2-(2-Methylphenoxy)ethyl prop-2-enoate | 114496-17-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(2-Methylphenoxy)ethyl prop-2-enoate
• CAS: 114496-17-2
• 化学式: C₁₂H₁₄O₃
• 分子量: 206.241
• InChiKey: BWTPZNAZVBTPIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(2-Methylphenoxy)ethyl prop-2-enoate 在 ferric(III) bromide 、 potassium perchlorate 作用下， 反应 6.0h， 以66.4%的产率得到
  参考文献：
  名称：

  JP5731346

  摘要：

  公开号：

文献信息

• Process for producing three-dimensional model
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20040222548A1

  公开（公告）日：2004-11-11

  A process for producing a three-dimensional model is provided. The process includes (a) a layer formation step of forming a layer of a powder material having a refractive index n 1 above a support, (b) a shape formation step of bonding the powder material layer into a predetermined shape by a binder that gives a refractive index n 2 , and (c) sequentially repeating the above steps. The absolute value of the difference between the refractive index n 1 of the powder material and the refractive index n 2 given by the binder is 0.1 or less, and the binder includes two or more types of binders selected from the group consisting of at least one type of colored binder, a white binder, and a colorless transparent binder.

  提供了一种制造三维模型的过程。该过程包括：（a）形成一层粉末材料，其折射率n1高于支撑物；（b）通过给予折射率n2的粘合剂将粉末材料层粘合成预定形状；（c）重复上述步骤。粉末材料的折射率n1与粘合剂给予的折射率n2之间的差的绝对值为0.1或以下，且粘合剂包括至少一种有色粘合剂、白色粘合剂和无色透明粘合剂中选择的两种或两种以上的粘合剂。
• (METH)ACRYLOYL-TERMINATED POLYISOBUTYLENE POLYMER, METHOD FOR PRODUCING THE SAME, AND ACTIVE ENERGY RAY-CURABLE COMPOSITION
  申请人：KANEKA CORPORATION

  公开号：US20140243444A1

  公开（公告）日：2014-08-28

  The purpose of the present invention is to provide a polymer having a low halogen atom content remaining in the polymer, a simple production method thereof, an active energy ray-curable composition that can be rapidly cured by an irradiation of a small amount of light, and a cured product thereof. These purpose can be achieved by an active energy ray-curable composition, including a polyisobutylene polymer (A) represented by the following general formula (1) (wherein R 1 represents a monovalent or polyvalent aromatic hydrocarbon group, or a monovalent or a polyvalent aliphatic hydrocarbon group; A represents a polyisobutylene polymer; R 2 represents a divalent saturated hydrocarbon group having 2-6 carbon atoms, which contains no hetero atoms; R 3 and R 4 each represent hydrogen, a monovalent hydrocarbon group having 1-20 carbon atoms, or an alkoxy group having 1-20 carbon atoms; R 5 represents hydrogen or a methyl group; and n denotes a natural number), and an active energy ray polymerization initiator (B).

  本发明的目的是提供一种聚合物，其聚合物中保留有较低的卤素原子含量，以及其简单的生产方法，一种能够通过少量光辐照快速固化的活性能量射线固化组合物以及其固化产物。这些目的可以通过一种活性能量射线固化组合物来实现，包括以下通式（1）所表示的聚异丁烯聚合物（A）（其中R1表示单价或多价芳香烃基或单价或多价脂肪烃基；A表示聚异丁烯聚合物；R2表示含有2-6个碳原子的二价饱和碳氢基团，不含杂原子；R3和R4分别表示氢、具有1-20个碳原子的单价碳氢基团或具有1-20个碳原子的烷氧基；R5表示氢或甲基基团；n表示自然数），以及活性能量射线聚合引发剂（B）。
• Printed thermoplastic resin products and method for printing such products
  申请人：HAYAKAWA RUBBER COMPANY LIMITED

  公开号：EP0588533A2

  公开（公告）日：1994-03-23

  An easily regeneratable printed thermoplastic resin product is provided by printing it with a specific radiation-curing ink composition and curing the printed ink with radiation to form a cured ink film thereon. The ink composition comprises a vehicle mixture containing : (A) an ingredient selected from the group consisting of a skeletal linear polyester oligomer having 1 to 10 double bonds in a molecule and a polymer of the oligomer, (B) an ingredient selected from the group consisting of a double bond-containing carboxylic acid wherein the acid has at least one acidic group which is capable of forming a water-soluble alkali metal salt in a molecule, a carboxylic ester of the acid and a carboxylic amide of the acid, (C) a double bond-containing polycarboxylic ester, having 2 to 10 acidic groups which are capable of forming an alkali metal salt which will swell with water absorption, (D) an ingredient selected from the group consisting of a fluorinated double bond-containing carboxylic ester wherein the fluorine component is oriented on the surface of a coplymer or polymer to give water-repellency, a block copolymer which comprises a surface-oriented and water-repellent fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and a block copolymer which comprises a surface-oriented and water-repellent siloxane group-containing polymer segment and a (meth)acrylic polymer segment, (E) a double bond-containing polycarboxylic ester, and (F) an ingredient selected from the group consisting of a double bond-containing monocarboxylic ester and its amide, wherein the acid value of the vehicle mixture is from 5 to 100. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.

