benzaldehyde O-[(4-methylphenyl)sulphonyl]oxime | 1517-28-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzaldehyde O-[(4-methylphenyl)sulphonyl]oxime
• 英文别名: benzaldehyde-[O-(toluene-4-sulfonyl)-oxime ]；Benzaldehyd-[O-(toluol-4-sulfonyl)-oxim]；O-p-Toluolsulfonyl-benz-anti-aldoxim；p-Toluolsulfonsaeure-；syn-Benzaldoxim-p-toluolsulfonat；[(E)-benzylideneamino] 4-methylbenzenesulfonate
• CAS: 1517-28-8
• 化学式: C₁₄H₁₃NO₃S
• 分子量: 275.328
• InChiKey: IRZDYZFJYUTZGH-RVDMUPIBSA-N

物化性质

• 熔点：
  85-86 °C
• 沸点：
  415.5±38.0 °C(Predicted)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  64.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  benzaldehyde O-[(4-methylphenyl)sulphonyl]oxime 生成 苯甲腈
  参考文献：
  名称：

  Forster; Judd, Journal of the Chemical Society, 1910, vol. 97, p. 259

  摘要：

  DOI：
• 作为产物：
  描述：

  苯甲醛肟 、 对甲苯磺酰氯 在 sodium amide 作用下， 以 乙醚 为溶剂， 反应 5.0h， 生成 benzaldehyde O-[(4-methylphenyl)sulphonyl]oxime
  参考文献：
  名称：

  Kinetics and mechanism of pyrolysis of sulphonyl hydrazones and oximes. Part 2—Structural effects and molecular reactivity

  摘要：

  The kinetics and products of the pyrolytic reaction of six tosyl arenecarboxaldoximes were studied over the temperature range ca 334 - 401 K to yield the following Arrhenius log A/s(-l) and E-a/kJ mol(-1), respectively: 10.92 and 98.25 for tosyl benzaldoxime and 10.83 and 100.4 for m-nitro-, 10.66 and 97.53 for p-chloro-, 11.80 and 107.8 for m-chloro-, 11.60 and 101.5 for p-methyl- and 10.84 and 97.75 for p-methoxybenzaldehyde O-[(4-methylphenyl) sulphonyl]oxime. At 500 K, the oxime compounds were found to be 9.4 x 10(3) - 2.7 x 10(4)-fold more reactive than their hydrazone analogues. Copyright (C) 1999 John Wiley & Sons, Ltd.

  DOI：

  10.1002/(sici)1099-1395(199908)12:8<654::aid-poc168>3.0.co;2-l

文献信息

• Kinetics and mechanism of pyrolysis of sulphonyl hydrazones and oximes. Part 1. Contribution to reactivity from hydrazone HNN and oxime ON bond polarity
  作者：Nouria A Al-Awadi、Mohamed H Elnagdi、Kamini Kaul、Swaminathan Ilingovan、Osman M.E El-Dusouqui

  DOI：10.1016/s0040-4020(98)00179-3

  日期：1998.4

  Rates were obtained for the pyrolysis of tosyl arenecarboxaldehyde hydrazones (1–5), and mesyl benzaldoxime (6). The substituted tosyl sulphonamides (TsHNN=CHAr: 1–5) and the mesylate (6) gave in a novel pyrolytic reaction the following Arrhenius log A/s−1 and Ea/kJ mol−1 values, respectively: 12.70 and 157.7 (1, ArC6H5), 12.29 and 152.6 (2, -NO2C6H4), 11.85 and 148.2 (3, -NO2C6H4), 12.17 and 152

  获得了对甲苯磺酰基甲醛甲醛hydr（1-5）和甲磺酰基苯甲醛肟（6）的热解速率。在新颖的热解反应中，取代的甲苯磺酰胺（Ts HNN = CHAr：1-5）和甲磺酸酯（6）分别给出以下Arrhenius log A / s -1和E a / kJ mol -1值：12.70和157.7 （1，ArC 6 ħ 5），12.29和152.6（2，-NO 2 ç 6 ħ 4），11.85和148.2（3，-NO 2C 6 H 4），12.17和152.0（4，-ClC 6 H 4），11.01和140.8（5，-CH 3 OC 6 H 4），（6）为12.96和109.9 。还研究了甲苯磺酰基苯甲醛肟（7）。反应生成氰基芳烃以及6和7的磺酸，以及1-5的-甲基苯磺酰胺。
• Polymer Compound, Photoresist Composition Containing Such Polymer Compound, and Method for Forming Resist Pattern
  申请人：Ogata Toshiyuki

  公开号：US20070224520A1

  公开（公告）日：2007-09-27

  A polymer compound that, within a chemically amplified positive resist system, exhibits a significant change in alkali solubility from a state prior to exposure to that following exposure, as well as a photoresist composition that includes such a polymer compound and a method for forming a resist pattern, which are capable of forming fine patterns with a high level of resolution. The polymer compound includes, as an alkali-soluble group (i), a substituent group in which a group selected from amongst alcoholic hydroxyl groups, carboxyl groups, and phenolic hydroxyl groups is protected with an acid dissociable, dissolution inhibiting group (ii) represented by a general formula (1) shown below: [Formula 1] —CH 2 —O-A O—CH 2 —] n (1) (wherein, A represents an organic group of 1 to 20 carbon atoms with a valency of at least n+1, and n represents an integer from 1 to 4).
• US7700259B2
  申请人：——

  公开号：US7700259B2

  公开（公告）日：2010-04-20
• Forster; Judd, Journal of the Chemical Society, 1910, vol. 97, p. 259
  作者：Forster、Judd

  DOI：——

  日期：——
• Kinetics and mechanism of pyrolysis of sulphonyl hydrazones and oximes. Part 2—Structural effects and molecular reactivity
  作者：Nouria A. Al-Awadi、Mohamed H. Elnagdi、Kamini Kaul、Swaminathan Ilingovan、Osman M. E. El-Dusouqui

  DOI：10.1002/(sici)1099-1395(199908)12:8<654::aid-poc168>3.0.co;2-l

  日期：1999.8

  The kinetics and products of the pyrolytic reaction of six tosyl arenecarboxaldoximes were studied over the temperature range ca 334 - 401 K to yield the following Arrhenius log A/s(-l) and E-a/kJ mol(-1), respectively: 10.92 and 98.25 for tosyl benzaldoxime and 10.83 and 100.4 for m-nitro-, 10.66 and 97.53 for p-chloro-, 11.80 and 107.8 for m-chloro-, 11.60 and 101.5 for p-methyl- and 10.84 and 97.75 for p-methoxybenzaldehyde O-[(4-methylphenyl) sulphonyl]oxime. At 500 K, the oxime compounds were found to be 9.4 x 10(3) - 2.7 x 10(4)-fold more reactive than their hydrazone analogues. Copyright (C) 1999 John Wiley & Sons, Ltd.