3,4-Dihydroxyallylbenzene | 524938-81-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4-Dihydroxyallylbenzene
• 英文别名: 1-[2-(1-Hydroxyprop-2-enyl)phenyl]prop-2-en-1-ol
• CAS: 524938-81-6
• 化学式: C₁₂H₁₄O₂
• 分子量: 190.242
• InChiKey: WPQLQGQMGQKWBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,4-Dihydroxyallylbenzene 在 tris-(dibenzylideneacetone)dipalladium(0) 、 10% palladium on active carbon 吡啶 、 氢气 、 1,4-双(二苯基膦)丁烷 作用下， 以 四氢呋喃 、 二氯甲烷 、 乙酸乙酯 为溶剂， 反应 24.0h， 生成 1,2-bis{3-[2-(acetylamino)-2-deoxy-3,4,6-tri-O-acetyl-α-D-glucopyranosyloxy]propyl}benzene
  参考文献：
  名称：

  PALLADIUM-CATALYZED SYNTHESIS OF BIS-GLYCOSIDES OF BUT-2-ENE-1,4-DIOL, BUTANE-1,4-DIOL AND 1,2-BIS(PROPENYL)BENZENE

  摘要：

  Palladium(O)-catalyzed reaction of various carbohydrates derived from glucofuranose, mannofuranose, ribofuranose, glucopyranose, and glucosamine, bearing a free hydroxyl group, with 1,4-bis-(methoxycarbonyloxy)but-2-ene afforded the corresponding bis-glycosides of butene-1,4-diol. Hydrogenation in the presence of palladium on charcoal of these unsaturated compounds led to the formation of the bis-glycosides of butane-1,4-diol. The condensation was successfully extended to the bis-carbonate of 1,2-bis[(1-hydroxy)propen-2-yl]benzene and derivatives of glucofuranose, ribofuranose and glucosamine.

  DOI：

  10.1081/car-120016853
• 作为产物：
  描述：

  乙烯基溴化镁 、 邻苯二甲醛 以 四氢呋喃 为溶剂， 反应 16.0h， 以35%的产率得到3,4-Dihydroxyallylbenzene
  参考文献：
  名称：

  PALLADIUM-CATALYZED SYNTHESIS OF BIS-GLYCOSIDES OF BUT-2-ENE-1,4-DIOL, BUTANE-1,4-DIOL AND 1,2-BIS(PROPENYL)BENZENE

  摘要：

  Palladium(O)-catalyzed reaction of various carbohydrates derived from glucofuranose, mannofuranose, ribofuranose, glucopyranose, and glucosamine, bearing a free hydroxyl group, with 1,4-bis-(methoxycarbonyloxy)but-2-ene afforded the corresponding bis-glycosides of butene-1,4-diol. Hydrogenation in the presence of palladium on charcoal of these unsaturated compounds led to the formation of the bis-glycosides of butane-1,4-diol. The condensation was successfully extended to the bis-carbonate of 1,2-bis[(1-hydroxy)propen-2-yl]benzene and derivatives of glucofuranose, ribofuranose and glucosamine.

  DOI：

  10.1081/car-120016853

文献信息

• [EN] ALKYLATION OF PHENOLIC COMPOUNDS<br/>[FR] ALKYLATION DE COMPOSÉS PHÉNOLIQUES
  申请人：UNIV SYDNEY

  公开号：WO2015051402A1

  公开（公告）日：2015-04-16

  The invention relates to a process for O-alkyiation of a phenolic compound comprising at least two hydroxyl groups bonded to an aromatic hydrocarbon, the process comprising reacting the phenolic compound with an alkylating agent in the presence of a base, at a suitable reaction temperature and for a suitable time period, thereby alkylating the at least two hydroxy] groups. The invention also relates to O-alkylaled phenolic compounds produced by this process.

  这项发明涉及一种用于对含有至少两个羟基与芳香烃键合的酚类化合物进行O-烷基化的过程，该过程包括在碱的存在下，将酚类化合物与烷基化剂在适当的反应温度和适当的时间内反应，从而使至少两个羟基发生烷基化。该发明还涉及由该过程产生的O-烷基化酚类化合物。
• Polyaldimine derivatives
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0375318A2

