ethyl-benzyl-phenyl-phosphine | 25945-92-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ethyl-benzyl-phenyl-phosphine
• 英文别名: Aethyl-benzyl-phenyl-phosphin；Benzyl-ethyl-phenylphosphane
• CAS: 25945-92-0
• 化学式: C₁₅H₁₇P
• 分子量: 228.274
• InChiKey: YQSBHYRKXZRCEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  ethyl-benzyl-phenyl-phosphine 生成 Aethyl-allyl-phenylphosphin
  参考文献：
  名称：

  Horner,L.; Mentrup,A., Justus Liebigs Annalen der Chemie, 1961, vol. 646, p. 65 - 77

  摘要：

  DOI：
• 作为产物：
  描述：

  ethylphenylphosphinous chloride 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 、 乙醚 、 二氯甲烷 为溶剂， 反应 5.0h， 生成 ethyl-benzyl-phenyl-phosphine
  参考文献：
  名称：

  Horner, Leopold; Jordan, Manfred, Phosphorus and Sulfur and the Related Elements, 1980, vol. 8, p. 225 - 234

  摘要：

  DOI：

文献信息

• A novel synthesis of unsymmetrical tertiary phosphines: selective nucleophilic substitution on phosphorus(III)
  作者：Sumita Singh、Kenneth M. Nicholas

  DOI：10.1039/a706428d

  日期：——

  A new synthesis of unsymmetrical tertiary phosphines has been developed employing selective, sequential alkylation of chloroaminophosphines by Grignard and organolithium reagents.

  已经开发出一种新合成不对称三级膦的方法，采用格林纳试剂和有机锂试剂对氯氨基膦进行选择性、顺序的烷基化。
• Methods for the synthesis of milnacipran and congeners thereof
  申请人：Buchwald L. Stephen

  公开号：US20050282898A1

  公开（公告）日：2005-12-22

  One aspect of the present invention relates to methods for synthesizing milnacipran or congeners thereof. Another aspect of the present invention relates to asymmetric methods for synthesizing enantiomerically enriched milnacipran or congeners thereof. The present invention also relates to methods for synthesizing intermediates useful in the non-asymmetric or asymmetric methods for synthesizing enantiomerically enriched milnacipran or congeners thereof.

  本发明的一个方面涉及合成米纳西普兰或其同系物的方法。本发明的另一个方面涉及不对称方法合成对映富集的米纳西普兰或其同系物。本发明还涉及合成中间体的方法，该中间体在合成不对称或对称的对映富集的米纳西普兰或其同系物的方法中有用。
• Titanium trichloride catalyst and process for production of alpha-olefin polymers
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0034935A1

  公开（公告）日：1981-09-02

  A component of a catalyst (for polymerizing olefins) is prepared by reacting a mixture of (1) a titanium trichloride hydrocarbon aluminum halide dialkyl ether composition, (2) a halogen, interhalogen compound or halgenated hydrocarbon and (3) a dialkyl ether, as in known from U.K. Patent No. 1,559,447; to increase activity of the catalyst and stereoregu- lanty of the polymer, the mixture also includes (4) an electron donor, namely an organic compound containing a N, O, Si, S and /or P atom, e.g. an amine, imine, nitrile, ether, ketone, ester, sulfide, silane, siloxane, phosphine, phosphite or phosphate, in an amount of 10-6 to 0.02 mols per gram of titanium trichloride composition (1). The reaction may be in an inert hydrocarbon solvent at 0° to 150°C for 5 minutes to 6 hours, after which the solid is isolated and washed. The catalyst also includes a known hydrocarbon aluminum halide or hydride as activator and may include a further stereoregularity improving agent. Olefins having 2 to 10 carbon atoms are homo- or copolymerized at0°to 100°C to form stereoregular polyolefin using the catalyst in a small amount, e.g. 50 mg per 1.4 Kg of propylene.

