N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-N,N'-diphenylpyrene-1,6-diamine | 1292285-13-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-N,N'-diphenylpyrene-1,6-diamine
• 英文别名: 1-N,6-N-diphenyl-1-N,6-N-bis[3-(9-phenylfluoren-9-yl)phenyl]pyrene-1,6-diamine
• CAS: 1292285-13-2
• 化学式: C₇₈H₅₂N₂
• 分子量: 1017.28
• InChiKey: QMUWZPAIRQVILN-UHFFFAOYSA-N

物化性质

• 密度：
  1.278±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  21
• 重原子数：
  80
• 可旋转键数：
  10
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-(3-溴苯基)-9-苯基-9H-芴 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 三叔丁基膦 、 sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 5.0h， 生成 N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-N,N'-diphenylpyrene-1,6-diamine
  参考文献：
  名称：

  Fluorene Derivative, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device

  摘要：

  公开号：

  EP2314565B1

文献信息

• Organic Compound, Light-Emitting Element, Display Module, Lighting Module, Light-Emitting Device, Display Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20150243892A1

  公开（公告）日：2015-08-27

  A light-emitting element with high emission efficiency. The light-emitting element includes a pair of electrodes and an EL layer between the pair of electrodes. In the light-emitting element, the EL layer contains at least a light-emitting material, the light-emitting material is a 1,6-bis(diphenylamino)pyrene derivative, and a structural change between an excited state and a ground state in the 1,6-bis(diphenylamino)pyrene derivative is smaller than that in a 1,6-bis(diphenylamino)pyrene derivative in which hydrogen is bonded to ortho positions of two phenyl groups of each of two diphenylamino groups.

  一个发光效率高的发光元件。该发光元件包括一对电极和一对电极之间的EL层。在发光元件中，EL层包含至少一种发光材料，发光材料为1,6-双(二苯基氨基)芘衍生物，且1,6-双(二苯基氨基)芘衍生物在激发态和基态之间的结构变化小于在每个二苯基氨基组的两个苯基的邻位上连接氢的1,6-双(二苯基氨基)芘衍生物。
• FLUORENE DERIVATIVE, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：Ogita Kaori

  公开号：US20110095678A1

  公开（公告）日：2011-04-28

  An object is to provide a new fluorene derivative as a good light-emitting material for organic EL elements. A fluorene derivative represented by General Formula (G1) is provided. In the formula, R 1 to R 8 separately represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α 1 to α 4 separately represent a substituted or unsubstituted phenylene group. Ar 1 represents a substituted or unsubstituted condensed aromatic hydrocarbon having 14 to 18 carbon atoms forming a ring. Ar 2 represents a substituted or unsubstituted aryl group having 6 to 13 carbon atoms forming a ring. Ar 3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. Further, j, m, and n separately represent 0 or 1, and p represents 1 or 2.

  提供一种新的萘衍生物作为有机EL元件的良好发光材料的目的。提供了一种由通用式（G1）表示的萘衍生物。在该式中，R1至R8分别表示氢原子、具有1至6个碳原子的烷基基团、取代或未取代的苯基团，或取代或未取代的联苯基团。此外，α1至α4分别表示取代或未取代的苯基亚基团。Ar1表示具有14至18个碳原子形成环的取代或未取代的紧凑芳香烃。Ar2表示具有6至13个碳原子形成环的取代或未取代的芳基基团。Ar3表示具有1至6个碳原子的烷基基团或具有6至12个碳原子的取代或未取代的芳基基团。此外，j、m和n分别表示0或1，p表示1或2。
• Light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10270051B2

  公开（公告）日：2019-04-23

  A light-emitting element is provided. The light-emitting element includes first and second electrodes and an EL layer therebetween. The EL layer includes a light-emitting layer containing first and second substances. The amount of the first substance is larger than that of the second substance. The second substance emits light. Average transition dipole moments of the second substance are divided into three components in x-, y-, and z-directions which are orthogonal to each other. Components parallel to the first or second electrode are assumed to be the components in the x- and y-directions, and a component perpendicular to the first or second electrode is assumed to be the component in the z-direction. The proportion of the component in the z-direction is represented by a, which is less than or equal to 0.2.

  提供一种发光元件。该发光元件包括第一和第二电极以及其间的 EL 层。EL 层包括含有第一和第二种物质的发光层。第一种物质的含量大于第二种物质的含量。第二种物质发光。第二种物质的平均过渡偶极矩在 x、y 和 z 方向上被分为三个分量，它们相互正交。与第一或第二电极平行的分量被假定为 x 和 y 方向上的分量，与第一或第二电极垂直的分量被假定为 z 方向上的分量。z 方向的分量比例用 a 表示，a 小于或等于 0.2。
• Manufacturing method of light-emitting element
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10608181B2

  公开（公告）日：2020-03-31

  A method for manufacturing a light-emitting element, in particular, a method for manufacturing a light-emitting element with high emission efficiency is provided. In the method for manufacturing a light-emitting element that includes a light-emitting layer containing a host material and a light-emitting material that is an organic compound or an organic metal complex, the light-emitting layer is formed by co-evaporation of the light-emitting material and the host material, and the light-emitting layer is deposited by co-evaporation while the percentage of the partial pressure of carbon dioxide with respect to the total pressure in an evaporation chamber for the co-evaporation is kept higher than that in the air.

  本发明提供了一种制造发光元件的方法，特别是一种制造高发射效率发光元件的方法。在该发光元件制造方法中，发光层包含主材料和发光材料（有机化合物或有机金属络合物），发光层是通过发光材料和主材料的共蒸发形成的，并且发光层是通过共蒸发沉积的，同时用于共蒸发的蒸发室中二氧化碳分压占总压的百分比保持高于空气中的百分比。
• Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20170338435A1

  公开（公告）日：2017-11-23

  A light-emitting element is provided. The light-emitting element includes first and second electrodes and an EL layer therebetween. The EL layer includes a light-emitting layer containing first and second substances. The amount of the first substance is larger than that of the second substance. The second substance emits light. Average transition dipole moments of the second substance are divided into three components in x-, y-, and z-directions which are orthogonal to each other. Components parallel to the first or second electrode are assumed to be the components in the x- and y-directions, and a component perpendicular to the first or second electrode is assumed to be the component in the z-direction. The proportion of the component in the z-direction is represented by a, which is less than or equal to 0.2.