Hydroxyl propyl acrylate | 91147-99-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Hydroxyl propyl acrylate
• 英文别名: propyl 2-hydroxyprop-2-enoate
• CAS: 91147-99-8
• 化学式: C₆H₁₀O₃
• 分子量: 130.14
• InChiKey: OGOBWYZAVILZEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Polymers of 3-butene esters, their preparation and use
  申请人：Eastman Chemical Company

  公开号：US20010051690A1

  公开（公告）日：2001-12-13

  The specification describes various polymers having monomer of formula (I): 1 In formula (I), R1 and R2 are, independently, hydrogen, a C 1 -C 24 alkyl group, an aromatic or heteroaromatic group, a C 3 -C 8 cycloalkyl or C 2 -C 7 heterocycloalkyl group, or a —C(O)R3 group in which R3 is a C 1 -C 24 alkyl group, an aromatic or heteroaromatic group, a C 3 -C 8 cycloalkyl or C 2 -C 7 heterocyclic group; or a —CH 2 —C(O)—R4 group in which R4 is a C 1 -C 6 alkyl group. At least one of R1 and R2 is a —C(O)R3 group. The polymer may be a homopolymer or a copolymer containing other ethylenically unsaturated monomers. The polymer may be used in a variety of coating compositions such as inks, adhesives, paints and films. Unique monomers where both R1 and R2 are acetoacetyl groups and novel monomers where R2 is an acetoacetyl group are also described.

  该规范描述了具有式(I)的单体的各种聚合物： 在式(I)中，R1和R2分别是氢、C1-C24烷基、芳香或杂芳基、C3-C8环烷基或C2-C7杂环烷基、或者—C(O)R3基团，其中R3是C1-C24烷基、芳香或杂芳基、C3-C8环烷基或C2-C7杂环基；或者—CH2—C(O)—R4基团，其中R4是C1-C6烷基。R1和R2中至少有一个是—C(O)R3基团。该聚合物可以是同聚物或含有其他乙烯基不饱和单体的共聚物。该聚合物可用于各种涂料组合物，如油墨、粘合剂、油漆和薄膜。还描述了R1和R2均为乙酰乙酰基团的独特单体以及R2为乙酰乙酰基团的新型单体。
• Two stage cure two component coating composition containing hydroxyl butyl acrylate polymers
  申请人：Lewin Ann Laura

  公开号：US20060051594A1

  公开（公告）日：2006-03-09

  An acrylic oligomer useful in a two stage curing coating composition having a weight average molecular weight of 100 to 3000, a polydispersity of 1.01 to 1.7 and one or more reactive functionalities reactive with isocyanate groups and having 7.0 to 40.0 weight percent, based on the weight of the acrylic oligomer, of hydroxyl moieties wherein at least 40.0 to 70.0 weight percent of the hydroxyl moieties are provided by hydroxy butyl acrylate and the remaining hydroxyl moieties are provided by fast reacting hydroxyl constituents of hydroxy ethyl acrylate, hydroxy ethyl methacrylate or any mixtures thereof and by slow reacting hydroxyl constituents of secondary hydroxyl containing hydroxy propyl acrylate and secondary hydroxyl containing hydroxy propyl methacrylate and any mixtures thereof.

  一种丙烯酸低聚物，适用于两阶段固化涂料组合物，其重均分子量为100至3000，聚分散度为1.01至1.7，具有与异氰酸酯基反应的一个或多个反应性官能团，并具有7.0至40.0重量百分比的羟基官能团，其中至少40.0至70.0重量百分比的羟基官能团由羟丙基丙烯酸丁酯提供，其余的羟基官能团由羟乙基丙烯酸酯，羟乙基甲基丙烯酸酯或二者的任何混合物以及次级羟基含量的羟丙基丙烯酸酯和次级羟基含量的羟丙基甲基丙烯酸酯和任何混合物提供。
• [EN] NEW PROPANOATES AND PROCESSES FOR PREPARING THE SAME<br/>[FR] NOUVEAUX PROPANOATES ET LEURS PROCÉDÉS DE PRÉPARATION
  申请人：DUPONT ELECTRONIC POLYMERS L P

