5,12-di([1,1':3',1''-terphenyl]-5'-yl)-naphthacene | 868273-34-1

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 5,12-di([1,1':3',1''-terphenyl]-5'-yl)-naphthacene
• 英文别名: 5,12-Bis(3,5-diphenylphenyl)tetracene
• CAS: 868273-34-1
• 化学式: C₅₄H₃₆
• 分子量: 684.88
• InChiKey: RMRBJLYKACVJTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.2
• 重原子数：
  54
• 可旋转键数：
  6
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  碳酸亚乙烯酯 、 5,12-di([1,1':3',1''-terphenyl]-5'-yl)-naphthacene 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 72.0h， 以78%的产率得到5,12-di([1,1':3',1''-terphenyl]-5'-yl)-6,11-dihydro-6,11-ethanonaphthacene-cis-13,14-diyl carbonate
  参考文献：
  名称：

  Photochemical synthesis of naphthacene and its derivatives for irreversible photo-responsive fluorescent molecules

  摘要：

  Highly fluorescent naphthacene derivatives and their photoconvertible precursors were synthesized for irreversibly photo-responsive fluorescent molecules. The fluorescence quantum yields (Phi(f)) of the precursors were less than 0.02, and the precursors can be converted to the highly fluorescent naphthacene derivatives (Phi(f) = 0.67-0.70) quantitatively by photo-irradiation. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.01.014
• 作为产物：
  描述：

  5,12-di([1,1':3',1''-terphenyl]-5'-yl)-6,11-dihydro-6,11-ethanonaphthacene-13,14-dione 以 甲苯 为溶剂， 生成 5,12-di([1,1':3',1''-terphenyl]-5'-yl)-naphthacene
  参考文献：
  名称：

  Photochemical synthesis of naphthacene and its derivatives for irreversible photo-responsive fluorescent molecules

  摘要：

  Highly fluorescent naphthacene derivatives and their photoconvertible precursors were synthesized for irreversibly photo-responsive fluorescent molecules. The fluorescence quantum yields (Phi(f)) of the precursors were less than 0.02, and the precursors can be converted to the highly fluorescent naphthacene derivatives (Phi(f) = 0.67-0.70) quantitatively by photo-irradiation. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.01.014

文献信息

• Photochemical synthesis of naphthacene and its derivatives for irreversible photo-responsive fluorescent molecules
  作者：Tatsuya Aotake、Yuko Yamashita、Tetsuo Okujima、Nobuhiko Shirasawa、Yukari Jo、Shigeo Fujimori、Hidemitsu Uno、Noboru Ono、Hiroko Yamada

  DOI：10.1016/j.tetlet.2013.01.014

  日期：2013.4

  Highly fluorescent naphthacene derivatives and their photoconvertible precursors were synthesized for irreversibly photo-responsive fluorescent molecules. The fluorescence quantum yields (Phi(f)) of the precursors were less than 0.02, and the precursors can be converted to the highly fluorescent naphthacene derivatives (Phi(f) = 0.67-0.70) quantitatively by photo-irradiation. (C) 2013 Elsevier Ltd. All rights reserved.