The present invention provides an ion selective electrode for anions such as Cl⁻ and cations such as Ca²⁺ which has a sensitive membrane comprising a polymer material and containing an ion sensitive material and a plasticizer. In this ion selective electrode, the ion sensitive material is an ion exchanger such as a quaternary ammonium salt, a quaternary phosphonium salt or an organic phosphate and the plasticizer is a compound having the formula (1):
wherein X represents an alkyl group, a phenyl group or a phenyl group to which a functional group bonds. As the plasticizer there may also be used a mixture of the compound of the formula (1) with an alcohol compound such as an alcohol having a dielectric constant of 10 or less and containing 10 or more carbon atoms or an ester compound.
本发明提供了一种用于阴离子(如 Cl-)和阳离子(如 Ca²⁺)的离子选择电极,该电极的敏感膜由聚合物材料组成,并含有离子敏感材料和
增塑剂。在这种离子选择电极中,离子敏感材料是一种离子交换剂,如季
铵盐、季
鏻盐或有机
磷酸盐,
增塑剂是一种具有式(1)的化合物:
其中 X 代表烷基、苯基或与官能团键合的苯基。作为
增塑剂,也可使用式(1)化合物与
醇类化合物的混合物,如介电常数为 10 或以下且含有 10 个或更多碳原子的醇或
酯类化合物。