(4',5'-bis(2,5-dimethylthiophen-3-yl)-2,2'-bithiophen-5-yl)dimesitylborane | 1350460-42-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: (4',5'-bis(2,5-dimethylthiophen-3-yl)-2,2'-bithiophen-5-yl)dimesitylborane
• 英文别名: [5-[4,5-Bis(2,5-dimethylthiophen-3-yl)thiophen-2-yl]thiophen-2-yl]-bis(2,4,6-trimethylphenyl)borane；[5-[4,5-bis(2,5-dimethylthiophen-3-yl)thiophen-2-yl]thiophen-2-yl]-bis(2,4,6-trimethylphenyl)borane
• CAS: 1350460-42-2
• 化学式: C₃₈H₃₉BS₄
• 分子量: 634.803
• InChiKey: UFSBBXAPWNNAQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.53
• 重原子数：
  43
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  113
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (4',5'-bis(2,5-dimethylthiophen-3-yl)-2,2'-bithiophen-5-yl)dimesitylborane 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Gated Photochromism in Triarylborane-Containing Dithienylethenes: A New Approach to a “Lock–Unlock” System

  摘要：

  Photochromic inactive dithienylethene derivatives appended with 3- or 5-dimesityiboryl-2,2'-bithiophene have been synthesized. Upon fluoride ion-binding, the photochromic reactivity is "unlocked", displaying a novel gated photochromic property.

  DOI：

  10.1021/ja208097a
• 作为产物：
  描述：

  4,4,5,5-tetramethyl-2-(2,2'',5,5''-tetramethyl-[3,2':3’,3''-terthiophen]-5'-yl)-1,3,2-dioxaborolane 在 四(三苯基膦)钯 、 正丁基锂 、 caesium carbonate 作用下， 以 四氢呋喃 、 乙醚 、 水 为溶剂， 反应 1.0h， 生成 (4',5'-bis(2,5-dimethylthiophen-3-yl)-2,2'-bithiophen-5-yl)dimesitylborane
  参考文献：
  名称：

  Gated Photochromism in Triarylborane-Containing Dithienylethenes: A New Approach to a “Lock–Unlock” System

  摘要：

  Photochromic inactive dithienylethene derivatives appended with 3- or 5-dimesityiboryl-2,2'-bithiophene have been synthesized. Upon fluoride ion-binding, the photochromic reactivity is "unlocked", displaying a novel gated photochromic property.

  DOI：

  10.1021/ja208097a

文献信息

• Photochromic Dithienylethene-Containing Triarylborane Derivatives: Facile Approach to Modulate Photochromic Properties with Multi-addressable Functions
  作者：Chun-Ting Poon、Wai Han Lam、Hok-Lai Wong、Vivian Wing-Wah Yam

  DOI：10.1002/chem.201404784

  日期：2015.1.26

  A series of dithienylethene‐containing triarylboranes has been designed, synthesized, and characterized. The electrochemistry, photophysics, and photochromic behavior have also been studied. The photophysical and photochromic properties could be facilely tuned in this system by varying the thiophene spacers (thiophene, thienothiophene, and bithiophene) between the dithienylethene and the dimesitylboron

  已设计，合成和表征了一系列含二噻吩基乙烯的三芳基硼烷。还研究了电化学，光物理和光致变色行为。可以通过在二噻吩乙烯和二烯基异丁酮（BMes 2）之间改变噻吩间隔基（噻吩，噻吩并噻吩和联噻吩）或噻吩间隔基中BMes 2取代的位置来方便地调节光物理性质和光致变色性质。已经发现，在引入BMes 2单元后，封闭形式的吸收对结构修饰更敏感。而且，在添加路易斯碱的（获得的多寻址光致变色反应˚F -），这是由于形成了硼-刘易斯碱加合物。计算研究进一步支持了光物理性质和光致变色性质对噻吩间隔基和BMes 2取代位置的依赖性。
• Gated Photochromism in Triarylborane-Containing Dithienylethenes: A New Approach to a “Lock–Unlock” System
  作者：Chun-Ting Poon、Wai Han Lam、Vivian Wing-Wah Yam

  DOI：10.1021/ja208097a

  日期：2011.12.14

  Photochromic inactive dithienylethene derivatives appended with 3- or 5-dimesityiboryl-2,2'-bithiophene have been synthesized. Upon fluoride ion-binding, the photochromic reactivity is "unlocked", displaying a novel gated photochromic property.