1,2,5-Trimethyl-2,3-diphenyl-1,3,5,2-triazasilepane-4-thione | 138767-59-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2,5-Trimethyl-2,3-diphenyl-1,3,5,2-triazasilepane-4-thione
• CAS: 138767-59-6
• 化学式: C₁₈H₂₃N₃SSi
• 分子量: 341.552
• InChiKey: AOWHUPCLZLUXCM-UHFFFAOYSA-N

物化性质

• 沸点：
  412.1±28.0 °C(Predicted)
• 密度：
  1.17±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.63
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  41.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2,5-Trimethyl-2,3-diphenyl-1,3,5,2-triazasilepane-4-thione 反应 2.0h， 以30%的产率得到1,3-dimethyl-2-phenylimino-1,3-diazolidine
  参考文献：
  名称：

  Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts

  摘要：

  Heteroorganic amidosilanes are readily obtained by interaction of CO2, CS2 and other heterocumulenes with pentacoordinated diaminosilanes. A comparison is made with the corresponding reactions of tetracoordinated species. Decomposition of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal beta-elimination.

  DOI：

  10.1016/0022-328x(91)86160-r
• 作为产物：
  描述：

  甲基苯基二氯硅烷 以 四氢呋喃 、 乙醚 、 氘代氯仿 为溶剂， 反应 26.0h， 生成 1,2,5-Trimethyl-2,3-diphenyl-1,3,5,2-triazasilepane-4-thione
  参考文献：
  名称：

  Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts

  摘要：

  Heteroorganic amidosilanes are readily obtained by interaction of CO2, CS2 and other heterocumulenes with pentacoordinated diaminosilanes. A comparison is made with the corresponding reactions of tetracoordinated species. Decomposition of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal beta-elimination.

  DOI：

  10.1016/0022-328x(91)86160-r

文献信息

• Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts
  作者：R.J.P. Corriu、Gérard F. Lanneau、V.D. Mehta

  DOI：10.1016/0022-328x(91)86160-r

  日期：1991.11

  Heteroorganic amidosilanes are readily obtained by interaction of CO2, CS2 and other heterocumulenes with pentacoordinated diaminosilanes. A comparison is made with the corresponding reactions of tetracoordinated species. Decomposition of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal beta-elimination.