N-octadecyl-1-phenylmethanimine | 60514-08-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-octadecyl-1-phenylmethanimine
• 英文别名: benzyliden-octadecyl-amine
• CAS: 60514-08-1
• 化学式: C₂₅H₄₃N
• 分子量: 357.623
• InChiKey: CSFWTPZVZBMCMK-SHHOIMCASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.37
• 重原子数：
  26.0
• 可旋转键数：
  18.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  十八胺 、 苯甲醛 生成 N-octadecyl-1-phenylmethanimine
  参考文献：
  名称：

  SERZHANINA, V. A.;KACHEROVSKAYA, F. B.;ROZHKOVA, N. G.;SMIRNOVA, G. K.;AN+, BECI AN BSSR. CEP. XIM. N., 1986, N 1, 116-118

  摘要：

  DOI：

文献信息

• A thermochromic polyurethane foam and a method for producing the foam
  申请人：MATSUI SHIKISO CHEMICAL CO., LTD

  公开号：EP0231030A2

  公开（公告）日：1987-08-05

  in order to provide a material having the properties of polyurethane foam and being adapted to change color with changes of temperature, a thermochromic polyurethane foam is obtained by reacting and foaming a mixture of a polyol and a polyisocyanate as main components, a thermochromic composition serving as a coloring agent being added to the main components singly or together with a usual dye or pigment, the thermochromic composition containing an electron-donating chromogenic material, an acidic substance and a solvent. The thermochromic composition may be enclosed in the form of microcapsules. The foam is used to provide manufactured articles with a temperature sensing and indicating function.

  为了提供一种具有聚氨酯泡沫特性并能随温度变化而变色的材料，一种热致变色聚氨酯泡沫是由多元醇和多异氰酸酯的混合物作为主要成分进行反应和发泡而得到的，作为着色剂的热致变色组合物被单独或与通常的染料或颜料一起添加到主要成分中，热致变色组合物含有一种电子负载致色材料、一种酸性物质和一种溶剂。 热致变色组合物可以以微胶囊的形式封装。 这种泡沫用于提供具有温度感应和指示功能的制成品。
• Additive for thermosetting resins and thermosetting resin composition containing additive
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0382205A2

  公开（公告）日：1990-08-16

  An additive for thermosetting resins, said additive comprising a compound having in the molecule an atomic grouping containing the >C=⊕N< bond; and a thermosetting resin composition comprising a thermo­setting resin and an effective amount of said ad­ditive.

  一种热固性树脂添加剂，所述添加剂包括一种化合物，其分子中的原子团含有 >C=⊕N< 键；以及一种热固性树脂组合物，所述组合物包括一种热固性树脂和有效量的所述添加剂。
• Additive for organic solvent or thermoplastic polymer
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0388921A2

  公开（公告）日：1990-09-26

  An additive for improving the dispersibility of a particulate substance in an organic medium or a thermoplastic polymer, said additive comprising at least one compound selected from the group consisting of compounds having a 1,3-oxazine structure in the molecule, compounds having a >C= < bond in the molecule and compounds having an oxazolinium ion in the molecule.

  一种添加剂，用于改善颗粒物质在有机介质或热塑性聚合物中的分散性，所述添加剂包括至少一种选自以下组别的化合物：分子中具有 1,3- 恶嗪结构的化合物、分子中具有 >C= < 键的化合物和分子中具有恶唑啉离子的化合物。
• Method for handling (2-alkyl) acryloyl isocyanate, method for producing (2-alkyl)acryloyl isocyanate, heterocyclic compound, and method for producing heterocyclic compound
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0671385A1

  公开（公告）日：1995-09-13

  A method for handling and stabilizing a (2-alkyl)acryloyl isocyanate represented by formula (1) is disclosed, which comprises the steps of:    reacting an azomethine compound represented by formula (2) with the (2-alkyl)acryloyl isocyanate to obtain a reaction product and    dissolving the reaction product into a solvent to regenerate the (2-alkyl)acryloyl isocyanate; wherein R¹ represents a hydrogen atom or a lower alkyl group, wherein R² represents an alkyl group, a cycloalkyl group, an aralkyl group, an alkenyl group, or an alkynyl group, and R³ and R⁴ each represents a hydrogen atom or a group which does not cause tautomerism with C=N in the formula, provided that at least one of R³ and R⁴ is not a hydrogen atom, and further a method for producing a (2-alkyl)acryloyl isocyanate is disclosed, which comprises the step of:    preparing a heterocyclic compound represented by formula (3) and    dissolving the heterocyclic compound into a solvent; wherein R¹ represents a hydrogen atom or a lower alkyl group, wherein R⁵ represents a hydrogen atom or a lower alkyl group, R⁶ represents an alkyl group, a cycloalkyl group, an aralkyl group, an alkenyl group, or an alkynyl group, and R⁷ and R⁸ each represents a hydrogen atom or a group in which a carbon atom located in the α-position to carbon atoms constituting a heterocyclic ring does not have a hydrogen atom, provided that at least one of R⁷ and R⁸ is not a hydrogen atom.

  本发明公开了一种处理和稳定由式（1）表示的(2-烷基)丙烯酰基异氰酸酯的方法，该方法包括以下步骤 将式（2）代表的偶氮亚甲基化合物与(2-烷基)丙烯酰基异氰酸酯反应，得到反应产物，以及 将反应产物溶解到溶剂中，以再生(2-烷基)丙烯酰基异氰酸酯； 其中 R¹ 代表氢原子或低级烷基、 其中 R² 代表烷基、环烷基、芳烷基、烯基或炔基，以及 R³ 和 R⁴ 各自代表氢原子或在式中不与 C=N 发生同分异构的基团，条件是 R³ 和 R⁴ 中至少有一个不是氢原子，还公开了一种生产 (2- 烷基)丙烯酰基异氰酸酯的方法，该方法包括以下步骤： 制备由式（3）代表的杂环化合物，并 将杂环化合物溶解到溶剂中； 其中 R¹ 代表氢原子或低级烷基、 其中 R⁵ 代表氢原子或低级烷基、 R⁶ 代表烷基、环烷基、芳烷基、烯基或炔基，以及 R⁷ 和 R⁸ 各自代表一个氢原子或一个位于构成杂环的碳原子的 α 位上的碳原子不含氢原子的基团，条件是 R⁷ 和 R⁸ 中至少有一个不是氢原子。
• Sterically Hindered Reactions of Grignard Reagents with Schiff Bases
  作者：BERTIN L. EMLING、R. J. HORVATH、A. J. SARACENO、E. F. ELLERMEYER、L. HAILE、L. D. HUDAC

  DOI：10.1021/jo01087a023

  日期：1959.5