3-Phenylpropanoic acid, undecyl ester | 959261-50-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-Phenylpropanoic acid, undecyl ester
• 英文别名: undecyl 3-phenylpropanoate
• CAS: 959261-50-8
• 化学式: C₂₀H₃₂O₂
• 分子量: 304.473
• InChiKey: LVXVAWQHAPVEQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  10-undecencyl cinnamate 在 palladium-loaded multi-walled carbon nanotube 氢气 、 甲酸铵 作用下， 以 乙醇 为溶剂， 160.0 ℃ 、1.2 MPa 条件下， 反应 0.08h， 以99%的产率得到3-Phenylpropanoic acid, undecyl ester
  参考文献：
  名称：

  Microwave-promoted hydrogenation and alkynylation reactions with palladium-loaded multi-walled carbon nanotubes

  摘要：

  负载有Pd(0)簇（平均粒径分布为9纳米）的多壁碳纳米管在微波辐射下作为催化剂，用于氢化和炔基化反应，且在“环保”条件下进行；获得了较高产率的还原肉桂酯和交叉偶联产物；使用哌啶作为碱提供了一种区域选择性的过程，合成了新型的双炔基化合物，且通过核磁共振相关实验和X射线衍射进行了明确表征。

  DOI：

  10.1039/b802014k

文献信息

• LOW VISCOSITY LOW VOLATILITY LUBRICATING OIL BASE STOCKS AND METHODS OF USE THEREOF
  申请人：ExxonMobil Research and Engineering Company

  公开号：EP3397737A2

  公开（公告）日：2018-11-07
• [EN] LOW VISCOSITY LOW VOLATILITY LUBRICATING OIL BASE STOCKS AND METHODS OF USE THEREOF<br/>[FR] HUILES DE BASE D'HUILE LUBRIFIANTE À FAIBLE VISCOSITÉ ET FAIBLE VOLATILITÉ ET PROCÉDÉS D'UTILISATION ASSOCIÉ
  申请人：EXXONMOBIL RES & ENG CO

  公开号：WO2017116899A2

  公开（公告）日：2017-07-06

  A lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein. The lubricating oil base stock has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683, and a Noack volatility from about 15 to about 90 percent as determined by ASTM D5800. A lubricating oil containing the lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein. A method for improving one or more of thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein.