tris(3,3,3-trifluoropropyl)phosphine oxide | 83280-93-7

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: tris(3,3,3-trifluoropropyl)phosphine oxide
• 英文别名: 3-[Bis(3,3,3-trifluoropropyl)phosphoryl]-1,1,1-trifluoropropane
• CAS: 83280-93-7
• 化学式: C₉H₁₂F₉OP
• mdl: MFCD00421762
• 分子量: 338.153
• InChiKey: VFVMURMCRDXIGP-UHFFFAOYSA-N

物化性质

• 熔点：
  193-195 °C(Solv: acetonitrile (75-05-8))
• 沸点：
  269.2±40.0 °C(Predicted)
• 密度：
  1.350±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  氯化铒(III) 、 tris(3,3,3-trifluoropropyl)phosphine oxide 以 乙腈 为溶剂， 以53%的产率得到trichloro-tris[(3,3,3-trifluoropropyl)phosphine oxide]erbium(III)
  参考文献：
  名称：

  The Er and Yb Complexes with Silicon-Containing Phosphates and Fluorine-Containing Phosphine Oxide: Synthesis, Spectra, and Films

  摘要：

  Three new silicon- and fluorine-containing ligands, namely bis(dimethylamido)(3-triethoxysilyipropylamido)phosphate O = P(NMe2)(2)NHCH2CH2CH2-Si(OEt)(3), diphenyl(3-triethoxysilyipropylamido)phosphate O = P(OPh)(2)NHCH2CH2CH2Si(OEt)(3), and tris(3,3,3-trifluoropropyl)phosphine oxide O = P(CH2CH2CF3)(3) are synthesized. The erbium and ytterbium complexes with amine, phosphate, and phosphine oxide li'gands Ln(NH2R)(3)Cl-3, Ln[O = P(NMe2)(2)NHR](3)Cl-3, Ln[O = P(OPh)(2)NHR](3)Cl-3 (R = CH2CH2CH2Si(OEt)(3)), Ln[O = P(OPh)(3)](3)Cl-3, Ln[O = P(CH2CH2CF3)(3)](3)Cl-3 are produced and their electronic absorption spectra and photoluminescence spectra are studied. The silicon-containing compounds form transparent thermostable films on silicate glass or quartz surface.

  DOI：

  10.1023/b:ruco.0000030166.83903.e0
• 作为产物：
  描述：

  3,3,3-trifluoropropyl magnesium chloride 在 三氯氧磷 作用下， 以 乙醚 为溶剂， 生成 tris(3,3,3-trifluoropropyl)phosphine oxide
  参考文献：
  名称：

  Erbium and ytterbium complexes with phosphates and phosphine oxides

  摘要：

  The new complexes of erbium and ytterbium. with amine, phosphate and phosphine oxide ligands Ln(NH2R)(3)Cl-3, Ln[O=P(NMe2)(2)NHR](3)Cl-3, Ln[O=P(OPh)(2)NHR](3)Cl-3, [R=CH2CH2CH2Si(OEt)(3)], Ln[O=P(OPh)(3)](3)Cl-3, Ln[O=P(CH2CH2CF3)(3)](3)Cl-3 and Ln[O=P(CH=CHPh)(3)](3)Cl-3 have been synthesised, and their absorption spectra have been measured in both films and solutions.

  DOI：

  10.1070/mc2004v014n03abeh001894

文献信息

• Dissociation constants for polyfluoro acids of phosphorus in various media
  作者：A. G. Matveeva、I. Yu. Kudryavtsev、A. A. Grigor'eva、E. I. Matrosov、E. K. Kuznetsova、L. S. Zakharov、M. I. Kabachnik

  DOI：10.1007/bf00954148

  日期：1982.7
• The Er and Yb Complexes with Silicon-Containing Phosphates and Fluorine-Containing Phosphine Oxide: Synthesis, Spectra, and Films
  作者：V. V. Semenov、N. F. Cherepennikova、L. G. Klapshina、M. A. Lopatin、T. G. Mushtina、N. P. Makarenko、S. Ya. Khorshev、G. A. Domrachev、W. E. Douglas、B. A. Bushuk

  DOI：10.1023/b:ruco.0000030166.83903.e0

  日期：2004.6

  Three new silicon- and fluorine-containing ligands, namely bis(dimethylamido)(3-triethoxysilyipropylamido)phosphate O = P(NMe2)(2)NHCH2CH2CH2-Si(OEt)(3), diphenyl(3-triethoxysilyipropylamido)phosphate O = P(OPh)(2)NHCH2CH2CH2Si(OEt)(3), and tris(3,3,3-trifluoropropyl)phosphine oxide O = P(CH2CH2CF3)(3) are synthesized. The erbium and ytterbium complexes with amine, phosphate, and phosphine oxide li'gands Ln(NH2R)(3)Cl-3, Ln[O = P(NMe2)(2)NHR](3)Cl-3, Ln[O = P(OPh)(2)NHR](3)Cl-3 (R = CH2CH2CH2Si(OEt)(3)), Ln[O = P(OPh)(3)](3)Cl-3, Ln[O = P(CH2CH2CF3)(3)](3)Cl-3 are produced and their electronic absorption spectra and photoluminescence spectra are studied. The silicon-containing compounds form transparent thermostable films on silicate glass or quartz surface.
• Erbium and ytterbium complexes with phosphates and phosphine oxides
  作者：Boris A. Bushuk、Sergei B. Bushuk、Nadezhda F. Cherepennikova、William E. Douglas、Georgii K. Fukin、Iliya S. Grigoriev、Larisa G. Klapshina、Arie van der Lee、Vladimir V. Semenov

  DOI：10.1070/mc2004v014n03abeh001894

  日期：2004.1

  The new complexes of erbium and ytterbium. with amine, phosphate and phosphine oxide ligands Ln(NH2R)(3)Cl-3, Ln[O=P(NMe2)(2)NHR](3)Cl-3, Ln[O=P(OPh)(2)NHR](3)Cl-3, [R=CH2CH2CH2Si(OEt)(3)], Ln[O=P(OPh)(3)](3)Cl-3, Ln[O=P(CH2CH2CF3)(3)](3)Cl-3 and Ln[O=P(CH=CHPh)(3)](3)Cl-3 have been synthesised, and their absorption spectra have been measured in both films and solutions.