  一种催化剂（用于聚合烯烃）的组分是通过以下物质的混合物反应制备的：(1)三氯化 钛烃卤化铝二烷基醚组合物；(2)卤素、卤间化合物或卤代烃；(3)二烷基醚，如英国专利 No.为了提高催化剂的活性和聚合物的立体性，混合物中还包括 (4) 电子供体，即含有 N、O、Si、S 和/或 P 原子的有机化合物，如胺、亚胺、腈、醚、酮、酯、硫化物、硅烷、硅氧烷、磷化氢、亚磷酸盐或磷酸盐，其用量为每克三氯化钛组合物 (1) 10-6 至 0.02 摩尔。 反应可在 0° 至 150°C 的惰性烃类溶剂中进行 5 分钟至 6 小时，然后分离和洗涤固体。 催化剂还包括作为活化剂的已知烃类卤化铝或氢化物，并可包括另一种立体规整度改进剂。 具有 2 至 10 个碳原子的烯烃在 0° 至 100°C 的温度下进行均聚或共聚，形成立体规整的聚烯烃，催化剂的用量很小，例如每 1.4 千克丙烯用 50 毫克。
• Olefin polymerization catalyst and olefin polymerisation process
  申请人：TOSOH CORPORATION

  公开号：EP0619326A1

  公开（公告）日：1994-10-12

  An olefin polymerization catalyst is provided which is composed of an olefin-prepolymerized catalyst prepared by prepolymerizing an olefin on a catalyst formed from (a) a carrier, (c) an organoaluminumoxy compound, and (d) a metallocene compound; (e) an organoaluminum compound, and (f) an ionizing ionic compound. The olefin-prepolymerized catalyst may be prepared with an organoaluminum compound as an additional component of the catalyst. A process for producing a polyolefin is also provided polymerizes or copolymerize olefin in the presence of the above olefin polymerization catalyst. This catalyst exhibits high catalyst activity in olefin polymerization even when the catalyst contains a smaller amount of an organoaluminumoxy compound, and the polyolefin production process gives a polymer having excellent particle properties.

  本发明提供了一种烯烃聚合催化剂，该催化剂由烯烃预聚催化剂组成，烯烃预聚催化剂的制备方法是将烯烃预聚在由(a)载体、(c)有机铝氧化合物和(d)茂金属化合物；(e)有机铝化合物和(f)电离离子化合物形成的催化剂上。烯烃预聚合催化剂可以用有机铝化合物作为催化剂的附加组分来制备。还提供了一种在上述烯烃聚合催化剂存在下聚合或共聚烯烃的聚烯烃生产工艺。这种催化剂在烯烃聚合中表现出很高的催化剂活性，即使催化剂中有机铝氧化合物的含量较低，聚烯烃生产工艺也能得到颗粒性能优良的聚合物。
• PROCESS FOR PRODUCING POLYOXYMETHYLENE COPOLYMER
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1876193A1

  公开（公告）日：2008-01-09

  The problem to be solved is to provide a process for producing a polyoxymethylene copolymer in a molding machine with a reduced generation of formaldehyde gas. In a process for continuously producing a polyoxymethylene copolymer comprising a step of melt-kneading a crude polyoxymethylene copolymer at a temperature not lower than the melting point thereof, devolatilizing under reduced pressure the formaldehyde gas generated as a decomposition product, subsequently mixing a formaldehyde scavenger containing a hydrazide compound (A) while keeping the copolymer in a molten state and immediately pelletizing the mixture, a dispersed solution obtained by slurry-dispersing said (A) in a diluent (B) having a melting point lower than temperature (Ta) which is the lower of the melting point and the decomposition temperature of (A), within a temperature range not lower than the melting point of (B) and lower than (Ta) is used as the formaldehyde scavenger.

  要解决的问题是提供一种在成型机中生产聚甲醛共聚物的工艺，该工艺可减少甲醛气体的产生。在一种连续生产聚甲醛共聚物的工艺中，包括以下步骤：在不低于熔点的温度下对粗聚甲醛共聚物进行熔融捏合，在减压下使作为分解产物产生的甲醛气体脱溶，随后在保持共聚物处于熔融状态的同时混合含有酰肼化合物（A）的甲醛清除剂，并立即对混合物进行造粒、将所述 (A) 在稀释剂 (B) 中进行浆状分散而得到的分散溶液用作甲醛清除剂，稀释剂 (B) 的熔点低于 (A) 的熔点和分解温度中较低的温度 (Ta)，温度范围不低于 (B) 的熔点且低于 (Ta)。