2,2-Bis(diphenylphosphoryl)ethyl-chloro-dimethyl-stannane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-Bis(diphenylphosphoryl)ethyl-chloro-dimethyl-stannane
• 英文别名: 2,2-bis(diphenylphosphoryl)ethyl-chloro-dimethylstannane
• 化学式: C₂₈H₂₉ClO₂P₂Sn
• 分子量: 613.648
• InChiKey: MNGXTZTYPIOVNY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.78
• 重原子数：
  34
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  盐酸 、 以 乙醚 、 二氯甲烷 为溶剂， 以92.3%的产率得到2,2-Bis(diphenylphosphoryl)ethyl-chloro-dimethyl-stannane
  参考文献：
  名称：

  The structural behaviour of 2,2-functionally disubstituted triorganotin chlorides

  摘要：

  A series of 13 2,2-difunctional triorganotin chlorides of the general formula Me(2)(Cl)SnCH2CH(X=O)Y=O(X=O, Y=O=P(O)R(2), C(O)R; R=(OPr)-Pr-i, Oet, Ph) has been synthesized by chlorination of the corresponding tetraorganotin compounds Me(3)SnCH(2)CH(X=O)Y=O with HCl in diethyl ether. The crystal structure determination of Me(2)(Cl)SnCH2[P(O)((OPr)-Pr-i)(2)](2) (VIII), IR spectroscopic data and NMR studies reveal, for the title compounds, molecular structures in which the tin atom, approaches a trigonal-bipyramidal pentacoordinated ligand arrangement as result of an intramolecular Sn ... O interaction of one of the two functional groups X=O or Y=O respectively, In solution the compounds undergo a ligand exchange process which has been investigated by NMR. A mechanism of this process is suggested.

  DOI：

  10.1016/0022-328x(95)06047-z

文献信息

• The structural behaviour of 2,2-functionally disubstituted triorganotin chlorides
  作者：F Richter、M Dargatz、H Hartung、D Schollmeyer、H Weichmann

  DOI：10.1016/0022-328x(95)06047-z

  日期：1996.5

  A series of 13 2,2-difunctional triorganotin chlorides of the general formula Me(2)(Cl)SnCH2CH(X=O)Y=O(X=O, Y=O=P(O)R(2), C(O)R; R=(OPr)-Pr-i, Oet, Ph) has been synthesized by chlorination of the corresponding tetraorganotin compounds Me(3)SnCH(2)CH(X=O)Y=O with HCl in diethyl ether. The crystal structure determination of Me(2)(Cl)SnCH2[P(O)((OPr)-Pr-i)(2)](2) (VIII), IR spectroscopic data and NMR studies reveal, for the title compounds, molecular structures in which the tin atom, approaches a trigonal-bipyramidal pentacoordinated ligand arrangement as result of an intramolecular Sn ... O interaction of one of the two functional groups X=O or Y=O respectively, In solution the compounds undergo a ligand exchange process which has been investigated by NMR. A mechanism of this process is suggested.