5-[[(3R,3aR,6R,6aR)-6-(4-carboxybutanoyloxy)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl]oxy]-5-oxopentanoic acid | 1597769-11-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 5-[[(3R,3aR,6R,6aR)-6-(4-carboxybutanoyloxy)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl]oxy]-5-oxopentanoic acid
• CAS: 1597769-11-3
• 化学式: C₁₆H₂₂O₁₀
• 分子量: 374.345
• InChiKey: YRUYSENGZPQPTO-DJUAPZDMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  26
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  146
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  戊二酸酐 、 1,4:3,6-dianhydro-D-mannitol 以 neat (no solvent) 为溶剂， 反应 24.0h， 以91%的产率得到5-[[(3R,3aR,6R,6aR)-6-(4-carboxybutanoyloxy)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl]oxy]-5-oxopentanoic acid
  参考文献：
  名称：

  [EN] TACKIFIER COMPOUNDS AND METHODS OF USING THE SAME
  [FR] COMPOSÉS POISSEUX ET PROCÉDÉS D'UTILISATION DE CEUX-CI

  摘要：

  本发明涉及粘合剂化合物及其使用方法。在各种实施例中，本发明提供一种粘合剂化合物，包括独立取代或未取代的融合环A和B，每个环独立选择自（C5-C10）环烷基和（C2-C10）杂环基。融合环A被（R1）1-8取代，融合环B被-(OC(O)R'C(O)R2)1-8取代。每次出现时，R'独立选择自（C2-C10）烷基，（C2-C10）烯基，（C2-C10）炔基，C5-C20（芳基）和（C1-C20）杂芳基，其中R'未取代或取代。每次出现时，R1独立选择自-OH，-OR3和-OC（O）R'C（O）R2。每次出现时，R2独立选择自-OH，-OR3，-NH2，-NHR3和-NR32。每次出现时，R3独立选择自（C1-C10）烷基，（C2-C10）烯基，（C2-C10）炔基，C5-C20（芳基）和（C1-C20）杂芳基，其中R3未取代或取代。

  公开号：

  WO2014062625A1

文献信息

• AZIRIDINATED TRIGLYCERIDES AND POLYMERS FORMED THEREFROM
  申请人：Iowa State University Research Foundation, Inc.

  公开号：US20160289218A1

  公开（公告）日：2016-10-06

  Various embodiments disclosed relate to aziridinated triglycerides and polymers formed therefrom. In various embodiments, the present invention provides an aziridinated triglyceride having the structure described herein. In various embodiments, the present invention provides a method of making the aziridinated triglyceride, a method of crosslinking the aziridinated triglyceride to form a polymer, the polymer formed from the aziridinated triglyceride, a triglyceride with at least one pendent unsaturated group that can be used to form the aziridinated triglyceride, and a method of making the triglyceride having at least one pendent unsaturated group.

  各种实施方式涉及到环氧化三酸甘油和由此形成的聚合物。在各种实施方式中，本发明提供了一种具有此处描述的结构的环氧化三酸甘油。在各种实施方式中，本发明提供了一种制备环氧化三酸甘油的方法，一种交联环氧化三酸甘油以形成聚合物的方法，由环氧化三酸甘油形成的聚合物，一种具有至少一个可用于形成环氧化三酸甘油的侧链不饱和基团的三酸甘油，以及一种制备具有至少一个侧链不饱和基团的三酸甘油的方法。
• Tackifier compounds and methods of using the same
  申请人：Iowa State University Research Foundation, Inc.

  公开号：US10280241B2

  公开（公告）日：2019-05-07

  The present invention relates to tackifier compounds and methods of using the same. In various embodiments, the present invention provides a tackifier compound including independently substituted or unsubstituted fused rings A and B each independently chosen from (C5-C10)cycloalkyl and (C2-C10)heterocyclyl. Fused ring A is substituted with (R1)1-8 and fused ring B is substituted with —(OC(O)R′C(O)R2)1-8. At each occurrence R′ is independently chosen from (C2-C10)alkanylene, (C2-C10)alkenylene, (C2-C10)alkynylene, C5-C20(arylene), and (C1-C20)heteroarylene, wherein R′ is unsubstituted or substituted. At each occurrence R1 is independently selected from —OH, —OR3, and —OC(O)R′C(O)R2. At each occurrence R2 is independently chosen from —OH, —OR3, —NH2, —NHR3, and —NR32. At each occurrence R3 is independently chosen from (C1-C10)alkanyl, (C2-C10)alkenyl, (C2-C10)alkynyl, C5-C20(aryl), and (C1-C20)heteroaryl, wherein R3 is unsubstituted or substituted.

