methyl N-[4-[(4-isocyanatophenyl)methyl]phenyl]carbamate | 37144-79-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl N-[4-[(4-isocyanatophenyl)methyl]phenyl]carbamate
• CAS: 37144-79-9
• 化学式: C₁₆H₁₄N₂O₃
• 分子量: 282.299
• InChiKey: SFPSKVGYOGOTEX-UHFFFAOYSA-N

物化性质

• 沸点：
  382.1±35.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  67.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N'-(亚甲基二-4,1-亚苯基)二-氨基甲酸 C,C'-二甲基酯 在 montmorillonite K-10 作用下， 以 萘烷 为溶剂， 反应 5.0h， 生成 methyl N-[4-[(4-isocyanatophenyl)methyl]phenyl]carbamate 、 4,4'-二苯甲烷二异氰酸酯、2,4'-二苯甲烷二异氰酸酯和2,2'-二苯甲烷二异氰酸酯的混合物
  参考文献：
  名称：

  A new and efficient catalytic method for synthesizing isocyanates from carbamates

  摘要：

  Operationally simple, recyclable and environmentally friendly montmorillonite efficiently catalyses dealcoholysis of a wide range of mono- and dicarbamates to isocyanates. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)00094-1

文献信息

• Superelastic polyurethane mastics
  申请人：BOSTIK SA

  公开号：US10875954B2

  公开（公告）日：2020-12-29

  The invention relates to a method for synthesizing NCO-terminated polyurethanes having improved elastic properties, said method involving the staggered addition of diisocyanate(s). The invention also relates to NCO-terminated polyurethanes that have high elongation at break and can be obtained using the disclosed method. The invention finally relates to adhesive, mastic and/or coating compositions comprising the disclosed NCO-terminated polyurethane.

  本发明涉及一种合成具有更好弹性性能的 NCO 端聚氨酯的方法，所述方法涉及交错添加二异氰酸酯。本发明还涉及一种 NCO 端聚氨酯，该聚氨酯具有较高的断裂伸长率，可通过所公开的方法获得。最后，本发明还涉及包含所公开的 NCO 端聚氨酯的粘合剂、胶泥和/或涂料组合物。
• Carbon Black Pigment for Electronic Paper, Dispersion of the Pigment, and Process for Production of the Pigment
  申请人：Kirino Tomoaki

  公开号：US20090286923A1

  公开（公告）日：2009-11-19

  A surface-modified carbon black pigment suitable as electronic paper black particles, a silicone oil dispersion of the carbon black pigment, and a process for producing the carbon black pigment are disclosed. The carbon black pigment includes surface-modified carbon black, a diphenylmethane group that is bonded to the carbon black via a urethane bond through a functional group on the surface of the carbon black being bonded to a polysiloxane group. The carbon black dispersion includes a silicone oil and the carbon black pigment, the carbon black pigment being dispersed in the silicone oil at a concentration of 1 to 20 wt %. The process for producing a carbon black pigment for electronic paper includes reacting a functional group on the surface of carbon black with a diphenyl compound having isocyanate groups on both ends in a non-reactive organic solvent so that a diphenylmethane group is bonded to the surface of the carbon black via a urethane bond, and causing the diphenylmethane group to be bonded to a polysiloxane in a silicone oil.
• SUPERELASTIC POLYURETHANE MASTICS
  申请人：BOSTIK SA

  公开号：US20190002621A1

  公开（公告）日：2019-01-03

  The invention relates to a method for synthesizing NCO-terminated polyurethanes having improved elastic properties, said method involving the staggered addition of diisocyanate(s). The invention also relates to NCO-terminated polyurethanes that have high elongation at break and can be obtained using the disclosed method. The invention finally relates to adhesive, mastic and/or coating compositions comprising the disclosed NCO-terminated polyurethane.
• US7855249B2
  申请人：——

  公开号：US7855249B2

  公开（公告）日：2010-12-21
• [EN] SUPERELASTIC POLYURETHANE MASTICS<br/>[FR] MASTICS POLYURETHANE SUPERELASTIQUES
  申请人：BOSTIK SA

  公开号：WO2017109383A1

  公开（公告）日：2017-06-29

  La présente invention concerne un procédé de fabrication de polyuréthanes à terminaisons NCO présentant des propriétés élastiques améliorées, ledit procédé comprenant un ajout séquencé de diisocyanate(s). La présente invention concerne également des polyuréthanes à terminaisons NCO présentant un allongement à la rupture élevé, susceptibles d'être obtenus par le procédé selon l'invention. L'invention concerne enfin des compositions adhésives, de mastic et/ou de revêtement de surface comprenant le polyuréthane à terminaisons NCO selon l'invention.