Bis(1,1-diethylpropyl) Phthalate | 111983-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis(1,1-diethylpropyl) Phthalate
• 英文别名: Bis(3-ethylpentan-3-yl) benzene-1,2-dicarboxylate
• CAS: 111983-09-6
• 化学式: C₂₂H₃₄O₄
• 分子量: 362.51
• InChiKey: SEBKNCYVSZUHCC-UHFFFAOYSA-N

物化性质

• 沸点：
  416.3±18.0 °C(Predicted)
• 密度：
  0.997±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  26
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-乙基-3-戊醇 、 邻苯二甲酰氯 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 、 水 为溶剂， 以89%的产率得到Bis(1,1-diethylpropyl) Phthalate
  参考文献：
  名称：

  Sterically hindered aromatic carboxylic esters

  摘要：

  本文描述了一种用于摄影乳剂和元素中的芳香羧酸酯溶剂，例如邻苯二甲酸酯和异苯二甲酸酯，具有臃肿或支链酯基取代基。这些溶剂最好用于青色层，以保护青色染料免受亚铁离子还原的影响。这些溶剂还提供了黄色染料光稳定性、暗处青色染料稳定性和品红色染料热稳定性和光稳定性的改进。

  公开号：

  US04827019A1

文献信息

• Dye-forming coupler and silver halide color photographic light-sensitive material
  申请人：Takeuchi Kiyoshi

  公开号：US20050079456A1

  公开（公告）日：2005-04-14

  A dye-forming coupler and compound of formula (I): wherein Q represents a residue that forms, together with —N—C═N—, a nitrogen-containing 6-membered ring; R A represents an aryl, heterocyclic, or —(R 1 ) r —(R 4 ) m group; X represents an aryl group; Y represents a hydrogen atom, or a group capable of being split-off upon a coupling reaction with an oxidized product of a developing agent: wherein, when R A represents an —(R 1 ) r —(R 4 ) m group, R 1 represents a methylene group, a methine group, or a carbon atom; r is 1 to 30; R 4 represents a substituent except for a hydrogen atom; m is 1 to 30; and the —(R 1 ) r —(R 4 ) m group does not represent a straight-chain alkyl group.

  一种染料形成偶联剂和化合物的公式（I）：其中Q代表与—N—C═N—一起形成含氮6元环的残基；RA代表芳基，杂环或—（R1）r—（R4）m基团；X代表芳基基团；Y代表氢原子或能够在偶联反应中与氧化的显影剂产生分裂的基团：其中，当RA代表—（R1）r—（R4）m基团时，R1代表亚甲基基团，亚胺基团或碳原子；r为1到30；R4代表除氢原子外的取代基；m为1到30；且—（R1）r—（R4）m基团不代表直链烷基。
• Dye-forming coupler, silver halide photographic light-sensitive material, and azomethine dye compound
  申请人：——

  公开号：US20030064332A1

  公开（公告）日：2003-04-03

  A dye-forming coupler of formula (I): 1 wherein Q represents a residue that forms, together with —N—C═N—, a nitrogen-containing 6-membered ring; R A represents an aryl, heterocyclic, or —(R 1 ) r —(R 4 ) m group; X represents an aryl group; Y represents a hydrogen atom, or a group capable of being split-off upon a coupling reaction with an oxidized product of a developing agent: wherein, when R A represents an —(R 1 ) r —(R 4 ) m group, R 1 represents a methylene group, a methine group, or a carbon atom; r is 1 to 30; R 4 represents a substituent except for a hydrogen atom; m is 1 to 30; and the —(R 1 ) r —(R 4 ) m group does not represent a straight-chain alkyl group. A silver halide photographic light-sensitive material which contains at least one of the coupler. An azomethine dye compound derived from the coupler.

  化合物(I)的染料形成偶联剂： 其中，Q代表与—N—C═N—一起形成含氮6元环的残基；RA代表芳基、杂环基或—(R1)r—(R4)m基团；X代表芳基基团；Y代表氢原子或能够在偶联反应中与显影剂氧化产物发生分裂的基团： 当RA代表—(R1)r—(R4)m基团时，R1代表亚甲基、亚胺基或碳原子；r为1到30；R4代表除氢原子外的取代基；m为1到30；而—(R1)r—(R4)m基团不代表直链烷基。 一种含有至少一种该偶联剂的银卤化物感光材料。 由该偶联剂衍生的偶氮甲基染料化合物。
• Silver halide color photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0342637A2

  公开（公告）日：1989-11-23

  A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer containing at least one cyan coupler represented by the following general formula (I) or (II): wherein Za and Zb each represents or -N=; Zc rep­resents -N= or -=; Y represents a hydrogen atom or a blocking group; X represents a hydrogen atom or a group which releases upon a reaction with an oxidation product of an aromatic primary amine color developing agent; R₁ represents a hydrogen atom or a substituent; or R₁ or X may form a polymer including a dimer or more. The silver halide color photographic material containing the novel cyan coupler is excellent in color reproducibility and image preservability.

