phenylmethanethiolato thallium(I) | 117028-38-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenylmethanethiolato thallium(I)
• 英文别名: TlSBn；Phenylmethanethiolate;thallium(1+)
• CAS: 117028-38-3
• 化学式: C₇H₇S*Tl
• 分子量: 327.582
• InChiKey: TYMKBZNHMNARAY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.35
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  phenylmethanethiolato thallium(I) 、 [(hydrotris(3,5-diisopropyl-1-pyrazolyl)borate)ZnCl] 以 not given 为溶剂， 生成 (iPr)2TpZn(SBn)
  参考文献：
  名称：

  S-Nitrosothiol and Nitric Oxide Reactivity at Zinc Thiolates

  摘要：

  S-Nitrosothiols undergo reversible transnitrosation reactions at tris (pyrazolyl)boratozinc thiolates (iPr2)TpZn-SR. These zinc thiolates are unreactive toward anaerobic NO but rapidly react with NO in the presence of O-2 or anaerobically with NO2 to release the S-nitrosothiol RSNO with formation of the corresponding zinc nitrate.

  DOI：

  10.1021/ic900664r
• 作为产物：
  描述：

  thallium (I) ethoxide 、 苄硫醇 以 正戊烷 为溶剂， 生成 phenylmethanethiolato thallium(I)
  参考文献：
  名称：

  Synthesis and Characterization of Novel Mononuclear Cadmium Thiolate Complexes in a Sulfur-Rich Environment

  摘要：

  Four different well-defined cadmium monothiolate complexes of general formula (Tmp-Tol)CdSR (R = Bz, Ph, p-Tol, C6F5), where Tmp-Tol is the bulky tris(2-mercapto-1-p-tolylimidazolyl)borate ligand, have been readily synthesized in good yield. An X-ray structure of the phenylthiolate derivative confirmed the monomeric nature of the complexes and allowed the similarities in bond lengths and angles of the thione and thiolate donor groups to be verified at a single metal center.

  DOI：

  10.1021/ic0109243

文献信息

• Reactions of some iron and tungsten mercapto-complexes with electrophilic acetylenes leading to novel metallacycles. The crystal and molecular structure of the η²-vinyl complex [W{η²-C(CF₃)C(CF₃)C(O)SMe}(CO)₂(η⁵-C₅H₅)]
  作者：Jack L. Davidson、Mahmoud Shiralian、Ljubica Manojlović-Muir、Kenneth W. Muir

  DOI：10.1039/dt9840002167

  日期：——

  ligand to give the η2-vinyl complex [Wη2-C(R)C(R)C(O)SR′}(CO)2(η5-C5H5)](R = CF3 only) followed by S-bonded vinyl ketone complexes [[graphic omitted]R′}(CO)2(η5-C5H5)] and ultimately O-bonded vinyl ketone derivatives [[graphic omitted]}(CO)2(η5-C5H5)] and co-ordinatively unsaturated alkyne complexes [W(SR′)(CO)(RCCR)(η5-C5H5)](R = CF3 only). An X-ray structure determination of the η2-vinyl complex [Wη

  的[Fe（SR'）（CO）的反应2（η 5 -C 5 H ^ 5）]与活化的炔烃CF 3 Ç CCF 3和的MeO 2 CC CCO 2我给杂环络合物[[图形省略] R'}（CO ）（η 5 -C 5 H ^ 5）]（R'=烷基或芳基，R = CF 3或CO 2 Me）的。相关衍生物[[图形省略] R'}（CO）2（η 5 -C 5 H ^ 5）]（R'= Me或Et）从[W（SR'）获得的（CO）3（η 5 -C 5 H5）]和在20℃下在己烷中的炔烃经历热异构化的25℃以上最初涉及SR的新颖1,3-移'配体跨越eneone配体，得到η序列2 -乙烯基配合物[W η 2 -C（R）C（R）C（O）SR'}（CO） 2（η 5 -C 5 H ^ 5）]（R = CF 3只），接着S-键合的乙烯基酮络合物[[图形省略] R'}（CO） 2（η 5 -C 5 H ^ 5）]和最终O型键合的乙烯基酮衍生物[[图形省略]}（CO）
• Krebs, Bernt; Broemmelhaus, Andreas, Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Krebs, Bernt、Broemmelhaus, Andreas

  DOI：——

  日期：——
• MUCHOWSKI, JOSEPH M.;GUZMAN, ANGEL
  作者：MUCHOWSKI, JOSEPH M.、GUZMAN, ANGEL

  DOI：——

  日期：——
• Synthesis and Characterization of Novel Mononuclear Cadmium Thiolate Complexes in a Sulfur-Rich Environment
  作者：Selma Bakbak、Christopher D. Incarvito、Arnold L. Rheingold、Daniel Rabinovich

  DOI：10.1021/ic0109243

  日期：2002.2.1

  Four different well-defined cadmium monothiolate complexes of general formula (Tmp-Tol)CdSR (R = Bz, Ph, p-Tol, C6F5), where Tmp-Tol is the bulky tris(2-mercapto-1-p-tolylimidazolyl)borate ligand, have been readily synthesized in good yield. An X-ray structure of the phenylthiolate derivative confirmed the monomeric nature of the complexes and allowed the similarities in bond lengths and angles of the thione and thiolate donor groups to be verified at a single metal center.
• <i>S</i>-Nitrosothiol and Nitric Oxide Reactivity at Zinc Thiolates
  作者：Matthew S. Varonka、Timothy H. Warren

  DOI：10.1021/ic900664r

  日期：2009.7.6

  S-Nitrosothiols undergo reversible transnitrosation reactions at tris (pyrazolyl)boratozinc thiolates (iPr2)TpZn-SR. These zinc thiolates are unreactive toward anaerobic NO but rapidly react with NO in the presence of O-2 or anaerobically with NO2 to release the S-nitrosothiol RSNO with formation of the corresponding zinc nitrate.