  公开（公告）日：1990-06-27

  This invention relates to a novel polyaldimine, preparation process of the polyaldimine, moisture curable polyurethane composition containing the polyaldimine and use of the composition. Polyaldimine of this invention is represented by the formula (I): wherein R¹, R² and R³ are a halogen atom, hydrogen atom, alkoxy group having 4 or less carbon atoms or an alkyl group having 5 or less carbon atoms, and may be the same or different; R⁴ is a hydrogen atom or a methyl group; Y is -N=CH-C(R⁵ )₃ or -N=CH-C(CH₃ )₂-CH₂-O-CO-R⁶ wherein R⁵ is an alkyl group having 4 or less carbon atoms, R⁶ is an alkyl group, anilino group, benzylamino group or an alkylamino group having 16 or less carbon atoms; and ℓ is an integer of 1 or 2, m is an integer of 1 to 3, and n is an integer of 0 to 300. Polyaldimine is prepared by condensation of the corresponding aromatic polyamine and aldehyde. A moisture curable polyurethane composition is prepared from the above polyaldimine and organic polyisocyanates. Sealing materials, wall covering materials, water proof materials and flooring materials can be prepared by blending thixotropic agents or fillers with the polyurethane composition. These materials have very good storage stability and are rapidly cured by atmospheric moisture and cured polyurethane resin having excellent properties can be obtained.

  本发明涉及一种新型聚醛亚胺、该聚醛亚胺的制备工艺、含有该聚醛亚胺的湿气固化聚氨酯组合物以及该组合物的用途。 本发明的聚醛亚胺由式（I）表示： 其中 R¹、R² 和 R³ 是卤素原子、氢原子、具有 4 个或更少碳原子的烷氧基或具有 5 个或更少碳原子的烷基，可以相同或不同；R⁴ 是氢原子或甲基；Y 是-N=CH-C(R⁵ )₃或-N=CH-C(CH₃ )₂-CH₂-O-CO-R⁶，其中 R⁵ 是具有 4 个或更少碳原子的烷基，R⁶ 是具有 16 个或更少碳原子的烷基、苯胺基、苄基氨基或烷基氨基；ℓ 是 1 或 2 的整数，m 是 1 至 3 的整数，n 是 0 至 300 的整数。 聚二甲酰亚胺是由相应的芳香族多胺和醛缩合而成。 由上述聚醛亚胺和有机多异氰酸酯制备出湿气固化型聚氨酯组合物。通过将触变剂或填料与聚氨酯组合物混合，可制备密封材料、墙面材料、防水材料和地板材料。这些材料具有非常好的贮存稳定性，并能在大气湿度的作用下迅速固化，固化后的聚氨酯树脂具有优异的性能。
• Process for the preparation of bisphenols
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0945420A1

  公开（公告）日：1999-09-29

  A process of the production of a bisphenol compound comprising: a step for reacting a phenolic compound (a) with at least one compound (b) selected from the group consisting of dialkenylbenzene compounds, bis(hydroxyalkyl)benzene compounds and (hydroxyalkyl)-alkenylbenzene compounds or at least one compound (c) selected from the group consisting of monoalkenylphenolic compounds and mono(hydroxyalkyl)phenolic compounds in the presence of an acidic catalyst to obtain a reaction mixture containing said bisphenol compound, a step for neutralizing the reaction mixture with an anion exchange resin, a step for removing a remaining phenolic compound from the reaction mixture to concentrate the neutralized reaction mixture, and a step for isolating the bisphenol compound from the resulting concentrated mixture. This process enables to produce a bisphenol compound, which is useful for preparing raw materials of thermoplastic polymers, surface-active agents and stabilizers.

  一种生产双酚化合物的工艺，包括 第一步： 在酸性催化剂存在下，将酚类化合物（a）与至少一种选自二烯基苯化合物、双（羟基烷基）苯化合物和（羟基烷基）-烯基苯化合物或至少一种选自单烯基酚类化合物和单（羟基烷基）酚类化合物的化合物（b）反应，得到含有所述双酚化合物的反应混合物、 用阴离子交换树脂中和反应混合物的步骤、 从反应混合物中去除剩余的酚类化合物以浓缩中和反应混合物的步骤，以及 从浓缩后的混合物中分离出双酚化合物的步骤。 该工艺可以生产出双酚化合物，这种化合物可用于制备热塑性聚合物的原料、表面活性剂和稳定剂。
• [EN] 2',3'-EPOXYPROPYL-3.4-DIHYDROXY BENZENE AND A PROCESS FOR THE PREPARATION THEREOF<br/>[FR] 2',3'-EPOXYPROPYL-3,4-DIHYDROXYBENZÈNE ET PROCÉDÉ POUR LA PRÉPARATION DE CELUI-CI
  申请人：COUNCIL SCIENT IND RES

  公开号：WO2012131717A8

  公开（公告）日：2012-10-26
• Neue Pfropfcopolymere, Verfahren zu ihrer Herstellung und ihre Verwendung
  申请人：BAYER AG

  公开号：EP0312872B1

  公开（公告）日：1991-09-04