4-([1,1'-biphenyl]-4-ylamino)phenol | 36982-53-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-([1,1'-biphenyl]-4-ylamino)phenol
• 英文别名: 4-Biphenyl-4-ylamino-phenol；4-(4-Phenylanilino)phenol
• CAS: 36982-53-3
• 化学式: C₁₈H₁₅NO
• 分子量: 261.323
• InChiKey: OLAFDQXFJSLRGI-UHFFFAOYSA-N

物化性质

• 熔点：
  148-149 °C
• 沸点：
  438.4±28.0 °C(Predicted)
• 密度：
  1.192±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.3
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-([1,1'-biphenyl]-4-ylamino)phenol 在 tris-(dibenzylideneacetone)dipalladium(0) 、 caesium carbonate 、 2-二-叔丁膦基-2',4',6'-三异丙基联苯 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 14.0h， 生成 N-(4-(3,5-dimethoxy-4-(((4-(trifluoromethyl)phenethyl)amino)methyl)phenoxy)phenyl)-[1,1′ -biphenyl]-4-amine
  参考文献：
  名称：

  Synthesis and biological evaluation of a novel c-Myc inhibitor against colorectal cancer via blocking c-Myc/Max heterodimerization and disturbing its DNA binding

  摘要：

  DOI：

  10.1016/j.ejmech.2022.114779
• 作为产物：
  描述：

  硝基联苯 、 苯酚 在 氢氟酸 、 钯 作用下， 生成 4-([1,1'-biphenyl]-4-ylamino)phenol
  参考文献：
  名称：

  Hydrogen Fluoride as a Condensing Agent. IV. Hydrogen Fluoride as a Solvent for Catalytic Reduction¹

  摘要：

  DOI：

  10.1021/ja01612a012

文献信息

• Fluoran derivatives, process for their preparation and their use in recording systems
  申请人：KANZAKI PAPER MANUFACTURING CO., LTD

  公开号：EP0089752A2

  公开（公告）日：1983-09-28

  A new fluoran derivative useful as a colorless chromogenic material has the general formula: wherein R1, R2, X, Y and Z have the same meaning as defined hereinbefore. Specifically Z is -CH2COOCH2CH=CH2, A is an alkyl having 1 to 18 carbon atoms or an aryl which may be substituted by at least one substituent selected from the group consisting of halogen atoms and alkyls having 1 to 4 carbon atoms, E is hydrogen or each R3 and R4 is hydrogen, an alkyl having 1 to 4 carbon atoms or phenyl; each R, and R2 is an alkyl having 1 to 12 carbon atoms, an aralkyl having 7 to 9 carbon atoms, cyclohexyl or phenyl which may be substituted by at least one substituent selected from the group consisting of halogen atoms and alkyls having 1 to 4 carbon atoms, or both of R, and R2 together with the adjacent nitrogen may form a heterocyclic ring; X is hydrogen, halogen atom, an alkyl having 1 to 4 carbon atoms or an alkoxyl having 1 to 2 carbon atoms; and Y is hydrogen, halogen atom or an alkyl having 1 to 4 carbon atoms; however, when Z is -CH2COOCH2CH=CH2 or each R, and R2 is an alkyl having 1 to 12 carbon atoms or an aralkyl having 7 to 9 carbon atoms, when Z is each R, and R2 is an alkyl having 1 to 4 carbon atoms, X is hydrogen and Y is hydrogen or methyl, when Z is each R, and R2 is an alkyl having 1 to 12 carbon atoms or an aralkyl having 7 to 9 carbon atoms, and, at least one of X and Y is selected from the before-mentioned substituents other than hydrogen, and when Z is A is an alkyl having 1 to 18 carbon atoms and each R, and R2 is an alkyl having 1 to 12 carbon atoms or an aralkyl having 7 to 9 carbon atoms, at least one of X and Y is selected from the beforementioned substituents other than hydrogen.

