1,3,5-TRIAZINE DERIVATIVE, PRODUCTION METHOD THEREOF AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THIS AS A COMPOSING COMPONENT
申请人:Yamakawa Tetsu
公开号:US20090281311A1
公开(公告)日:2009-11-12
Since the conventional electron transporters have low thermal stability, the organic electroluminescent devices using them are not sufficient in terms of the compatibility of their luminance and luminous efficiency with device lifetime.
A 1,3,5-triazine derivative of formula (1) is obtained by a metal catalyst-aided coupling reaction of a compound of formula (2) with a compound of formula (3), and this is used as a composing component of an organic electroluminescent device.
[In the formulae, Ar
1
and Ar
2
represent phenyl group or the like, R
1
and R
2
represent hydrogen atom or the like, R
3
represents methyl or the like, m is an integer of 0 to 2, X represents 2,4-pyridylene or the like, p is 1 or 2, a and b are 1 or 2, a+b is 3, q is 0 or an integer of p or less, M represents —MgR
4
group or the like, R
4
represents chlorine atom or the like, r is p-q, and Y represents a leaving group.]
由于传统的电子传输体具有低热稳定性,使用它们的有机电致发光器件在亮度和发光效率与器件寿命的兼容性方面不足。通过化合物(2)和化合物(3)的金属催化偶联反应获得式(1)的1,3,5-三嗪衍生物,并将其用作有机电致发光器件的组成部分。[在公式中,Ar1和Ar2代表苯基或类似基团,R1和R2代表氢原子或类似原子团,R3代表甲基或类似基团,m为0至2的整数,X代表2,4-吡啶基或类似基团,p为1或2,a和b为1或2,a+b为3,q为0或小于等于p的整数,M代表-MgR4基团或类似基团,R4代表氯原子或类似原子团,r为p-q,Y代表离去基团。]