N-Morpholinomethyl-carbazol | 27850-89-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: N-Morpholinomethyl-carbazol
• 英文别名: 4-((9H-carbazol-9-yl)methyl)morpholine；9-morpholin-4-ylmethyl-carbazole；9-morpholinomethyl-carbazole；9-Morpholinomethyl-carbazol；9-(4-morpholinylmethyl)-9H-carbazole；4-(carbazol-9-ylmethyl)morpholine
• CAS: 27850-89-1
• 化学式: C₁₇H₁₈N₂O
• 分子量: 266.343
• InChiKey: PFEKOKFOEJWYTB-UHFFFAOYSA-N

物化性质

• 熔点：
  148 °C
• 沸点：
  439.5±45.0 °C(Predicted)
• 密度：
  1.20±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  17.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-methoxymethyl-morpholine 、 咔唑 在 hafnium tetrakis(trifluoromethanesulfonate) 作用下， 以 二氯甲烷 为溶剂， 反应 5.0h， 以92%的产率得到N-Morpholinomethyl-carbazol
  参考文献：
  名称：

  Hf(OTf)₄-Catalyzed Regioselective N-Aminomethylation of Indoles and Related NH-Containing Heterocycles

  摘要：

  Under Lewis acidic conditions using Hf(OTf)(4), the aminomethylation of an indole derivative with a typical N,O-acetal preferentially produced kinetically favored N-aminomethylated indole derivatives instead of thermodynamically favored 3-aminomethylated indoles.

  DOI：

  10.1021/jo1006043

文献信息

• BASE AND RADICAL GENERATOR, COMPOSITION USING SAME AND METHOD FOR CURING SAME
  申请人：THREE BOND CO., LTD.

  公开号：EP2444391B1

  公开（公告）日：2013-11-06
• Hellmann et al., Chemische Berichte, 1954, vol. 87, p. 1690,1697
  作者：Hellmann et al.

  DOI：——

  日期：——
• Photosensitive Polybenzoxazines and Methods of Making the Same
  申请人：Yamanaka Kazuhiro

  公开号：US20100009290A1

  公开（公告）日：2010-01-14

  Photosensitive polybenzoxazine compositions include a photosensitive additive such as an o-diazoquinone and a polymer comprising a repeating unit represented by the following formula (I) wherein R 1 comprises an aliphatic group, an alicyclic group, an aromatic group, a heterocyclic group, or combinations thereof, R 2 comprises an aliphatic group, an alicyclic group, an aromatic group, a heterocyclic group, or combinations thereof, R 4 comprises a hydrophilic group, a hydrophilic group protected by an acid-cleavable group, a hydrophilic group protected by a base-cleavable group, a cross-linkable group, or combinations thereof, and i represents an integer of 1 or more. The photosensitive compositions may be formed by combining a precursor polymer with a photosensitive additive and a solvent, patterning the precursor polymer, and heating the precursor polymer at a thermal processing temperature in a range of from about 180° C. to about 300° C. to convert the precursor polymer into the final polymer.
• Photosensitive Polyimides and Methods of Making the Same
  申请人：Yamanaka Kazuhiro

  公开号：US20100216070A1

  公开（公告）日：2010-08-26

  Photosensitive polyimide compositions include a photosensitive additive and a polymer comprising a repeating unit represented by the following formula (I): wherein R 1 comprises an aliphatic group, an alicyclic group, an aromatic group, a heterocyclic group, or combinations thereof, R 2 comprises an aliphatic group, an alicyclic group, an aromatic group, a heterocyclic group, or combinations thereof, R 3 represents hydrogen or an organic group comprising a hydrophilic group, an acid-cleavable group, a base-cleavable group, a cross-linkable group, or combinations thereof, and h represents an integer of 1 or more. The photosensitive compositions may be formed by combining a precursor polymer with a processing solvent, followed by a relatively low-temperature cyclization process in which the precursor polymer is converted to the final polymer. The resulting polyimide may be separated from the solution and purified. It may then be combined with a casting solvent and a photosensitive additive.
• POLARIZING PLATE MANUFACTURING METHOD
  申请人：Murakami Ai

  公开号：US20120057230A1

  公开（公告）日：2012-03-08

  A method for manufacturing a polarizing plate comprising a polarizing film and a transparent protective film provided on at least one surface of the polarizing film, the method comprising the steps of: subjecting at least a surface of the transparent protective film to be bonded to the polarizing film to an adhesion improving treatment; bringing water into contact with at least the surface subjected to the adhesion improving treatment; and laminating the transparent protective film on the polarizing film so that the surface subjected to the adhesion improving treatment and brought into contact with water is bonded to the polarizing film.