N-(3,4-dimethylphenyl)-3,4-dimethylbenzamide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(3,4-dimethylphenyl)-3,4-dimethylbenzamide
• 化学式: C₁₇H₁₉NO
• 分子量: 253.344
• InChiKey: DWPKJOVSHMCNDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3,4-二甲基碘苯 、 草酸 在 sodium azide 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以51%的产率得到N-(3,4-dimethylphenyl)-3,4-dimethylbenzamide
  参考文献：
  名称：

  用于 N-芳基苯甲酰胺合成的负载型 Pd 催化串联方法

  摘要：

  芳基碘作为草酸 [(CO 2 H) 2 ] 的 C 端和叠氮化钠 (NaN 3 ) 的 N端双芳基化剂，用于 N-芳基苯甲酰胺 (Ar-CO-NH-Ar) 合成是一种罕见的在这项研究中已成功尝试的发明。通过使用原位CO 从 (CO 2 H) 2和 NaN 3对芳基碘进行双功能转化，开发了一种用于合成 N-芳基苯甲酰胺的单步串联方法遵循羰基化和叠氮化两种不同的途径。发现聚苯乙烯负载的钯 (Pd@PS) 催化剂非常适合在双层小瓶 (DLV) 系统中在碱、配体和无添加剂条件下进行多米诺反应。此外，使用芳基叠氮化物进一步扩展了相同的方法，用于不对称 N-芳基苯甲酰胺 (Ar-CO-NH-Ar') 合成。此外，还进行了 DFT 研究以支持所提出的机制。

  DOI：

  10.1016/j.mcat.2021.111948

文献信息

• HOLLOW FIBER, DOPE COMPOSITION FOR FORMING HOLLOW FIBER, AND METHOD OF PREPARING HOLLOW FIBER USING THE SAME
  申请人：JUNG Chul-Ho

  公开号：US20090282982A1

  公开（公告）日：2009-11-19

  Disclosed is a hollow fiber that includes a hollow positioned at the center of the hollow fiber, macropores positioned at adjacent to the hollow, and mesopores and picopores positioned at adjacent to macropores, and the picopores are three dimensionally connected to each other to form a three dimensional network structure. The hollow fiber includes a polymer derived from polyamic acid, and the polyamic acid includes a repeating unit obtained from aromatic diamine including at least one ortho-positioned functional group with respect to an amine group and dianhydride.
• POLYIMIDES DOPE COMPOSITION, PREPARATION METHOD OF HOLLOW FIBER USING THE SAME AND HOLLOW FIBER PREPARED THEREFROM
  申请人：LEE Young-Moo

  公开号：US20090286078A1

  公开（公告）日：2009-11-19

  Disclosed herein are a polyimide dope solution composition, a method for preparing a hollow fiber using the composition and a hollow fiber prepared by the method. More specifically, disclosed are a method for preparing a hollow fiber, comprising preparing a polyimide dope solution composition comprising polyhydroxyimide, polythiolimide or polyaminoimide, spinning the composition to prepare a hollow fiber, and thermally rearranging the hollow fiber, and the hollow fiber prepared by the method. In accordance with the method, a hollow fiber made of a high free volume polymer membrane can be prepared by spinning the dope solution composition to prepare a hollow fiber and thermally rearranging the hollow fiber via thermal treatment. The hollow fiber thus prepared exhibits excellent gas permeability and selectivity, thus being suitable for use as a gas separation membrane.
• POLYAMIC ACIDS DOPE COMPOSITION, PREPARATION METHOD OF HOLLOW FIBER USING THE SAME AND HOLLOW FIBER PREPARED THEREFROM
  申请人：LEE Young-Moo

  公开号：US20090286904A1

  公开（公告）日：2009-11-19

  Disclosed herein are a polyamic acid dope solution composition, a method for preparing a hollow fiber using the composition and a hollow fiber prepared by the method. More specifically, disclosed are a method for preparing a hollow fiber, comprising preparing a polyamic acid dope solution composition comprising polyhydroxyamic acid, polythiolamic acid or polyaminoamic acid, spinning the composition to prepare a hollow fiber, and imidizing and thermally rearranging the hollow fiber, and the hollow fiber prepared by the method. In accordance with the method, a hollow fiber made of a high free volume polymer membrane can be prepared by spinning the dope solution composition to prepare a hollow fiber and thermally rearranging the hollow fiber via thermal treatment. The hollow fiber thus prepared exhibits excellent gas permeability and selectivity, thus being suitable for use as a gas separation membrane.
• HOLLOW FIBER, DOPE COMPOSITION FOR FORMING HOLLOW FIBER, AND METHOD OF MAKING HOLLOW FIBER USING THE SAME
  申请人：Jung Chul-Ho

  公开号：US20090297850A1

  公开（公告）日：2009-12-03

  Disclosed is a hollow fiber that includes a hollow positioned at the center of the hollow fiber, macropores positioned at adjacent to the hollow, and mesopores and picopores positioned at adjacent to macropores, and the picopores are three dimensionally connected to each other to form a three dimensional network structure. The hollow fiber includes a polymer derived from polyimide, and the polyimide includes a repeating unit obtained from aromatic diamine including at least one ortho-positioned functional group with respect to an amine group and dianhydride.
• POLYMER COMPOUNDS AND A PREPARATION METHOD THEREOF
  申请人：LEE Young-Moo

  公开号：US20100099804A1

  公开（公告）日：2010-04-22

  Disclosed herein are polymer compounds, a method for preparing thereof. More specifically, provided are polymer compounds with well-connected, narrow size distribution free-volume element and a method for preparing the polymer compounds by thermal rearrangement for aromatic polyimides containing ortho-positioned functional groups in the solid state.