  本发明涉及增粘剂化合物及其使用方法。在各种实施方案中，本发明提供了一种增粘剂化合物，包括各自独立地选自(C5-C10)环烷基和(C2-C10)杂环基的取代或未取代的熔合环 A 和 B。融合环 A 被 (R1)1-8 取代，融合环 B 被-(OC(O)R′C(O)R2)1-8 取代。在每次出现时，R′独立地选自(C2-C10)烷烃、(C2-C10)烯烃、(C2-C10)炔烃、C5-C20(芳基)和(C1-C20)杂芳基，其中 R′未被取代或被取代。在每次出现时，R1 独立选自-OH、-OR3 和-OC(O)R′C(O)R2。在每次出现时，R2 独立选自-OH、-OR3、-NH2、-NHR3 和-NR32。在每次出现时，R3 独立选自(C1-C10)烷基、(C2-C10)烯基、(C2-C10)炔基、C5-C20（芳基）和(C1-C20)杂芳基，其中 R3 是未取代的或取代的。
• Polymers and methods of making the same
  申请人：Iowa State University Research Foundation, Inc.

  公开号：US10392471B2

  公开（公告）日：2019-08-27

  Various embodiments disclosed relate to polymers and methods of making the same. In various embodiments, the present invention provides a method of forming a polymer including subjecting a composition including a carboxylic acid having the structure (Rf—O)z1—Ra to conditions sufficient to form a polymer having the structure Reg—[O—Ra(O—Rb)z1-2—O—C(O)—R′(O—Rd)z2-1—C(O)]n—O—Ra(O—Rb)z1-2—O—Reg or a salt or ester thereof, wherein Ra, R′ Rb, Rd, Rf, Reg, z1, z2, and n are as defined herein. In various embodiments, the polymer is a tackifier, a viscosifier, or a combination thereof.

  本发明公开的各种实施方案涉及聚合物及其制造方法。在各种实施方案中，本发明提供了一种形成聚合物的方法，包括将包括具有结构 (Rf-O)z1-Ra 的羧酸的组合物置于足以形成具有结构 Reg-[O-Ra(O-Rb)z1-2-O-C(O)-R′(O-Rd)z2-1-C(O)]n-O-Ra(O-Rb)z1-2-O-Reg 的聚合物或其盐或酯的条件下、其中 Ra、R′ Rb、Rd、Rf、Reg、z1、z2 和 n 如本文所定义。在不同的实施方案中，聚合物是增粘剂、增粘剂或它们的组合。
• Aziridinated triglycerides and polymers formed therefrom
  申请人：Iowa State University Research Foundation, Inc.

  公开号：US10501448B2

  公开（公告）日：2019-12-10

  Various embodiments disclosed relate to aziridinated triglycerides and polymers formed therefrom. In various embodiments, the present invention provides an aziridinated triglyceride having the structure described herein. In various embodiments, the present invention provides a method of making the aziridinated triglyceride, a method of crosslinking the aziridinated triglyceride to form a polymer, the polymer formed from the aziridinated triglyceride, a triglyceride with at least one pendent unsaturated group that can be used to form the aziridinated triglyceride, and a method of making the triglyceride having at least one pendent unsaturated group.

  本发明的各种实施方案涉及氮丙啶化甘油三酯及其聚合物。在各种实施方案中，本发明提供了一种具有本文所述结构的氮丙啶化甘油三酯。在不同的实施方案中，本发明提供了一种制造氮丙啶化甘油三酯的方法、一种交联氮丙啶化甘油三酯以形成聚合物的方法、由氮丙啶化甘油三酯形成的聚合物、一种具有至少一个可用于形成氮丙啶化甘油三酯的下垂不饱和基团的甘油三酯，以及一种制造具有至少一个下垂不饱和基团的甘油三酯的方法。
• TACKIFIER COMPOUNDS AND METHODS OF USING THE SAME
  申请人：Iowa State University Research Foundation, Inc.

  公开号：US20150274861A1

  公开（公告）日：2015-10-01

  The present invention relates to tackifier compounds and methods of using the same. In various embodiments, the present invention provides a tackifier compound including independently substituted or unsubstituted fused rings A and B each independently chosen from (C 5 -C 10 )cycloalkyl and (C 2 -C 10 )heterocyclyl. Fused ring A is substituted with (R 1 ) 1-8 and fused ring B is substituted with —(OC(O)R′C(O)R 2 ) 1-8 . At each occurrence R′ is independently chosen from (C 2 -C 10 )alkanylene, (C 2 -C 10 )alkenylene, (C 2 -C 10 )alkynylene, C 5 -C 20 (arylene), and (C 1 -C 20 )heteroarylene, wherein R′ is unsubstituted or substituted. At each occurrence R 1 is independently selected from —OH, —OR 3 , and —OC(O)R′C(O)R 2 . At each occurrence R 2 is independently chosen from —OH, —OR 3 , —NH 2 , —NHR 3 , and —NR 3 2 . At each occurrence R 3 is independently chosen from (C 1 -C 10 )alkanyl, (C 2 -C 10 )alkenyl, (C 2 -C 10 )alkynyl, C 5 -C 20 (aryl), and (C 1 -C 20 )heteroaryl, wherein R 3 is unsubstituted or substituted.