6-hydroxy-5-phenylpyrimidine-2,4(1H,3H)-dione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 6-hydroxy-5-phenylpyrimidine-2,4(1H,3H)-dione
• 英文别名: 6-Hydroxy-5-phenyl-1H-pyrimidine-2,4-dione
• 化学式: C₁₀H₈N₂O₃
• 分子量: 204.185
• InChiKey: YKIRLIHLAMNNJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  78.4
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  巴比妥酸 、 benzenediazonium tetrafluoroborate 在 吡啶 作用下， 以 二甲基亚砜 为溶剂， 以84 %的产率得到6-hydroxy-5-phenylpyrimidine-2,4(1H,3H)-dione
  参考文献：
  名称：

  通过电子供体-受体 (EDA) 复合物用重氮盐光触发活性亚甲基化合物的 C 芳基化

  摘要：

  在没有光催化剂的情况下，在可见光条件下阐明活性亚甲基化合物的C-芳基化是一个智力挑战。通过电子供体-受体（EDA）复合物的光诱导活性亚甲基化合物的C-芳基化显示了合成药理学相关化合物的战略途径。这种广泛而有效的方法促进了在环保条件下的C-芳基化，表现出与不同官能团的示例性相容性并产生多种化合物。这种环境上可持续的转变强调了程序简单和反应条件良好的优点。值得注意的是，所有所得产品均通过 EDA 复合物的中介作用，明智地从活性亚甲基化合物和重氮盐衍生而来。

  DOI：

  10.1039/d3cc05356c

文献信息

• POLARIZING PLATE PROTECTIVE FILM, POLARIZING PLATE, AND DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20170226317A1

  公开（公告）日：2017-08-10

  A polarizing plate protective film which prevents deterioration of polarization performance in a high temperature, high humidity environment, and a polarizing plate and display device using the film including a compound represented by the following General Formula (I). (X-L n z General Formula (I) X represents a formyl group, a boronic acid group, or a group represented by the following General Formula (I-B) or a group represented by the following General Formula (I-C), where L represents a single bond or divalent linking group, and n represents an integer equal to or greater than 2. When n is 2, Z represents a single bond or a divalent group, and when n≧3, Z represents an n-valent group. R A and R B represent an alkyl group, a cycloalkyl group, an aryl group, or an acyl group. R A and R B may be bonded to each other to form a ring. * represents a bond to be bonded to L.

  一种偏光板保护膜，可防止在高温高湿环境中偏光性能的恶化，以及使用包括下述一般式（I）所代表的化合物的偏光板和显示装置。 （X-L n z 一般式（I） X代表甲酰基、硼酸基或由下述一般式（I-B）所代表的基团或由下述一般式（I-C）所代表的基团，其中L代表单键或二价连接基团，n代表大于或等于2的整数。当n为2时，Z代表单键或二价基团，当n≧3时，Z代表n价基团。 RA和RB代表烷基、环烷基、芳基或酰基。RA和RB可以相互连接形成环。*代表要连接到L的键。
• RESIN COMPOSITION, PROTECTIVE FILM FOR POLARIZING PLATE, POLARIZING PLATE, AND DISPLAY
  申请人：FUJIFILM Corporation

  公开号：US20160200933A1

  公开（公告）日：2016-07-14

  A resin composition including compounds represented by Formulas (1) and (TA); and a protective film for a polarizing plate and a display using the same: wherein A 11 and A 12 independently designate a heteroatom; Y 11 and Y 12 independently designate a hydrogen atom or a substituent; at least one of Y 11 and Y 12 has the Hammett's substituent constant σp value of 0.2 or more; Q 11 designates a group of atoms required for forming a 5- or 6-membered ring bonded with A 11 , A 12 and the carbon atom of >C═; R 1a to R 1e each independently designate a hydrogen atom or a substituent other than a hydroxy group; when at least one of R 1a to R 1e is a substituent, at least one has the Hammett's substituent constant σp value of 0.3 or more; and R 1g to R 1j and R 1k to R 1p independently designate a hydrogen atom or a substituent.
• COMPOSITION FOR POLARIZING PLATE, POLARIZING PLATE PROTECTIVE FILM, CELLULOSE ACYLATE FILM, POLARIZER, POLARIZING PLATE, AND DISPLAY
  申请人：FUJIFILM Corporation

  公开号：US20160185993A1

  公开（公告）日：2016-06-30

  A composition for a polarizing plate containing a polymer having a partial structure represented by the following ring structure α or β in the molecule, a polarizing plate protective film, a cellulose acylate film, a polarizer, a polarizing plate, and a display; wherein L 1 represents a single bond, —C(═O)—, —C(═S)—, an alkylene group, or an arylene group; and the symbol * designates a boning hand, or a site to which a hydrogen atom, a substituent, or a linking group binds.
• US9256099B2
  申请人：——

  公开号：US9256099B2

  公开（公告）日：2016-02-09
• US9341882B2
  申请人：——

  公开号：US9341882B2

  公开（公告）日：2016-05-17