  通过用特定的辐射固化油墨组合物印刷热塑性树脂产品，并用辐射固化印刷油墨，在其上形成固化油墨膜，提供了一种易于再生的印刷热塑性树脂产品。 油墨组合物包括一种载体混合物，其中含有......： (A) 从以下组别中选出的成分：分子中含有 1 至 10 个双键的骨架线性聚酯低聚物和该低聚物的聚合物； (B) 从以下组别中选出的成分：含双键的羧酸，其中该酸至少有一个酸性基团，能在分子中形成水溶性碱金属盐、(C) 含雙鍵的聚羧酸酯，其中有 2 至 10 個酸性基團，可形成吸水後 會膨脹的鹼金屬鹽、 (D) 从以下组别中选出的一种成分：含氟双键羧酸酯，其中的氟成分在共聚物或聚合物的表面定向，以产生憎水性、(E) 含双键的聚羧酸酯，及 (F) 从含双键单羧酸酯及其酰胺组成的组中选出的成分，其中载体混合物的酸值为 5 至 100。 这种油墨可用于在特定的热塑性产品上显示和装饰商品名称、图案、说明、条形码等，固化后的油墨膜很容易用碱水溶液剥离。
• Radiation curing ink
  申请人：HAYAKAWA RUBBER COMPANY LIMITED

  公开号：EP0588534A2

  公开（公告）日：1994-03-23

  A radiation-curing ink composition contains a vehicle mixture comprising : (A) an ingredient selected from the group consisting of a skeletal linear polyester oligomer having 1 to 10 double bonds in a molecule and a polymer of the oligomer, (B) an ingredient selected from the group consisting of a double bond-containing carboxylic acid wherein the acid has at least one acidic group which is capable of forming a water-soluble alkali metal salt in a molecule, a carboxylic ester of the acid and a carboxylic amide of the acid, (C) a double bond-containing carboxylic ester, having 2 to 10 acidic groups which are capable of forming an alkali metal salt capable of swelling with water absorption, (D) an ingredient selected from the group consisting of a fluorinated double bond-containing carboxylic ester wherein the fluorine component is oriented on the surface of a copolymer or polymer to give water-repellency, a block copolymer which comprises a surface-oriented and water-repellent fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and a block copolymer which comprises a surface-oriented and water-repellent siloxane group-containing polymer segment and a (meth)acrylic polymer segment, (E) a double bond-containing polycarboxylic ester, and (F) an ingredient selected from the group consisting of a double bond-containing carboxylic monoester and its amide, wherein the acid value of the vehicle mixture is from 5 to 100, is provided. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.

  一种辐射固化油墨组合物含有一种载体混合物，该载体混合物包括 ..：(A) 从以下组中选出的成分：分子中含有 1 至 10 个双键的骨架线性聚酯低聚物和该低聚物的聚合物； (B) 从以下组中选出的成分：含双键的羧酸，其中该酸具有至少一个酸性基团，能在分子中形成水溶性碱金属盐、(C) 含雙鍵的羧酸酯，其中有 2 至 10 個酸性基團，能形成能吸水膨脹 的鹼金屬鹽、(D) 从以下组别中选出的成分：含氟双键羧酸酯，其中的氟成分在共聚物或聚合物表面定向，以产生憎水性；嵌段共聚物，包括表面定向和憎水的含氟烷基聚合物段和（甲基）丙烯酸聚合物段；以及嵌段共聚物，包括表面定向和憎水的含氟烷基聚合物段和（甲基）丙烯酸聚合物段、(E) 含双键的聚羧酸酯，和 (F) 从含双键的羧酸单酯及其酰胺组成的组中选出的成分，其中载体混合物的酸值为 5 至 100。 这种油墨可用于在特定的热塑性产品上显示和装饰商品名称、图案、说明、条形码等，而且固化后的油墨膜很容易用碱水溶液剥离。
• Image recording sheet comprising an active energy ray-curable composition
  申请人：Oji Paper Company Limited

  公开号：EP1090775A1

  公开（公告）日：2001-04-11

  An image recording sheet capable of being printed by conventional dye sublimation and hot melt ink thermal transfer printing procedures and having a high gloss and a high fuse adhesion resistance to the dye or ink sheet, has an image receiving layer formed on a substrate by curing a layer of an activation energy ray-curable compound of the formula (1): wherein R1 and R2 = H or a methyl group.

  一种可通过常规染料升华和热熔墨水热转印印花程序进行印花的图像记录片，具有高光泽度和对染料或墨水片的高熔融粘附性，其图像接收层是通过固化一层式（1）的活化能射线固化化合物而在基材上形成的： 其中 R1 和 R2 = H 或甲基。