tritium bromine | 15606-42-5

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 英文名称: tritium bromine
• CAS: 15606-42-5
• 化学式: BrH
• 分子量: 82.904
• InChiKey: CPELXLSAUQHCOX-MNYXATJNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  1
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tritium bromine 、 水 以 not given 为溶剂， 生成 氢氧化氚
  参考文献：
  名称：

  Dissociation and Exchange Equilibria of the Tritium Halides

  摘要：

  The ratios of the partition functions of the tritium halides to their respective protium halides have been calculated. These are combined with one another to give the exchange equilibria between the six pairs of tritium and protium halides. The exchange equilibria with water are calculated. From the exchange equilibria between the tritium halides and protium and the free energy of dissociation of the protium halides, the dissociation equilibria of the tritium halides have been calculated. The experimental data on the dissociation of HI are reviewed and it is shown that the data of Taylor and Crist on DI and HI are self-consistent as well as in good agreement with theory. The heat of formation of HI at absolute zero, ΔH00, is found to be − 1007±10 calories per mole.

  DOI：

  10.1063/1.1747665
• 作为产物：
  描述：

  氢溴酸 、 tritium 以 gas 为溶剂， 生成 tritium bromine
  参考文献：
  名称：

  等动力学关系。五，双分子反应体系的研究

  摘要：

  检查了双分子反应系列中等动力学关系的出现。结果表明，Arrhenius曲线交点的横坐标由碰撞配合物与周围热浴的相互作用以及该配合物必须克服的势垒的高度决定。负等速温度（即“反补偿”）的出现已被解释并证明适用于二阶气相反应。随着反应物和热浴之间相互作用的增加（例如在冷凝相反应中），相交的共同点朝着更高的等速等温线移动。该理论适用于气相和液相反应，

  DOI：

  10.1016/0301-0104(87)85059-0

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: O: MVol.6, 85, page 2054 - 2056
  作者：

  DOI：——

  日期：——
• Dissociation and Exchange Equilibria of the Tritium Halides
  作者：Jacob Bigeleisen

  DOI：10.1063/1.1747665

  日期：1950.4

  The ratios of the partition functions of the tritium halides to their respective protium halides have been calculated. These are combined with one another to give the exchange equilibria between the six pairs of tritium and protium halides. The exchange equilibria with water are calculated. From the exchange equilibria between the tritium halides and protium and the free energy of dissociation of the protium halides, the dissociation equilibria of the tritium halides have been calculated. The experimental data on the dissociation of HI are reviewed and it is shown that the data of Taylor and Crist on DI and HI are self-consistent as well as in good agreement with theory. The heat of formation of HI at absolute zero, ΔH00, is found to be − 1007±10 calories per mole.
• The isokinetic relationship. V. Investigation of Bimolecular reaction systems
  作者：Wolfgang Linert

  DOI：10.1016/0301-0104(87)85059-0

  日期：1987.6

  is explained and demonstrated for second-order gas phase reactions. With increasing interactions between the reactants and the heat bath (for example in condensed phase reactions) the common point of intersection is shifted towards greater reciprocal isokinetic temperatures. The theory is applied to both gas phase and liquid phase reactions, the crucial heat-bath vibrational frequencies calculated

  检查了双分子反应系列中等动力学关系的出现。结果表明，Arrhenius曲线交点的横坐标由碰撞配合物与周围热浴的相互作用以及该配合物必须克服的势垒的高度决定。负等速温度（即“反补偿”）的出现已被解释并证明适用于二阶气相反应。随着反应物和热浴之间相互作用的增加（例如在冷凝相反应中），相交的共同点朝着更高的等速等温线移动。该理论适用于气相和液相反应，