  一种可用作无色发色材料的新芴衍生物通式如下 其中 R1、R2、X、Y 和 Z 的含义与前文定义相同。 具体地说，Z 是-CH2COOCH2CH=CH2、 A 是具有 1 至 18 个碳原子的烷基或芳基，可被至少一个选自卤素原子和具有 1 至 4 个碳原子的烷基的取代基取代； E 是氢或 每个 R3 和 R4 是氢、具有 1 至 4 个碳原子的烷基或苯基；每个 R 和 R2 是具有 1 至 12 个碳原子的烷基、具有 7 至 9 个碳原子的芳基、环己基或苯基，可被至少一种选自卤素原子和具有 1 至 4 个碳原子的烷基的取代基取代，或 R 和 R2 与相邻的氮可形成杂环；X 是氢、卤素原子、具有 1 至 4 个碳原子的烷基或具有 1 至 2 个碳原子的烷氧基； Y 是氢、卤素原子或具有 1 至 4 个碳原子的烷基；但当 Z 是-CH2COOCH2CH=CH2 或 每个 R 和 R2 是具有 1 至 12 个碳原子的烷基或具有 7 至 9 个碳原子的芳烷基时，当 Z 是 每个 R 和 R2 都是具有 1 至 4 个碳原子的烷基，X 是氢，Y 是氢或甲基，当 Z 是 当 Z 是每个 R，且 R2 是具有 1 至 12 个碳原子的烷基或具有 7 至 9 个碳原子的芳烷基，且 X 和 Y 中至少有一个选自氢以外的前述取代基，且当 Z 是 A 是具有 1 至 18 个碳原子的烷基，每个 R 和 R2 是具有 1 至 12 个碳原子的烷基或具有 7 至 9 个碳原子的芳烷基，且 X 和 Y 中至少有一个选自氢以外的前述取代基。
• COMPOSITION FOR USE IN ORGANIC DEVICE, POLYMER FILM, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3173456A1

  公开（公告）日：2017-05-31

  The present invention relates to a composition for use in an organic device, comprising at least two cross-linking compounds, wherein each of the at least two cross-linking compounds is a polymer that has a hole-transporting site and constitutional repeating units, the at least two polymers having different average numbers of cross-linking groups per constitutional repeating unit and/or different numbers of cross-linking groups in portions other than the constitutional repeating units, and wherein the cross-linking compounds are compounds having a partial structure of the following formula [109]: The present invention further pertains to an organic electroluminescent element that comprises an anode and a cathode on a substrate and at least one organic layer disposed between the anode and the cathode, wherein at least one organic layer is a layer that is produced by forming a film of the composition for use in an organic device above.

  本发明涉及一种用于有机器件的组合物，该组合物包含至少两种交联化合物，其中 至少两种交联化合物中的每一种都是具有空穴传输位点和构型重复单元的聚合物，至少两种聚合物在每个构型重复单元中具有不同的平均交联基团数和/或在构型重复单元以外的部分中具有不同的交联基团数，以及 其中交联化合物是具有下式[109]部分结构的化合物： 本发明还涉及一种有机电致发光元件，该元件包括基底上的阳极和阴极以及设置在阳极和阴极之间的至少一个有机层，其中至少一个有机层是通过形成用于上述有机器件的组合物薄膜而产生的层。
• COMPOUND FOR ORGANIC ELECTRONIC DEVICE, ORGANIC ELECTRONIC DEVICE USING SAME, AND ELECTRONIC DEVICE THEREFOR
  申请人：Duk San Neolux Co., Ltd.

  公开号：EP3730490A1

  公开（公告）日：2020-10-28

  The present invention provides an organic electroluminescent element and electronic device thereof, wherein the organic electroluminescent element comprises the compound represented by Formula 1 as material for an emission-auxiliary layer, and by comprising the compound represented by Formula 1 in the emission-auxiliary layer, the driving voltage of the organic electroluminescent element can be lowered, and the luminous efficiency and life time of the organic electroluminescent element can be improved.

  本发明提供了一种有机电致发光元件及其电子装置，其中有机电致发光元件包括作为发射辅助层材料的式 1 所代表的化合物，通过在发射辅助层中加入式 1 所代表的化合物，可以降低有机电致发光元件的驱动电压，提高有机电致发光元件的发光效率和使用寿命。
• COMPOSITION FOR ORGANIC DEVICE, POLYMER MEMBRANE AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2117062B1

  公开（公告）日：2017-01-18
• Material for organic electronic device and organic electronic device using the same
  申请人：LG CHEM, LTD.

  公开号：EP2796448B1

  公开（公告）日：2018-04-25