Methyl-N-triethylcarbinyl-carbamat | 14442-76-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Methyl-N-triethylcarbinyl-carbamat
• 英文别名: methyl N-(3-ethylpentan-3-yl)carbamate
• CAS: 14442-76-3
• 化学式: C₉H₁₉NO₂
• 分子量: 173.255
• InChiKey: GPSTXVQRZOGPGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-乙基-3-戊醇 在 sodium hydroxide 作用下， 生成 Methyl-N-triethylcarbinyl-carbamat
  参考文献：
  名称：

  N-Nitroamides and N-Nitrocarbamates. III. Rotational Isomerism, Steric Effects, and Physical Properties at Low Temperatures¹

  摘要：

  DOI：

  10.1021/jo01347a067

文献信息

• Fluorine-containing acetophenone derivative, fluroine based additive, curable composition including same, and cured product thereof
  申请人：DIC Corporation

  公开号：US10961405B2

  公开（公告）日：2021-03-30

  The invention provides a fluorine-containing acetophenone derivative which is useful as an additive that can impart excellent antifouling properties and scratch resistance to the surface of a cured coating and that also offers high transparency of the coating; a fluoroadditive and an active energy ray curable composition which each include the above derivative; a cured product of the composition; and an article having a cured coating of the composition. Specifically, this object is achieved by using a fluorine-containing acetophenone derivative, typically represented by the structural formula below, that is obtained by introducing an acryloyl group into a poly(perfluoroalkylene ether) chain and thereafter introducing, using Michael addition reaction, an α-aminoacetophenone-based structural unit capable of generating radical species by photocleavage

  本发明提供了一种含氟苯乙酮衍生物，该衍生物可用作添加剂，可赋予固化涂层表面优异的防污性能和抗划伤性，还可提供涂层的高透明度；一种氟添加剂和一种活性能量射线固化组合物，其中均包括上述衍生物；一种该组合物的固化产品；以及一种具有该组合物固化涂层的物品。具体地说，这一目标是通过使用含氟苯乙酮衍生物来实现的，该衍生物通常由以下结构式表示，它是通过将丙烯酰基引入聚（全氟烷基醚）链，然后利用迈克尔加成反应引入能够通过光裂解产生自由基的α-氨基苯乙酮结构单元而得到的
• N-Nitroamides and N-Nitrocarbamates. III. Rotational Isomerism, Steric Effects, and Physical Properties at Low Temperatures¹
  作者：Emil H. White、Mark C. Chen、Lester A. Dolak

  DOI：10.1021/jo01347a067

  日期：1966.9