  公开号：WO2010024841A1

  公开（公告）日：2010-03-04

  A process for preparing proponates which comprises the steps of (i) supplying a solution of methanol containing 4-hydroxyphenylmethylcarbinol, (ii) subjecting said solution to an acid catalyzed displacement reaction for a sufficient period of time and under suitable conditions of temperature and pressure to convert substantially all of said carbinol to 4-hydroxyphenylmethylcarbinol methyl ether in solution, (iii) replacing the methanol in said ether containing solution with a second solvent and (iv) reacting the ether containing ethyl lactate solution with a suitable acid catalyst for a sufficient period of time and under suitable conditions of temperature and pressure to form said propanoates. New compositions of matter which comprise the propanoates, prepared in the above manner, have application in the electronic chemicals market such as in a photoresist composition.

  一种制备丙酸酯的方法，包括以下步骤：(i)提供含有4-羟基苯甲基碳醇的甲醇溶液，(ii)将该溶液在酸催化的位移反应下，在适当的温度和压力条件下足够长的时间内转化几乎全部的碳醇为溶液中的4-羟基苯甲基碳醇甲醚，(iii)用第二溶剂取代所述醚所含甲醇的溶液，(iv)在适当的温度和压力条件下，用适当的酸催化剂反应所述醚含乙酸乙酯溶液足够长的时间，以形成所述丙酸酯。按照上述方法制备的新物质组成包括丙酸酯，在电子化学品市场上具有应用，例如在光刻胶组合物中。
• Alkoxylated amine and process therefor
  申请人：Coates S. John

  公开号：US20050159625A1

  公开（公告）日：2005-07-21

  A composition that can be used as a component in auto clear coat and primer is disclosed. The composition comprises or is an alkoxylated amine having the formula of (A)[N(R 1 H) 2 ] p including an isomer or mixture of isomers thereof. Also disclosed is a process, which comprises contacting an amine with an epoxide under a condition sufficient to produce an alkoxylated amine. Further disclosed is a composition that can be used as coating composition and primer, which comprises an alkoxylated amine and an organic polyisocyanate.

  本发明公开了一种可用作汽车清漆和底漆组分的组合物。该组合物包括或是具有以下式子的烷氧基化胺物质(A)[N(R1H)2]pi，其中包括其异构体或混合物。本发明还公开了一种工艺，包括将胺物质与环氧化合物接触在足以生成烷氧基化胺的条件下。此外，本发明还公开了一种可用作涂层组分和底漆的组合物，包括烷氧基化胺和有机聚异氰酸酯。
• Reshapable hair styling non-rinse composition comprising (meth)acrylic copolymers
  申请人：L'OREAL

  公开号：US20030147833A1

  公开（公告）日：2003-08-07

  A reshapable hair styling composition comprising, optionally in a cosmetically acceptable vehicle, at least one (meth)acrylic copolymer, wherein the at least one (meth)acrylic copolymer comprises: (a) units derived from at least one monomer chosen from butyl (meth)acrylate monomers, (b) units derived from at least one monomer chosen from hydroxy alkyl (meth)acrylate monomers, and (c) optional units derived from at least one co-polymerizable monomer other than said (a) and (b) monomers, wherein said composition provides a reshapable effect and is a non-rinse composition.

  一种可重塑的发型造型组合物，包括至少一种（甲基）丙烯酸酯共聚物，可选地在美容上可接受的载体中，其中至少一种（甲基）丙烯酸酯共聚物包括：（a）由至少选自丁基（甲基）丙烯酸酯单体制备的单元，（b）由至少选自羟基烷基（甲基）丙烯酸酯单体制备的单元，以及（c）可选单体衍生的单元，除了所述的（a）和（b）单体之外的任何共聚单体，其中该组合物提供可重塑效果且为非冲洗配方。