1-methoxy-4-(2,2,2-trichloroethyl)benzene | 3883-15-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-methoxy-4-(2,2,2-trichloroethyl)benzene
• 英文别名: 2,2,2-Trichlor-1-<4-methoxy-phenyl>-ethan；2,2,2-Trichlor-1-(4-methoxy-phenyl)-ethan
• CAS: 3883-15-6
• 化学式: C₉H₉Cl₃O
• 分子量: 239.529
• InChiKey: IQAXWEPTIVVMJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-methoxy-4-(2,2,2-trichloroethyl)benzene 、 potassium thioacyanate 以 乙醚 为溶剂， 反应 20.0h， 生成 氰硫基酸,1,1-二氯-2-(4-甲氧苯基)乙基酯
  参考文献：
  名称：

  Grishchuk, B. D.; Gorbovoi, P. M.; Kudrik, E. Ya., Journal of general chemistry of the USSR, 1991, vol. 61, # 11, p. 2396 - 2401

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1-二氯乙烯 、 para-methoxyphenyldiazonium chloride 在 copper dichloride 作用下， 生成 1-methoxy-4-(2,2,2-trichloroethyl)benzene
  参考文献：
  名称：

  Dombrovskii,A.V.; Naidan,V.M., Journal of general chemistry of the USSR, 1962, vol. 32, p. 1256 - 1258

  摘要：

  DOI：

文献信息

• New oxazolinone compounds useful as intermediates for the preparation of insecticidal and acaracidal cinnamide compounds
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0274546A1

  公开（公告）日：1988-07-20

  The present invention relates to novel cinna­mamide compounds and oxazolinone compounds and processes for the preparation thereof. The compounds of the invention are useful for controlling insects and acarina and the oxazolinone also are useful intermediates in the prepa­ration of the cinnamamide insecticides and acaricides.

  本发明涉及新型肉桂酰胺化合物和噁唑烷酮化合物以及其制备方法。该发明的化合物对控制昆虫和螨虫具有用途，而噁唑烷酮也是肉桂酰胺类杀虫剂和螨虫剂的制备中间体。
• Process for preparing azetidinone derivatives
  申请人：OTSUKA KAGAKU YAKUHIN KABUSHIKI KAISHA

  公开号：EP0114729A1

  公开（公告）日：1984-08-01

  A process for preparing an azetidinone derivative represented by the formula (1) wherein R1 represents a substituted or unsubstituted aryl group, a substituted or unsubstituted phenylmethyl group or a substituted or unsubstituted phenoxymethyl group, R2 represents a hydrogen atom or a group for protecting carboxylic acid and Ar represents a substituted or unsubstituted phenyl group, the process comprising reacting a thiazolineazetidinone derivative represented by the formula (2) wherein R1 and R2 are as defined above with a sulfonyl bromide represented by the formula (3) wherein Ar is as defined above in water-containing organic solvent.

  一种制备式(1)代表的氮杂环丁酮衍生物的工艺，其中R1代表取代或未取代的芳基、取代或未取代的苯基甲基或取代或未取代的苯氧基甲基，R2代表氢原子或保护羧酸的基团，Ar代表取代或未取代的苯基，该工艺包括在含水有机溶剂中将式(2)代表的噻唑啉酮衍生物（其中R1和R2如上定义）与式(3)代表的磺酰溴反应，其中Ar如上定义。
• Crosslinked, porous polymers for controlled delivery of agricultural ingredients
  申请人：CIBA-GEIGY AG

  公开号：EP0190996A2

  公开（公告）日：1986-08-13

  A controlled-release, delivery composition which comprises (A) a crosslinked copolymer, capable of swelling in ethanol to give a swollen copolymer containing at least 40% by weight of ethanol, and capable of swelling in water to give a swollen copolymer containing no more than 20% by weight of water, where the swelling ratio (% ethanol: % water) is 2:1 to 22:1, which comprises the copolymerization product of (a) 50 to 99 % by weight of said copolymer of a water-insoluble monoolefinic monomer or (a) with 0 to 45 % weight of total monomers of a water-soluble monoolefinic monomer, with (b) 50 to 1 % by weight, but not more than 20 mol % of a divinyl or polyvinyl crosslinking agent; and (B) an effective amount of an active agricultural ingredient is useful for the controlled and prolonged release of said ingredient.

  一种控释给药组合物，它包括(A)一种交联共聚物，该共聚物能在乙醇中溶胀，得到含乙醇至少 40%（重量）的溶胀共聚物，并能在水中溶胀，得到含水不超过 20%（重量）的溶胀共聚物，其中溶胀比（乙醇百分比：水百分比）为 2:1 至 22:1：(A)50-99%（重量百分比）的水不溶性单烯烃单体或(a)0-45%（重量百分比）的水溶性单烯烃单体与(b)50-1%（重量百分比）但不超过 20 摩尔%的二乙烯基或聚乙烯交联剂的共聚产物；以及(B)有效量的农业活性成分，有助于控制和延长所述成分的释放。
• Cephalosporin derivatives
  申请人：Otsuka Kagaku Kabushiki Kaisha

  公开号：EP0214600A2

  公开（公告）日：1987-03-18

  A cephalosporin compound substituted by imidazolium ring in 3-position of cephem having the following formula (I), and pharmaceutically acceptable salt thereof, wherein R1 is an organic residue known in β-lactam antibiotics, R2 is hydrogen atom or methoxy, n is 0 or 1, A is a nitrogen-containing group constituting imidazolium ring, is useful as an agent for preventing and treating bacterial infections.

  一种在头孢菌素的 3 位被咪唑环取代的头孢菌素化合物，具有下式(I)及其药学上可接受的盐、 其中 R1 是β-内酰胺类抗生素中已知的有机残基，R2 是氢原子或甲氧基，n 是 0 或 1，A 是构成咪唑环的含氮基团，可作为预防和治疗细菌感染的药物。
• SILOXANE RESIN COMPOSITION AND METHOD FOR PRODUCING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1942150A1

  公开（公告）日：2008-07-09

  A siloxane resin composition comprising a siloxane compound and 1-t-butoxy-2-propanol is provided as a siloxane resin composition capable of being applied onto a substrate with a level difference and good in the capability to cover the level difference of the substrate.

  提供了一种由硅氧烷化合物和 1-t-丁氧基-2-丙醇组成的硅氧烷树脂组合物，作为一种硅氧烷树脂组合物，该组合物能够涂抹在有水平差的基底上，并具有良好的覆盖基底水平差的能力。