising: (a) hydrogen peroxide or a peroxide which generates hydrogen peroxide in an a aqueous solution thereof and (b) an organic peracid precursor which generates an organic peracid represented by general formula (I) upon reacting with component (a). In formula (I), wherein R1 represents a straight-chain or branched C1 to C5 alkyl or alkenyl group; R2 represents a straight-chain or branched C1 to C8 alkylene group, or a phenylene group which may be substituted with a straight-chain or branched C1 to Cs alkyl group; nA groups may be the same or different from one another and each represents a C2 to C4 alkylene group; and n is a number of 0 to 100.

  一种漂白组合物，包括：(a)过氧化氢或在其水溶液中生成过氧化氢的过氧化物；(b)有机过酸前体，与组分(a)反应后生成通式(I)代表的有机过酸。在式(I)中，其中 R1 代表直链或支链 C1 至 C5 烷基或烯基；R2 代表直链或支链 C1 至 C8 亚烷基，或可被直链或支链 C1 至 Cs 烷基取代的亚苯基；nA 基团可以彼此相同或不同，且各代表一个 C2 至 C4 亚烷基；n 是 0 至 100 的数字。
• Dental materials and methods
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10350297B2

  公开（公告）日：2019-07-16

  The present application is directed to a dental material and a method of using the dental material. The dental material can include a hardenable resin; an initiator system; a filler; and from about 1 wt % to about 20 wt % zinc compound, based on the weight of the hardenable resin. The contrast ratio of the cured dental material increases by at least about 10 units after continuous exposure to an aqueous solution for 21 days.

  本申请涉及一种牙科材料和使用该牙科材料的方法。该牙科材料可包括可硬化树脂、引发剂系统、填料和约 1 wt % 至约 20 wt % 的锌化合物（基于可硬化树脂的重量）。在水溶液中持续暴露 21 天后，固化牙科材料的对比度至少增加约 10 个单位。
• Bleach compositions
  申请人：The Procter & Gamble Co.

  公开号：US20040038843A1

  公开（公告）日：2004-02-26

  Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.

  洗衣或清洁组合物，包括：(a) 催化有效量，优选约 1 ppb 至约 99.9% 的过渡金属漂白催化剂，它是过渡金属和交桥大环配体的复合物；(b) 至少约 0.1% 的一种或多种洗衣或清洁辅助材料，优选包括氧漂白剂。优选组合物为洗衣组合物和自动洗碗机洗涤剂，通过使用此类催化剂可提高清洁/漂白效果。
• CATALYSTS AND METHODS FOR CATALYTIC OXIDATION
  申请人：The University of Kanses

  公开号：EP0966323A1

  公开（公告）日：1999-12-29