2-bromo-1',3'-dihydrospiro[fluorene-9,2'-indene] | 401941-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2-bromo-1',3'-dihydrospiro[fluorene-9,2'-indene]
• 英文别名: N2-(2-bromo-1',3'-dihydrospirocyclic[fluorene-9,2'-indene])；2'-Bromospiro[1,3-dihydroindene-2,9'-fluorene]
• CAS: 401941-41-1
• 化学式: C₂₁H₁₅Br
• 分子量: 347.254
• InChiKey: PVMZOXYCYJQSJG-UHFFFAOYSA-N

物化性质

• 沸点：
  420.6±24.0 °C(Predicted)
• 密度：
  1.48±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-bromo-1',3'-dihydrospiro[fluorene-9,2'-indene] 在 bis-triphenylphosphine-palladium(II) chloride 、 四(三苯基膦)钯 正丁基锂 、 溴 、 甲基三辛基氯化铵 、 sodium carbonate 、 potassium carbonate 作用下， 以 四氢呋喃 、 乙醇 、 正己烷 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 18.0h， 生成 2'-(10-Phenylanthracen-9-yl)-7'-[4-(10-phenylanthracen-9-yl)phenyl]spiro[1,3-dihydroindene-2,9'-fluorene]
  参考文献：
  名称：

  LUMINESCENT COMPOUNDS AND ELECTROLUMINESCENT DEVICE USING THE SAME

  摘要：

  本发明涉及有机电致发光化合物和采用这些化合物的有机电致发光器件。更具体地，该发明涉及含有蒽基或在芴或间芴芴环的芳基上具有蒽基取代基的有机电致发光化合物，作为有机电致发光层中的蓝色电致发光材料。根据本发明的电致发光化合物表现出高发光效率和优异的寿命特性，因此可以制备出具有非常良好操作寿命的OLED器件。

  公开号：

  US20110054229A1
• 作为产物：
  描述：

  2-溴芴 、 1,2-二(溴甲基)苯 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 生成 2-bromo-1',3'-dihydrospiro[fluorene-9,2'-indene]
  参考文献：
  名称：

  LUMINESCENT COMPOUNDS AND ELECTROLUMINESCENT DEVICE USING THE SAME

  摘要：

  本发明涉及有机电致发光化合物和采用这些化合物的有机电致发光器件。更具体地，该发明涉及含有蒽基或在芴或间芴芴环的芳基上具有蒽基取代基的有机电致发光化合物，作为有机电致发光层中的蓝色电致发光材料。根据本发明的电致发光化合物表现出高发光效率和优异的寿命特性，因此可以制备出具有非常良好操作寿命的OLED器件。

  公开号：

  US20110054229A1

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE AND AMINE COMPOUND FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20220059771A1

  公开（公告）日：2022-02-24

  An organic electroluminescence device includes a first electrode and a second electrode which face each other, and a plurality of organic layers between the first electrode and the second electrode, where at least one of the organic layers includes an amine compound represented by Formula 1, and the organic electroluminescence device may exhibit improved luminous efficiency:

  一种有机电致发光器件包括彼此面对的第一电极和第二电极，以及位于第一电极和第二电极之间的多个有机层，其中至少一个有机层包括由化学式1表示的胺化合物，该有机电致发光器件可能表现出改善的发光效率。
• EP1623970
  申请人：——

  公开号：——

  公开（公告）日：——
• EP1623968
  申请人：——

  公开号：——

  公开（公告）日：——
• Arylamine compound and organic electroluminescence device containing the same
  申请人：Kawamura Hisayuki

  公开号：US20070018569A1

  公开（公告）日：2007-01-25

  Provided are a novel arylamine compound of a specific structure having at least one spiro bond; an organic EL device in which an organic compound layer comprising one layer or plural layers including at least a luminescent layer is interposed between a cathode and an anode, wherein at least one of the above organic compound layers contains the arylamine derivative described above; an organic EL device in which an organic compound layer comprising one layer or plural layers including at least a luminescent layer is interposed between a cathode and an anode, wherein at least one of the above organic compound layers contains the arylamine derivative described above and a luminescent material; and an organic EL device in which an organic compound layer comprising one layer or plural layers including at least a luminescent layer is interposed between a cathode and an anode, wherein the above organic compound layer is prepared by laminating a hole transporting layer containing the arylamine derivative described above and a luminescent layer comprising a phosphorescence-emitting metal complex and a host material. Provided are an organic EL device which has a high luminance, a high heat resistance and a long life and which is excellent in a hole transporting property and has a high luminous efficiency and a novel arylamine compound which realizes the same.
• Compound having spiro bond, material for luminescent coating formation and organic electroluminescence element including the same
  申请人：Inoue Tetsuya

  公开号：US20070042220A1

  公开（公告）日：2007-02-22

  A novel compound having a spiro bond with a specific structure, a material for forming a luminous coated film comprising the compound having the spiro bond with the specific structure, and an organic electroluminescence device which comprises at least one organic thin film layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises the compound having the spiro bond. The organic EL device employing either the compound having a spiro bond or the material for forming luminous coated film in accordance with the present invention is superior in heat resistance, has stability of the thin film composing the device, emits uniform blue light, and exhibits an excellent luminance, current efficiency even under a low driving voltage.