6-bromo-N-phenyl-N-(6-phenylpyridin-2-yl)pyridine-2-amine | 1418283-64-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6-bromo-N-phenyl-N-(6-phenylpyridin-2-yl)pyridine-2-amine
• 英文别名: 6-bromo-N-phenyl-N-(6-phenylpyridin-2-yl)pyridin-2-amine；N-(6-bromopyridin-2-yl)-N,6-diphenylpyridin-2-amine
• CAS: 1418283-64-3
• 化学式: C₂₂H₁₆BrN₃
• 分子量: 402.293
• InChiKey: VGEHZRUKHFMRON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  29
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  6-bromo-N-phenyl-N-(6-phenylpyridin-2-yl)pyridine-2-amine 在 2-双环己基膦-2',6'-二甲氧基联苯 、 tris-(dibenzylideneacetone)dipalladium(0) 、 potassium phosphate monohydrate 、 溶剂黄146 作用下， 以 水 、 甲苯 为溶剂， 反应 72.0h， 生成
  参考文献：
  名称：

  Tetradentate platinum complexes

  摘要：

  公开号：

  EP2551274B1
• 作为产物：
  描述：

  苯胺 在 1,1'-双(二苯基膦)二茂铁 、 tris-(dibenzylideneacetone)dipalladium(0) 、 四(三苯基膦)钯 、 potassium carbonate 、 sodium t-butanolate 作用下， 生成 6-bromo-N-phenyl-N-(6-phenylpyridin-2-yl)pyridine-2-amine
  参考文献：
  名称：

  ジベンゾ［１，４］アザボリニン構造を含むリン光発光体

  摘要：

  要解决的问题：提供一种包含二苯并[1,4]氮硼烷的化合物，用作有机发光器件中的发射体。解决方案：提供一种包含二苯并[1,4]氮硼烷的化合物，其中配体由图中的化合物1-11和1-12表示，其中配体与铱或铂等中心金属配位，包括二苯并[1,4]氮硼烷结构，而氮和硼不与金属配位。选定的图纸：图4

  公开号：

  JP2017226667A

文献信息

• TETRADENTATE PLATINUM COMPLEXES
  申请人：Kottas Gregg

  公开号：US20130082245A1

  公开（公告）日：2013-04-04

  Novel phosphorescent tetradentate platinum compounds of Formula I are provided. The complexes contain a dibenzo moiety, which allows for the creation of OLED devices with improved properties when compounds of Formula I are incorporated into such devices. Compounds of Formula I′ that comprise two ligands that contain a 5-membered carbocyclic or heterocyclic ring, one of which contains an imidazole ring with a twisted aryl group attached to N−1 and a second aromatic ring that is attached to the platinum via a carbon atom. These compounds may be advantageously used in OLEDs.

  提供了公式I的新型荧光四齿配位铂化合物。这些配合物包含一个二苯并基团，当I式化合物被纳入OLED器件中时，可以改善器件性能。I'式化合物包括两个配体，其中一个包含一个扭曲芳基团连接到N-1的咪唑环，另一个芳香环通过碳原子连接到铂上，并含有一个5元环碳环或杂环。这些化合物可以优势地用于OLED器件中。
• PHOSPHORESCENT EMITTERS CONTAINING DIBENZO[1,4]AZABORININE STRUCTURE
  申请人：UNIVERSAL DISPLAY CORPORATION

  公开号：US20140014922A1

  公开（公告）日：2014-01-16

  A dibenzo[1,4]azaborine comprising compound, and devices and formulations including the same are described. The compound includes a ligand L 1 including wherein E 1 is N; E 2 is B; and R 3 and R 4 represent mono, di, tri, tetra substitutions or no substitution; wherein R 1 , R 2 , R 3 and R 4 are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any two adjacent R 1 , R 2 , R 3 , and R 4 are optionally joined to form a ring, which may be further substituted; wherein L 1 is coordinated to a metal M, provided that the metal M does not form bond with E 1 and E 2 ; and wherein L 1 may be linked with other ligands to comprise a bidentate, tridentate, tetradentate, pentadentate or hexadentate ligand.
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Kottas Gregg

  公开号：US20170240579A9

  公开（公告）日：2017-08-24

  Novel phosphorescent tetradentate platinum compounds of Formula I are provided. The complexes contain a dibenzo moiety, which allows for the creation of OLED devices with improved properties when compounds of Formula I are incorporated into such devices. Compounds of Formula I′ that comprise two ligands that contain a 5-membered carbocyclic or heterocyclic ring, one of which contains an imidazole ring with a twisted aryl group attached to N−1 and a second aromatic ring that is attached to the platinum via a carbon atom. These compounds may be advantageously used in OLEDs.
• US9231218B2
  申请人：——

  公开号：US9231218B2

  公开（公告）日：2016-01-05
• US9783564B2
  申请人：——

  公开号：US9783564B2

  公开（公告）日：2017-10-10