(1-phenylallyl)diphenylphosphine oxide | 13303-57-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1-phenylallyl)diphenylphosphine oxide
• 英文别名: Diphenyl-(1-phenyl-allyl)-phosphinoxid；3-Diphenylphosphinoyl-3-phenylpropen；1-Diphenylphosphorylprop-2-enylbenzene
• CAS: 13303-57-6
• 化学式: C₂₁H₁₉OP
• 分子量: 318.355
• InChiKey: YFAWAENMXQIRAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (1-phenylallyl)diphenylphosphine oxide 、 O-ethyl [3-(1,3-dioxoisoindol-2-yl)-2-oxopropyl]sulfanylmethanethioate 在 二叔丁基过氧化物 作用下， 以 氯苯 为溶剂， 以66%的产率得到2-((E)-2-Oxo-6-phenyl-hex-5-enyl)-isoindole-1,3-dione
  参考文献：
  名称：

  取代的烯丙基二苯基膦氧化物作为自由基烯丙基化剂。

  摘要：

  DOI：

  10.1002/anie.200601556
• 作为产物：
  描述：

  2-(Diphenyl-phosphinoyl)-1-phenyl-3-trimethylsilanyl-propan-1-ol 在 三氟乙酸 作用下， 生成 (1-phenylallyl)diphenylphosphine oxide
  参考文献：
  名称：

  Davidson,A.H. et al., Journal of the Chemical Society. Perkin transactions I, 1977, p. 550 - 565

  摘要：

  DOI：

文献信息

• Flame resistant alkenyl aromatic compounds and polymers containing chemically bonded phosphorus and blends with polyphenylene ether
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0147724A2

  公开（公告）日：1985-07-10

  Flame retardant alkenyl aromatic compounds which are vinylbenzyl diaryl phosphine oxides and a method for their preparation are described. They may be polymerized into higher molecular weight flame retardant materials which, in turn, may be admixed with polyphenylene ether resins to form thermoplastic flame resistant molding compositions. The present materials are more resistant to losses in the flame retardancy upon thermal processing, e.g., molding, because the active flame retardant agent, phosphorus is chemically bound to the polymeric matrix.

  本文介绍了作为乙烯基苄基二芳基膦氧化物的阻燃烯基芳香族化合物及其制备方法。它们可以聚合成更高分子量的阻燃材料，然后与聚苯醚树脂混合，形成热塑性阻燃成型组合物。由于活性阻燃剂磷与聚合物基体发生化学结合，因此本材料在热加工（如成型）过程中的阻燃性能更强。
• Phosphorus-containing resin composition and article made therefrom
  申请人：Elite Material Co., Ltd.

  公开号：US11118055B2

  公开（公告）日：2021-09-14

  A phosphorus-containing resin composition comprises a first phosphorus-containing compound, a second phosphorus-containing compound and a maleimide resin; wherein the first phosphorus-containing compound comprises a compound of Formula (I), a compound of Formula (II), or a combination thereof, and wherein the second phosphorus-containing compound is different from the first phosphorus-containing compound, and the second phosphorus-containing compound is absent of a group capable of reacting with the maleimide resin.

  一种含磷树脂组合物包括第一种含磷化合物、第二种含磷化合物和马来酰亚胺树脂；其中第一种含磷化合物包括式（I）化合物、式（II）化合物或其组合，第二种含磷化合物不同于第一种含磷化合物，且第二种含磷化合物不含能与马来酰亚胺树脂反应的基团。
• Grayson, J. Ian; Warren, Stuart; Zaslona, Alex T., Journal of the Chemical Society. Perkin transactions I, 1987, p. 967 - 976
  作者：Grayson, J. Ian、Warren, Stuart、Zaslona, Alex T.

  DOI：——

  日期：——
• GRAYSON, J. IAN;WARREN, STUART;ZASLONA, ALEX T., J. CHEM. SOC. PERKIN TRANS.,(1987) N 5, 967-976
  作者：GRAYSON, J. IAN、WARREN, STUART、ZASLONA, ALEX T.

  DOI：——

  日期：——
• PHOSPHORUS-CONTAINING RESIN COMPOSITION AND ARTICLE MADE THEREFROM
  申请人：Elite Material Co., Ltd.

  公开号：US20200399471A1

  公开（公告）日：2020-12-24

  A phosphorus-containing resin composition comprises a first phosphorus-containing compound, a second phosphorus-containing compound and a maleimide resin; wherein the first phosphorus-containing compound comprises a compound of Formula (I), a compound of Formula (II), or a combination thereof, and wherein the second phosphorus-containing compound is different from the first phosphorus-containing compound, and the second phosphorus-containing compound is absent of a group capable of reacting with the maleimide resin.