3,6-bis(dibenzothiophen-4-yl)-9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole | 1365891-53-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 3,6-bis(dibenzothiophen-4-yl)-9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole
• 英文别名: 3,6-Di(dibenzothiophen-4-yl)-9-[4-(10-phenylanthracen-9-yl)phenyl]carbazole；3,6-di(dibenzothiophen-4-yl)-9-[4-(10-phenylanthracen-9-yl)phenyl]carbazole
• CAS: 1365891-53-7
• 化学式: C₆₂H₃₇NS₂
• 分子量: 860.114
• InChiKey: XICJGGNIWMMEDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.7
• 重原子数：
  65
• 可旋转键数：
  5
• 环数：
  14.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-(4-溴苯基)-10-苯基蒽 、 3,6-di(benzothiophen-4-yl)-9H-carbazole 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 10.0h， 以38%的产率得到3,6-bis(dibenzothiophen-4-yl)-9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole
  参考文献：
  名称：

  Carbazole Derivative, Light-Emitting Element Material and Organic Semiconductor Material

  摘要：

  提供一种新型的咔唑衍生物，具有出色的载体传输性能，并可适当用作传输层或作为发光元件的主体材料。另一个目标是提供一种有机半导体材料和一种使用该咔唑衍生物的发光元件材料。作为能够实现上述目标的咔唑衍生物，已经成功合成了一种咔唑衍生物，其中咔唑的2-或3-位置之一被二苯并噻吩骨架或二苯并呋喃骨架的4-位置取代的咔唑基团与具有14至70个碳原子的芳香烃结合，并包括一个紧凑的三环、四环、五环、六环或七环。

  公开号：

  US20120071668A1

文献信息

• Carbazole derivative, light-emitting element material and organic semiconductor material
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10071993B2

  公开（公告）日：2018-09-11

  An object is to provide a novel carbazole derivative that has an excellent carrier-transport property and can be suitably used for a transport layer or as a host material of a light-emitting element. Another object is to provide an organic semiconductor material and a light-emitting element material each using the carbazole derivative. As the carbazole derivative that can achieve the above objects, a carbazole derivative in which a carbazolyl group whose either 2- or 3-position of carbazole is substituted by the 4-position of a dibenzothiophene skeleton or a dibenzofuran skeleton is bonded to aromatic hydrocarbon that has 14 to 70 carbon atoms and includes a condensed tricyclic ring, a condensed tetracyclic ring, a condensed pentacyclic ring, a condensed hexacyclic ring, or a condensed heptacyclic ring has been able to be synthesized.

  一个目的是提供一种新型咔唑衍生物，它具有优异的载流子传输特性，可适当用于传输层或作为发光元件的主材料。另一个目的是提供一种使用该咔唑衍生物的有机半导体材料和发光元件材料。作为可实现上述目的的咔唑衍生物，一种咔唑衍生物，其中咔唑的 2 位或 3 位被二苯并噻吩骨架或二苯并呋喃骨架的 4 位取代的咔唑基与具有 14 至 70 个碳原子并包括缩合三环的芳香烃键合、已能合成缩合四环、缩合五环、缩合六环或缩合七环。
• US8642782B2
  申请人：——

  公开号：US8642782B2

  公开（公告）日：2014-02-04
• US9450188B2
  申请人：——

  公开号：US9450188B2

  公开（公告）日：2016-09-20
• [EN] CARBAZOLE DERIVATIVE, LIGHT-EMITTING ELEMENT MATERIAL AND ORGANIC SEMICONDUCTOR MATERIAL<br/>[FR] DÉRIVÉ DE CARBAZOLE, MATÉRIAU POUR ÉLÉMENT ÉLECTROLUMINESCENT ET MATÉRIAU SEMI-CONDUCTEUR ORGANIQUE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2012039262A1

  公开（公告）日：2012-03-29

  An object is to provide a novel carbazole derivative that has an excellent carrier-transport property and can be suitably used for a transport layer or as a host material of a light-emitting element. Another object is to provide an organic semiconductor material and a light-emitting element material each using the carbazole derivative. As the carbazole derivative that can achieve the above objects, a carbazole derivative in which a carbazolyl group whose either 2- or 3-position of carbazole is substituted by the 4-position of a dibenzothiophene skeleton or a dibenzofuran skeleton is bonded to aromatic hydrocarbon that has 14 to 70 carbon atoms and includes a condensed tricyclic ring, a condensed tetracyclic ring, a condensed pentacyclic ring, a condensed hexacyclic ring, or a condensed heptacyclic ring has been able to be synthesized.
• Carbazole Derivative, Light-Emitting Element Material and Organic Semiconductor Material
  申请人：Suzuki Hiroki

  公开号：US20120071668A1

  公开（公告）日：2012-03-22

  An object is to provide a novel carbazole derivative that has an excellent carrier-transport property and can be suitably used for a transport layer or as a host material of a light-emitting element. Another object is to provide an organic semiconductor material and a light-emitting element material each using the carbazole derivative. As the carbazole derivative that can achieve the above objects, a carbazole derivative in which a carbazolyl group whose either 2- or 3-position of carbazole is substituted by the 4-position of a dibenzothiophene skeleton or a dibenzofuran skeleton is bonded to aromatic hydrocarbon that has 14 to 70 carbon atoms and includes a condensed tricyclic ring, a condensed tetracyclic ring, a condensed pentacyclic ring, a condensed hexacyclic ring, or a condensed heptacyclic ring has been able to be synthesized.

  提供一种新型的咔唑衍生物，具有出色的载体传输性能，并可适当用作传输层或作为发光元件的主体材料。另一个目标是提供一种有机半导体材料和一种使用该咔唑衍生物的发光元件材料。作为能够实现上述目标的咔唑衍生物，已经成功合成了一种咔唑衍生物，其中咔唑的2-或3-位置之一被二苯并噻吩骨架或二苯并呋喃骨架的4-位置取代的咔唑基团与具有14至70个碳原子的芳香烃结合，并包括一个紧凑的三环、四环、五环、六环或七环。