  一种卤化银彩色感光材料，包括一个支撑体，支撑体上有至少一个卤化银乳剂层，该层含有至少一个由以下通式（I）或（II）表示的青色耦合剂： 其中 Za 和 Zb 分别代表 或-N=； Zc 代表 -N=或-=；Y 代表氢原子或封端基；X 代表氢原子或与芳香族伯胺显色剂的氧化产物反应后释放的基团；R₁ 代表氢原子或取代基；或 R₁ 或 X 可形成包括二聚体或更多的聚合物。 含有新型青色耦合剂的卤化银彩色感光材料在色彩再现性和图像保存性方面都非常出色。
• Silver halide colour photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0447921A2

  公开（公告）日：1991-09-25

  A silver halide color light-sensitive material including a support having thereon at least one hydrophilic colloidal layer is disclosed, wherein the hydrophilic colloidal layer contains a DIR coupler represented by formula (I): wherein R¹ represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; R² represents an organic group; X and Y each represent -N= or wherein R³ represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, an amino group, an acyl group, an acylamino group, a carbamoyl group, a carbamoylamino group, a sulfonyl group, a sulfonylamino group, a sulfamoyl group, a sulfamoylamino group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, a hydroxyl group, a sulfenyl group, a sulfinyl group, an aliphatic group, an aromatic group, or a heterocyclic group; and Z represents a releasable group which is released on reacting with an oxidation product of an aromatic primary amine developing agent to become a development inhibitor or a precursor thereof and which diffuses into a color developing solution and then decomposes to a compound having no substantial influence on photographic properties.

  本发明公开了一种卤化银彩色光敏材料，该材料包括一个支架，支架上至少有一个亲水胶体层，其中亲水胶体层含有由式（I）表示的 DIR 耦合剂： 其中 R¹ 代表氢原子、脂肪族基团、芳香族基团或杂环基团；R² 代表有机基团；X 和 Y 各自代表-N= 或 其中 R³ 代表氢原子、卤素原子、氰基、硝基、氨基、酰基、酰氨基、氨基甲酰基、 氨基酰胺基、磺酰基、磺酰氨基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基、磺酰胺基磺酰胺基、烷氧基、芳氧基、烷氧羰基、芳氧羰基、羟基、亚磺酰基、亚硫酰基、脂肪族基、芳香族基或杂环基；Z 代表可释放基团，该基团与芳香族伯胺显影剂的氧化产物反应后释放，成为显影抑制剂或其前体，并扩散到显色溶液中，然后分解为对感光性能无实质性影响的化合物。
• Silver halide color photographic photosensitive material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：EP0499279A1

  公开（公告）日：1992-08-19

  A compound represented by the following general formula (I) is added to at least one layer of a silver halide photographic photosensitive material, thereby improving sharpness and graininess or decreasing a variation in photographic performance during storage after photography and before development: General Formula (I) where A represents a coupler moiety, each of R¹ and R² independently represents a hydrogen atom or a substituent, each of R³ and R⁴ independently represents a hydrogen atom or an alkyl group, INH represents a group having a development inhibiting function, and R⁵ represents a nonsubstituted phenyl group, a nonsubstituted primary alkyl group, or a primary alkyl group substituted with a group other than an aryl group, at least one of R¹ to R⁴ being a substituent other than a hydrogen atom, and an -OC(=O)- group combining with one of two nitrogen atoms forming a pyrazole ring.

  在卤化银感光材料的至少一层中加入以下通式 (I) 所代表的化合物，可改善清晰度和颗粒感，或减少摄影后和显影前储存期间摄影性能的变化： 通式（I） 其中 A 代表耦合剂分子，R¹ 和 R² 各自独立地代表氢原子或取代基，R³ 和 R⁴ 各自独立地代表氢原子或烷基，INH 代表具有显影抑制功能的基团，R⁵ 代表非取代苯基、非取代的伯烷基，或被芳基以外的基团取代的伯烷基，R¹至 R⁴ 中至少有一个是氢原子以外的取代基，-OC(=O)- 基团与两个氮原子之一结合形成吡唑环。